Low-cost chromatic devices

• US 9,684,218 B2
• Filed: 11/07/2013
• Issued: 06/20/2017
• Est. Priority Date: 11/07/2012
• Status: Active Grant

• Current Assignee: University of South Florida (State University System of Florida)
• Original Assignee: University of South Florida (State University System of Florida)
• Inventors: Ram, Manoj Kumar, Stefanakos, Elias K., Goswami, D. Yogi
• Primary Examiner(s): SAHLE, MAHIDERE S
• Application Number:
  US14/425,568
• Publication Number:
  US 20150234248A1
• Time in Patent Office: 1,321 Days
• Field of Search: 359240, 359265-275
• CPC Class Codes: C03C 17/42 at least one coating of an organic material and at least one non-metal coating
• CPC Class Codes: C03C 2217/211 SnO2
• CPC Class Codes: C03C 2217/215 In2O3
• CPC Class Codes: G02F 1/15165 Polymers
• CPC Class Codes: G02F 1/153 Constructional details

Abstract

In one embodiment, a chromatic device includes an active layer and an electrolyte layer in contact with the active layer, wherein the active layer has an opaque color that blocks light but changes to a translucent color that transmits light when a metal object is placed in electrical contact with the active layer in the presence of the electrolyte layer.

Claims

1. A chromatic device comprising:

an active layer;

an electrolyte layer in contact with the active layer; and

a metal object that can be alternately placed into and out of electrical contact with the active layer;

wherein the active layer has an opaque color that blocks light when the metal object is not in electrical contact with the active layer but changes to a translucent color that transmits light when the metal object is placed in electrical contact with the active layer in the presence of the electrolyte layer, wherein the active layer changes color without applying electrical energy to the active layer.

2. The device of claim 1, further comprising a conductive, transparent substrate on which the active layer is formed.

3. The device of claim 2, wherein the substrate is a metal oxide-coated conducting glass plate.

4. The device of claim 1, wherein the active layer comprises a conducting polymer.

5. The device of claim 1, wherein the conducting polymer is a polyaniline.

6. The device of claim 1, wherein the conducting polymer is a polypyrrole.

7. The device of claim 1, wherein the conducting polymer comprises one or more of polyaniline, POT, poly(ethoxy-aniline), substituted polyaniline, polypyrrole, polythiophene, polyindole, polycarbazole, or substituted polycarbazole.

8. The device of claim 1, wherein the electrolyte layer comprises an oxidant and an acid.

9. The device of claim 8, wherein the oxidant comprises one or more of aluminum nitrate, ammonium dichromate, ammonium peroxydisulphate, barium nitrate, bismuth nitrate, calcium hypoperchlorate, copper (II) nitrate, cupric nitrate, ferric nitrate, hydrogen peroxide, lithium hydroxide monohydrate, magnesium nitrate, magnesium perchlorate, potassium chlorate, potassium dichromate, potassium permanganate, sodium hypochlorite, sodium periodate, zinc nitrate hydrate, nitric acid, sulfuric acid, perchloric acid, ammonium nitrate, silver nitrate, benzoyl peroxide, or tetranitromethane.

10. The device of claim 8, wherein the acid comprises one or more of glacial acetic acid, propionic acid, hydrochloric acid, hydrofluoric acid, phosphoric acid, acetic acid (non-glacial), sulfuric acid, formic acid, benzoic acid, hydrofluoric acid, nitric acid, phosphoric acid, sulfuric acid, tungstosilicic acid hydrate, hydriodic acid, carboxylic acids, acetic acid, dicarboxylic, tricarboxylic, oxalic acid, hexacarboxylic acid, citric acid, or tartaric acid.

11. A chromatic window for alternately blocking and transmitting light, the window comprising:

a conductive, transparent substrate;

an active layer formed on the substrate;

an electrolyte layer in contact with the active layer; and

a metal object that can be alternately placed into and out of electrical contact with the active layer;

wherein the active layer has an opaque color that blocks light when no metal object is in electrical contact with the active layer but changes to a translucent color that transmits light when a metal object is placed in electrical contact with the active layer in the presence of the electrolyte layer, wherein the active layer changes color without applying electrical energy to the active layer.

12. The window of claim 11, wherein the substrate is a metal oxide-coated conducting glass plate.

13. The window of claim 11, wherein the active layer comprises a conducting polymer.

14. The window of claim 13, wherein the conducting polymer is a polyaniline or a polypyrrole.

15. The window of claim 13, wherein the conducting polymer comprises one or more of polyaniline, POT, poly(ethoxy-aniline), substituted polyaniline, polypyrrole, polythiophene, polyindole, polycarbazole, or substituted polycarbazole.

16. The window of claim 11, wherein the electrolyte layer comprises an oxidant and an acid.

17. A method for controlling the transmission of light, the method comprising:

covering a window with an active layer and an electrolyte layer in contact with the active layer, wherein the active layer is opaque in its natural state and prevents light from passing through the window; and

moving a metal object into electrical contact with the active layer to supply electrons from the metal object to the active layer to cause the active layer to change to a translucent color that enables light to pass through the window, wherein no electrical potential or field is applied to the active layer.

18. The method of claim 17, wherein the active layer comprises a conducting polymer.

19. The method of claim 18, wherein the conducting polymer comprises one or more of polyaniline, POT, poly(ethoxy-aniline), substituted polyaniline, polypyrrole, polythiophene, polyindole, polycarbazole, or substituted polycarbazole.

20. The method of claim 17, wherein the electrolyte layer comprises an oxidant and an acid.