Process

• US 9,683,063 B2
• Filed: 12/15/2014
• Issued: 06/20/2017
• Est. Priority Date: 12/23/2013
• Status: Active Grant

• Current Assignee: Ineos Europe AG (Ineos AG)
• Original Assignee: Ineos Europe AG (Ineos AG)
• Inventors: Chamayou, Jean-Louis, Viguier, Renaud, Sere Peyrigain, Pierre
• Primary Examiner(s): CHEUNG, WILLIAM K
• Application Number:
  US15/104,399
• Publication Number:
  US 20160311953A1
• Time in Patent Office: 918 Days
• Field of Search: 526 65, 526 67, 526 70, 422134, 422135
• CPC Class Codes: B01J 19/24 Stationary reactors without moving elements inside B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02
• CPC Class Codes: B01J 2219/00164 controlling the flow
• CPC Class Codes: B01J 2219/24 Stationary reactors without moving elements inside
• CPC Class Codes: B01J 4/02 for feeding measured , i.e. prescribed quantities of reagents
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 2/00 Processes of polymerisation
• CPC Class Codes: C08F 2/007 Scale prevention in the auxiliary parts
• CPC Class Codes: C08F 2/01 characterised by special features of the polymerisation apparatus used
• CPC Class Codes: C08F 2/34 Polymerisation in gaseous state
• CPC Class Codes: C08F 210/16 Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
• CPC Class Codes: Y02P 20/582 Recycling of unreacted starting or intermediate materials

Abstract

Process for polymerizing olefins in a polymerization reactor system including at least first and second introduction points by which the same reaction component may be introduced directly at different locations on the reactor system. At a first time, the reaction component is introduced through at least the first introduction point, such that a proportion X of the reaction component which is introduced through the first and second introduction points is introduced through the first introduction point. At a second, later, time the same reaction component is introduced through at least the second introduction point and such that a proportion Y of the reaction component which is introduced through the first and second introduction points is introduced through the first introduction point. Y is less than X, and at least one of the first and second introduction points is located on the reactor system at a location not on the reactor.

Claims

1. A process for the polymerisation of olefins in a polymerisation reactor system, the polymerisation reactor system comprising a reactor and further comprising at least first and second introduction points by which the same reaction component may be introduced directly at different locations on the reactor system, the process comprising:

(i) at a first time introducing the reaction component through at least the first introduction point and such that a proportion X of the reaction component which is introduced through said first and second introduction points is introduced through the first introduction point, and

(ii) at a second, later, time introducing the same reaction component through at least the second introduction point and such that a proportion Y of the reaction component which is introduced through said first and second introduction points is introduced through the first introduction point,

wherein Y is less than X,

and further wherein at least one of the first and second introduction points is located on the reactor system at a location not on the reactor.

2. A process according to claim 1 wherein X is greater than 0.2.

3. A process according to claim 1 wherein Y is less than 0.5.

4. A process according to claim 1 wherein Y is less than or equal to X−

0.1.

5. A process according to claim 1 wherein flow is switched entirely from introduction through the first introduction point but not the second introduction point at the first time, to introduction through the second introduction point but not the first introduction point at the second time.

7. A process according to claim 1 wherein the polymerisation reactor system comprises

(i) a gas phase reactor having a gas outlet and one or more withdrawal lines for withdrawal of a polymer-containing stream,

(ii) a recycle loop for recycling gas exiting the reactor through the gas outlet back to the reactor,

(iii) a polymer separation system for separating reactants from the polymer product in the withdrawn polymer-containing stream, and

(iv) a recycle system for recycling reactants removed from the reactor in the withdrawn polymer-containing stream back to the reactor.

8. A process according to claim 7 wherein the at least one location at which at least one of the first and second introduction points is located which is part of the reactor system other than the reactor is at least one location where the reaction component is introduced directly into one or more of the recycle loop, the polymer separation system and the recycle system.

9. A process according to claim 7 wherein the at least one location which is part of the reactor system other than the reactor is such that reaction component is introduced into a vessel which is in the recycle loop, in the polymer separation system or in the recycle system, or in a line or equipment other than a vessel which is upstream of such vessel.

10. A process according to claim 1 wherein the at least one location which is part of the reactor system other than the reactor is such that the reaction component is not passed to the reactor directly nor via any fresh feed lines which themselves feed directly to the reactor.

11. A process according to claim 1 wherein the at least one location which is part of the reactor system other than the reactor is such that the reaction component introduced at this location is not introduced directly in any line which line itself feeds directly to the reactor.

12. A process according to claim 1 wherein the “

first time”

is prior to catalyst injection (“

pre-start-up”

) or during the start-up phase, the start-up phase being defined herein as the time after catalyst injection until the production rate exceeds 50% of the targeted steady-state production rate.

13. A process according to claim 1 wherein the “

second time”

is during the start-up phase, between the start-up phase and steady-state operation or at steady-state operation.

14. A process according to claim 1 wherein the reaction component is selected from the group consisting of scavengers, comonomers and condensing agents.

15. A process according to claim 4 wherein the polymerisation reactor system comprises

(i) a gas phase reactor having a gas outlet and one or more withdrawal lines for withdrawal of a polymer-containing stream,

(ii) a recycle loop for recycling gas exiting the reactor through the gas outlet back to the reactor,

(iii) a polymer separation system for separating reactants from the polymer product in the withdrawn polymer-containing stream, and

(iv) a recycle system for recycling reactants removed from the reactor in the withdrawn polymer-containing stream back to the reactor.

16. A process according to claim 15 wherein the at least one location at which at least one of the first and second introduction points is located which is part of the reactor system other than the reactor is at least one location where the reaction component is introduced directly into one or more of the recycle loop, the polymer separation system and the recycle system.

17. A process according to claim 15 wherein the at least one location which is part of the reactor system other than the reactor is such that reaction component is introduced into a vessel which is in the recycle loop, in the polymer separation system or in the recycle system, or in a line or equipment other than a vessel which is upstream of such vessel.

19. A process according to claim 2 wherein X is greater than 0.5.

20. A process according to claim 4 wherein Y is less than or equal to X−

0.5.

6. A process for the polymerisation of olefins in a polymerisation reactor system, the polymerisation reactor system comprising at least a first introduction point and a second introduction point, the process comprising introducing the same reaction component directly at different locations on the reactor system, wherein at a first time the reaction component is introduced through the first introduction point but not the second introduction point, and at a second, later, time the same reaction component is introduced through the second introduction point but not the first introduction point.

18. A polymerisation reactor system comprising:

(a) a first introduction point connected to a source of a reaction component and by which the reaction component may be introduced directly to the polymerisation reactor system at a first location,

(b) a second introduction point connected to the same source of a reaction component and by which the reaction component may be introduced directly to the polymerisation reactor system at a second location different to the first location, and

(c) a control system which controls the supply of the reaction component to the polymerisation reactor system and which prevents the reaction component being introduced through both the first and second introduction points at the same time.