Method for making carbon nanotube composite film

• US 9,691,526 B2
• Filed: 04/15/2013
• Issued: 06/27/2017
• Est. Priority Date: 09/11/2012
• Status: Active Grant

• Current Assignee: Beijing FUNATE Innovation Technology Co., Ltd. (Hon Hai Precision Industry Co., Ltd.)
• Original Assignee: Beijing FUNATE Innovation Technology Co., Ltd. (Hon Hai Precision Industry Co., Ltd.)
• Inventors: Feng, Chen, Qian, Li, Wang, Yu-Quan
• Primary Examiner(s): Bareford, Katherine A
• Assistant Examiner(s): MCCLURE, CHRISTINA D
• Application Number:
  US13/862,745
• Publication Number:
  US 20140072723A1
• Time in Patent Office: 1,534 Days
• Field of Search: 427552
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: B82Y 40/00 Manufacture or treatment of nanostructures
• CPC Class Codes: C01B 32/168 After-treatment
• CPC Class Codes: C01B 32/176 Cutting
• CPC Class Codes: H01B 13/003 using irradiation

Abstract

A method for making carbon nanotube composite film is provided. An original carbon nanotube film includes carbon nanotubes joined end to end by van der Waals attractive force. The carbon nanotubes substantially extend along a first direction. A patterned carbon nanotube film is formed by patterning the original carbon nanotube film to define at least one row of through holes arranged in the original carbon nanotube film along the first direction. Each row of through holes includes at least two spaced through holes. The patterned carbon nanotube film is treated with a polymer solution. The patterned carbon nanotube film is shrunk into the carbon nanotube composite film.

Claims

1. A method for making carbon nanotube composite film, comprising:

providing an original carbon nanotube film comprising a plurality of carbon nanotubes joined end to end by van der Waals attractive force and substantially extending along a first direction, and the plurality of carbon nanotubes in the original carbon nanotube film define a plurality of micropores;

forming a patterned carbon nanotube film by patterning the original carbon nanotube film to define a plurality of through holes arranged into a plurality of rows of through holes in the original carbon nanotube film along the first direction, each row of through holes comprising at least two spaced through holes, a space between two adjacent through holes is greater than a size of one of the plurality of micropores in the original carbon nanotube film;

the patterned carbon nanotube film comprises a plurality of connecting parts and a plurality of extending parts both extending along the first direction, the plurality of connecting parts is separated from each other by the plurality of though holes along the first direction, and the plurality of extending parts is separated from each other by the plurality of connecting parts along a second direction crossed with the first direction;

the plurality of extending parts comprises a first portion of the plurality of carbon nanotubes; and

the plurality of connecting parts comprises a second portion of the plurality of carbon nanotubes; and

treating the patterned carbon nanotube film with a polymer solution comprising an organic solvent and a polymer material dissolved in the organic solvent such that the plurality of extending parts is shrunk into a plurality of carbon nanotube linear units;

a pulling force is produced in a process shrinking of the plurality of extending parts, and an interfacial tension is produced between the plurality of connecting parts and the organic solvent; and

extending directions of the second portion of the plurality of carbon nanotubes are shifted into directions intersecting so as to cross the first direction, by the pulling force and the interfacial tension, to form a plurality of carbon nanotube groups; and

the plurality of carbon nanotube groups comprises the second portion of the plurality of carbon nanotubes intercrossed with each other.

2. The method of claim 1, wherein the patterning the original carbon nanotube film comprises using a laser beam or an electron beam to irradiate the original carbon nanotube film.

3. The method of claim 1, wherein a shape of each through hole is a circle, ellipse, triangle, or quadrangle.

4. The method of claim 1, wherein a shape of each through hole is a rectangle, and a space between adjacent through holes is greater than or equal to 0.1 millimeters.

5. The method of claim 1, wherein a shape of each through hole is a rectangle having sides greater than 0.1 millimeters.

6. The method of claim 1, wherein the plurality of through holes in a second direction are arranged in columns, and the plurality of through holes in a same column are spaced from each other.

7. The method of claim 6, wherein a space along the second direction between adjacent through holes is greater than a length in the second direction of each through hole.

8. The method of claim 1, wherein the treating the patterned carbon nanotube film further comprises:

suspending the patterned carbon nanotube film to obtain a suspended patterned carbon nanotube film;

applying the polymer solution on the suspended patterned carbon nanotube film to soak the patterned carbon nanotube film, thus shrinking the patterned carbon nanotube film into a treated patterned carbon nanotube film; and

solidifying the polymer solution on the treated patterned carbon nanotube film.

9. The method of claim 1, wherein the patterned carbon nanotube film is shrunk due to an interfacial tension of the organic solvent in the polymer solution.

10. The method of claim 1, wherein the polymer material is infiltrated into the patterned carbon nanotube film.

11. The method of claim 1, wherein the polymer material is a transparent material.

12. The method of claim 1, wherein a concentration of the polymer solution is in a range from about 0.1 wt % to about 1 wt %.

13. The method of claim 1, wherein the polymer solution comprises the polymer material, the polymer material is selected from the group consisting of epoxy resin, acrylic resin, polyurethane, and any combination thereof.

14. The method of claim 1, wherein the treating the patterned carbon nanotube film with the polymer solution shrinks the patterned carbon nanotube film into the plurality of carbon nanotube linear units spaced from each other;

and the plurality of carbon nanotube groups spaced from each other and combined with the plurality of carbon nanotube linear units by van der Waals force along a second direction; and

the polymer material is coated on surfaces of the plurality of carbon nanotube linear units and the plurality of carbon nanotube groups.

15. The method of claim 14, wherein the treating the patterned carbon nanotube film with the polymer solution enlarges an effective size of the plurality of through holes in the second direction to form a space between adjacent carbon nanotube linear units.

16. The method of claim 1, wherein a first angle defined by the second portion of carbon nanotubes and the first direction is greater than or equal to 45 degrees, and less than or equal to 90 degrees.

17. The method of claim 1, wherein the patterned carbon nanotube film comprises a first end and a second end opposite to the first end, in the process of treating the patterned carbon nanotube film with the polymer solution, the first end is connected to a carbon nanotube array, and the second end is connected to a collecting unit.

18. The method of claim 1, wherein in the process of treating the patterned carbon nanotube film with the polymer solution, the patterned carbon nanotube film is suspended.

19. The method of claim 1, wherein the plurality of carbon nanotube linear units consists of the first portion of the plurality of carbon nanotubes substantially parallel to each other and a first portion of the polymer material.

20. The method of claim 1, wherein the plurality of carbon nanotube groups consists of the second portion of the polymer material and the second portion of the plurality of carbon nanotubes.