Functionalized silicate nanoparticle composition, removing and exfoliating asphaltenes with same

• US 9,683,163 B2
• Filed: 03/17/2015
• Issued: 06/20/2017
• Est. Priority Date: 12/31/2012
• Status: Active Grant

• Current Assignee: Baker Hughes Incorporated (Baker Hughes Company)
• Original Assignee: Baker Hughes Incorporated (Baker Hughes Company)
• Inventors: Khabashesku, Valery N., Chakraborty, Soma, Mazyar, Oleg A., Agrawal, Gaurav, Hain, Toby D.
• Primary Examiner(s): Li, Aiqun
• Application Number:
  US14/659,919
• Publication Number:
  US 20150191646A1
• Time in Patent Office: 826 Days
• Field of Search: 507 90, 507234, 166304
• CPC Class Codes: C09K 2208/10 Nanoparticle-containing well treatment fluids
• CPC Class Codes: C09K 3/32 for absorbing liquids to remove pollution, e.g. oil, gasoline, fat
• CPC Class Codes: C09K 8/524 organic depositions, e.g. paraffins or asphaltenes
• CPC Class Codes: C09K 8/536 characterised by their form or by the form of their components, e.g. encapsulated material
• CPC Class Codes: C09K 8/58 Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
• CPC Class Codes: C11D 3/162 containing Si

Abstract

Removing an asphaltene particle from a substrate includes contacting a silicate nanoparticle with a chemical group to form a functionalized silicate nanoparticle, the chemical group includes a first portion; and a second portion comprising an aromatic moiety or a nonaromatic moiety, the first portion being bonded to the silicate nanoparticle; contacting the asphaltene particle with the functionalized silicate nanoparticle, the asphaltene particle being disposed on the substrate; interposing the functionalized silicate nanoparticle between the asphaltene particle and the substrate; and separating the asphaltene particle from the substrate with the functionalized silicate nanoparticle to remove the asphaltene particle. A composition includes a functionalized silicate nanoparticle comprising a reaction product of a silicate nanoparticle and a functionalization compound; and a fluid. The functionalization compound includes a chemical group that includes a first portion, the first portion being directly bonded to the silicate nanoparticle in the functionalized silicate nanoparticle; and a second portion including an aromatic moiety or a nonaromatic moiety.

Claims

1. A process for removing an asphaltene particle from a substrate, the process comprising:

contacting a silicate nanoparticle with a chemical group to form a functionalized silicate nanoparticle, the chemical group comprising;

a first portion; and

a second portion comprising an aromatic moiety, the first portion being directly bonded to the silicate nanoparticle in the functionalized silicate nanoparticle; and

the second portion comprising a moiety of a guanidine, a guanidinium salt, a biguanidine, a biguanidinium salt, or a sulfonium salt;

contacting the asphaltene particle with the functionalized silicate nanoparticle, the asphaltene particle being disposed on the substrate;

interposing the functionalized silicate nanoparticle between the asphaltene particle and the substrate; and

separating the asphaltene particle from the substrate with the functionalized silicate nanoparticle to remove the asphaltene particle from the substrate.

2. The process of claim 1, further comprising exfoliating the asphaltene particle with the functionalized silicate nanoparticle.

3. The process of claim 2, wherein exfoliating the asphaltene particle comprises intercalating the aromatic moiety or the nonaromatic moiety of the functionalized silicate nanoparticle in a gallery of the asphaltene particle.

4. The process of claim 2, further comprising heating the functionalized silicate nanoparticle to a temperature effective to exfoliate the functionalized silicate nanoparticle, asphaltene particle, or a combination thereof.

5. The process of claim 1, further comprising contacting the asphaltene particle with a fluid to increase a distance of separation between the asphaltene particle and the substrate after separating the asphaltene particle from the substrate.

6. The process of claim 5, wherein the fluid comprises water, oil, carbon dioxide, a liquefied C1-C6 alkane, completion fluid, brine, acid base, or a combination thereof.

7. The process of claim 1, wherein contacting the silicate nanoparticle with the group is performed in-situ in an environment comprising, a pipeline, downhole, formation, tubular, frac feature, production zone, reservoir, or a combination thereof.

8. The process of claim 7, further comprising removing the asphaltene particle from the environment after separating the asphaltene particle from the substrate.

9. The process of claim 1, wherein the substrate comprises a metal, composite, sand, rock, mineral, glass, formation, downhole element, or a combination thereof.

10. The process of claim 1, wherein the silicate nanoparticle comprises a silsesquioxane, cyclosilicate, inosilicate, nesosilicate, phyllosilicate, sorosilicate, tectosilicate, or a combination thereof.

11. The process of claim 10, wherein the phyllosilicate comprises halloysite, kaolinite, illite, montmorillonite, vermiculite, talc, palygorskite, pyrophyllite, or a combination thereof.

12. The process of claim 10, wherein the silicate nanoparticle comprises a platelet, sphere, polyhedron, rod, cylinder, or a combination thereof.

13. The process of claim 1, wherein the aromatic moiety comprises anthracyl, azulenyl, benzocyclooctenyl, benzocycloheptenyl, biphenylyl, chrysenyl, fluorenyl, indanyl, indenyl, naphthyl, pentalenyl, phenalenyl, phenanthrenyl, phenanthryl, phenyl, pyrenyl, tetrahydronaphthyl, a heteroaryl group, a derivative thereof, or a combination thereof.

14. The process of claim 13, wherein the heteroaryl group comprises acridinyl, benzimidazolyl, benzofuranyl, benzofurazanyl, benzothiazolyl, benzothiophenyl, benzoxazolyl, carbazolyl, chromanyl, cinnolinyl, dibenzofuranyl, furazanyl, furopyridinyl, furyl, imidazolyl, indazolyl, indolinyl, indolizinyl, indolyl, isochromanyl, isoindolinyl, isoindolyl, isoquinolinyl, isothiazolyl, isoxazolyl, naphthyridinyl, oxadiazolyl, oxazolyl, perimidinyl, phenanthridinyl, phenanthrolinyl, phenazinyl, phenoxathiinyl, phenothiazinyl, phenoxazinyl, phthalazinyl, pteridinyl, purinyl, pyrazinyl, pyrazolyl, pyridazinyl, pyridinyl, pyrimidinyl, pyrrolyl, quinazolinyl, quinolinyl, quinoxalinyl, tetrazolyl, thiadiazolyl, thiazolyl, thienyl, triazinyl, triazolyl, a derivative thereof, or a combination thereof.

15. The process of claim 1, wherein the first portion of the chemical group comprises a bond, linker group, or a combination thereof.

16. The process of claim 15, wherein the linker group comprises a bond, C1 to C30 alkylene, C3 to C30 cycloalkenylene, C1 to C30 fluoroalkylene, C3 to C30 cycloalkylene, C3 to C30 heterocycloalkylene, C5 to C30 arylene, C6 to C40 aralkylene, C6 to C30 aryleneoxy, C2 to C30 heteroarylene, C6 to C40 heteroaralkylene, C2 to C30 alkenylene, C2 to C30 alkynylene, C1 to C30 amide, amine, C1 to C30 oxyalkylene, C1 to C30 oxyarylene, oxygen (O), sulfur (S), or a combination thereof, and

the linker group is disposed between the silicate nanoparticle and the second portion of the chemical group in the functionalized silicate nanoparticle.