System for co-firing cleaned coal and beneficiated organic-carbon-containing feedstock in a coal combustion apparatus

• US 9,702,548 B2
• Filed: 02/18/2015
• Issued: 07/11/2017
• Est. Priority Date: 06/16/2014
• Status: Expired due to Fees

• Current Assignee: CTP Biotechnology, LLC
• Original Assignee: Biomass Energy Enhancements LLC.
• Inventors: Scalzo, Philip James, Tait, Carleton Drew, Van Thorre, Doug M, Catto, Michael L
• Primary Examiner(s): Toomer, Cephia D
• Application Number:
  US14/624,731
• Publication Number:
  US 20150362180A1
• Time in Patent Office: 874 Days
• CPC Class Codes: C10L 2200/0469 Renewables or materials of biological origin
• CPC Class Codes: C10L 2290/02 Combustion or pyrolysis
• CPC Class Codes: C10L 2290/08 Drying or removing water
• CPC Class Codes: C10L 2290/28 Cutting, disintegrating, shredding or grinding
• CPC Class Codes: C10L 2290/30 Pressing, compressing or compacting
• CPC Class Codes: C10L 2290/36 Applying radiation such as microwave, IR, UV
• CPC Class Codes: C10L 2290/545 Washing, scrubbing, stripping, scavenging for separating fractions, components or impurities during preparation or upgrading of a fuel
• CPC Class Codes: C10L 5/08 without the aid of extraneous binders briquetting peat C10F
• CPC Class Codes: C10L 5/143 with lignin-containing products
• CPC Class Codes: C10L 5/363 Pellets or granulates
• CPC Class Codes: C10L 5/366 Powders
• CPC Class Codes: C10L 5/447 Carbonized vegetable substances, e.g. charcoal, or produced by hydrothermal carbonization of biomass
• CPC Class Codes: F23C 1/06 lump and pulverulent fuel
• CPC Class Codes: F23C 2900/01001 Co-combustion of biomass with coal
• CPC Class Codes: F23C 6/042 with fuel supply in stages for staged combustion F23C6/047
• CPC Class Codes: F23C 99/00 Subject-matter not provided for in other groups of this subclass
• CPC Class Codes: F23D 1/00 Burners for combustion of pulverulent fuel disposition of burners F23C
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02E 50/30 Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

A co-firing process is described using cleaned coal and processed biomass to reduce adverse by-products in a coal combusting apparatus. The coal feedstock comprises an aggregate blend of cleaned coal and processed biomass. The biomass feedstock comprises processed biomass pellets. The total energy density is predetermined and can be similar to the coal component or higher than the coal component. The intracellular salt in the processed biomass is at least 60 wt % less for the processed organic-carbon-containing feedstock used to make the processed biomass pellets than that of the starting un-processed processed organic-carbon-containing feedstock. The cleaned coal has a sulfur content that is 50 wt % less than that of un-cleaned coal before it passed through the coal-cleaning sub-system.

Claims

1. A co-firing system for combusting coal and processed biomass in a coal combusting apparatus with less adverse by-products, comprising:

a first chamber of a coal combusting apparatus configured to pulverize a coal feedstock comprising a processed biomass/cleaned coal blended compact aggregate that comprises at least 10 wt % of a coal having a sulfur content of at least 50 wt % less than that of the content of sulfur in the coal before it passed through a coal cleaning sub-system and at least 10 wt % of a processed biomass from a processed biomass system and to feed the pulverized cleaned coal feedstock into the coal combusting apparatus in a first concentration of feedstock;

a second chamber of the coal combusting apparatus configured to pulverize a processed biomass pellet feedstock from the processed biomass system and to feed the pulverized processed biomass pellet feedstock into the coal combusting apparatus in a second concentration of feedstock with the weight ratio of the first concentration to the second concentration between 1 to 9 and 9 to 1,

wherein the processed biomass system is configured to make processed biomass from unprocessed organic-carbon-containing feedstock that includes free water, intercellular water, intracellular water, intracellular water-soluble salts, and at least some plant cells comprising cell walls that include lignin, hemicellulose, and microfibrils within fibrils , the processed biomass system comprising;

a beneficiation sub-system configured to convert the unprocessed organic-carbon-containing feedstock into a processed organic-carbon-containing feedstock with characteristics that include having an energy density of at least 17 MMBTU/ton (20 GJ/MT), a water content of less than 20 wt %, and a water-soluble intracellular salt content that is decreased more than 60 wt % on a dry basis from that of the unprocessed organic-carbon-containing feedstock;

a coal cleaning sub-system configured to convert un-cleaned coal into cleaned coal having a sulfur content at least 50 wt % less than that of the content of sulfur in the un-cleaned coal before it passed through the coal cleaning sub-system;

a blending sub-system configured to convert the cleaned coal and some of the processed biomass into processed biomass/cleaned coal blended compact aggregate with a weight ratio of cleaned coal to processed biomass ranging from 1 to 9 to 9 to 1; and

a pelletizing sub-system configured to convert some of the processed organic-carbon-containing feedstock into processed biomass pellets.

2. The co-firing system of claim 1, wherein the blending sub-system comprises:

a sizing chamber to properly sized particles of coal and processed biomass to a similar size;

a combining chamber configured to blend the similarly sized particles into a blended powder of a predetermined ratio of coal to processed biomass; and

a compacting chamber to compress the blended powder into blended compact aggregates, wherein the pelletizing sub-system comprises;

a compression chamber configured to separate the processed organic-carbon-containing feedstock into discrete units of mass having a longest length of at least 0.16 inch (0.41 cm) and a density of at least 37.5 pounds per cubic foot (0.60 grams per cubic centimeter) to form processed biomass pellets; and

a collection chamber configured to gather aggregates of processed biomass pellets.

3. The co-firing system of claim 1, wherein the processed biomass comprises processed biochar, the blended compact aggregate has an energy density of at least 21 MMBTU/ton (25 GJ/MT), the processed organic-carbon-containing feedstock is passed through a heating sub-system to form processed biochar that is blended with coal into a blended compact aggregate in a blending sub-system, and the water-soluble intracellular salt content decrease is based on comparing the processed organic-carbon-containing feedstock before it is passed through the heating sub-system to the unprocessed organic-carbon-containing feedstock.

4. The co-firing system of claim 1, wherein the beneficiation sub-system comprises:

a transmission device configured to convey into a reaction chamber unprocessed organic-carbon-containing feedstock comprising free water, intercellular water, intracellular water, intracellular water-soluble salts, and at least some plant cells comprising cell walls that include lignin, hemicellulose, and microfibrils within fibrils;

at least one reaction chamber comprising at least one entrance passageway, at least one exit passageway for fluid, at least one exit passageway for processed organic-carbon-containing feedstock , and at least three sections, the sections comprising;

a wet fibril disruption section configured to interact with at least some of the lignin and hemicellulose between the fibrils to make at least some regions of the cell wall more susceptible to penetration by water-soluble salts without dissolving more than 25 percent of the lignin and hemicellulose;

a vapor explosion section in communication with the wet fibril disruption section and at least configured to volatilize plant fibril permeable fluid through rapid decompression to penetrate the more susceptible regions of the cell wall so as to create a porous organic-carbon-containing feedstock with plant cell wall passageways for intracellular water and intracellular water-soluble salts to pass from the plant cell; and

a compaction section in communication with the vapor explosion section and configured to compress the porous organic-carbon-containing feedstock as to permit the escape of intracellular water and intracellular water-soluble salt from the reaction chamber fluid exit passageway and to create processed organic-carbon-containing feedstock that passes out through its reaction chamber exit passageway; and

a collection device in communication with the reaction chamber and configured to gather the processed organic-carbon-containing feedstock having a water content of less than 20% by weight, a combined lignin and hemicellulose content that is decreased by at least 25% on a dry basis from that of the unprocessed organic-carbon-containing feedstock, and a water-soluble intracellular salt content that is decreased by at least 60% on a dry basis from that of the unprocessed organic-carbon-containing feedstock.

5. The co-firing system of claim 3, wherein the heating sub-system is an oxygen-deprived thermal sub-system that comprises a reaction chamber configured to heat processed organic-carbon-containing feedstock in an atmosphere that contains less than 4 percent oxygen to a temperature sufficient to convert at least some processed organic-carbon-containing feedstock into processed biogas and processed biochar.

6. The co-firing system of claim 5, wherein the oxygen-deprived thermal sub-system is selected from

a horizontal sublimation system comprising:

a hot box configured to be able to heat from an ambient temperature to an operating sublimation temperature, maintain an initial operating sublimation temperature and a final operating sublimation temperature that are stable within less than ±

10°

C., and cool from operating sublimation temperatures to an ambient temperature without leaking any oxygen into the hot box and having at least one heat source in communication with the interior of the hot box to supply heat as needed;

at least one horizontal reaction chamber largely located within the hot box, having a surface, configured to heat the processed organic-carbon-containing feedstock without external catalyst or additional water to an operating sublimation temperature in a time frame that is short enough to sublime at least part of the processed organic-carbon-containing feedstock without creating any liquid, configured to heat from an ambient temperature to an operating sublimation temperature, operate at a sublimation temperature, and cool from a operating sublimation temperature to an ambient temperature without leaking any product gas fuel into the surrounding hot box, and comprising an input end outside the hot box and configured to receive compressed feedstock through an input line and an output end outside the hot box and configured to discharge product gas fuel gas through a discharge line and solid char fuel through an output line;

a first powered transport mechanism that is located within the reaction chamber and is configured to convey sublimation products of the processed organic-carbon-containing feedstock through the reaction chamber as the processed organic-carbon-containing feedstock is transformed into processed biogas and processed biochar; and

a gas-tight element on both the input line and output line and configured to prevent hot biogas from adversely escaping from the reaction chamber; and

a vertical sublimation system comprising;

at least one vertical reaction chamber configured to heat the processed organic-carbon-containing feedstock without external catalyst or additional water, carbon dioxide, or carbon monoxide, to an operating sublimation temperature in a time frame that is short enough to sublime at least part of the processed organic-carbon-containing feedstock without creating any liquid;

a first powered transport mechanism that is located partly within the reaction chamber, has an extended part that extends outside the reaction chamber, and is configured to convey sublimation products of the processed organic-carbon-containing feedstock through the reaction chamber as the processed organic-carbon-containing feedstock is transformed into biogas and processed biochar; and

a self-adjusting seal that is configured to continuously contain the processed biogas within the reaction chamber at the region surrounding the extended part of the powered transport mechanism during changing temperatures of startup and shutdown operations, and during steady-state sublimation temperature during operation.

7. The co-firing system of claim 3, wherein the heating sub-system is a microwave sub-system, comprising:

at least one reaction chamber within a microwave reflecting enclosure, the reaction chamber comprising at least one microwave-transparent chamber wall and at least one reaction cavity within the reaction chamber that is configured to hold the organic-carbon-containing feedstock in an externally supplied oxygen free atmosphere;

a microwave subsystem comprising at least one device configured to emit microwaves when energized, the microwave device positioned relative to the reaction chamber so that the microwaves are directed through the microwave-transparent chamber wall and into the reaction cavity; and

a mechanism configured to provide relative motion between the microwave device and the reaction chamber.

8. The co-firing system of claim 4, wherein the vapor explosion section of the beneficiation sub-system comprises:

a wash element that is configured to remove and clean microparticles of unprocessed organic-carbon-containing feedstock, lignin fragments, and hemicellulosic fragments from the vapor explosion section into a fine, sticky mass of biomass with high lignin content; and

a blending chamber of the blending sub-section is further configured to receive fine, sticky mass of biomass to permit lower temperatures in a compaction chamber formation during formation of blended compact aggregates.

9. The co-firing system of claim 4, wherein the processed organic-carbon-containing feedstock has a water soluble intracellular salt content that is decreased by more than 75 wt % on a dry basis from that of unprocessed organic-carbon-containing feedstock and the compaction section of the beneficiated sub-system is configured to provide at least one rinsing step.

20. The co-firing system of claim 1 wherein the compaction section is configured to compress the porous organic-carbon-containing feedstock between pressure plates configured to minimize formation of water-impermeable felt.

10. A process of co-firing coal and processed biomass for combusting coal in a coal combusting apparatus with less adverse by-products comprising:

passing un-cleaned coal through a coal cleaning sub-system to form cleaned coal having a sulfur content that is at least 50 wt % less than that of the content of sulfur in an un-cleaned coal; and

making a processed biomass feedstock pellet in a processed biomass system via a processed biomass system process that comprises;

inputting into the processed biomass a system comprising a first and a second subsystem an unprocessed organic-carbon-containing feedstock that includes free water, intercellular water, intracellular water, intracellular water-soluble salts, and at least some plant cells comprising cell walls that include lignin, hemicellulose, and microfibrils within fibrils;

passing unprocessed organic-carbon-containing feedstock through the first subsystem, a beneficiation sub-system via a beneficiation sub-system process, to result in processed organic-carbon-containing feedstock with characteristics that include having an energy density of at least 17 MMBTU/ton (20 GJ/MT), a water content of less than 20 wt %, and a water-soluble intracellular salt content that is decreased more than 60 wt % on a dry basis from that of the unprocessed organic-carbon-containing feedstock; and

passing the processed organic-carbon-containing feedstock through the second subsystem, a pelletizing sub-system via a pelletizing sub-system process, to result in pelletized processed biomass pellet feedstock;

passing the cleaned coal with part of the processed biomass through a blending sub-system via a blending sub-system process to form a processed biomass/cleaned coal blended compact aggregate that comprises the processed biomass/cleaned coal blended compact aggregate and the processed biomass in a wt ratio of between 1 to 9 and 9 to 1;

providing the processed biomass/cleaned coal blended compact aggregate to a first chamber of the coal combusting apparatus, the first chamber configured to pulverize coal and feed the coal into the coal combusting apparatus in a first concentration weight of feedstock; and

providing part of the processed biomass pellet feedstock to a second chamber of the coal combusting apparatus, the second chamber configured to pulverize the processed biomass and feed the processed biomass into the coal combusting apparatus in a second concentration weight of feedstock with the ratio of the first concentration weight to the second concentration weight is between 1 to 9 and 9 to 1.

11. The process of claim 10, wherein the beneficiation sub-system process comprises:

inputting into a beneficiation sub-system reaction chamber unprocessed organic-carbon-containing feedstock comprising free water, intercellular water, intracellular water, intracellular water-soluble salts, and at least some plant cells comprising cell walls that include lignin, hemicellulose, and microfibrils within fibrils;

exposing the feedstock to hot solvent under pressure for a time at conditions specific to the feedstock to make some regions of the cell walls comprising crystallized cellulosic fibrils, lignin, and hemicellulose more able to be penetrable by water-soluble salts without dissolving more than 25 percent of the lignin and hemicellulose;

removing the pressure so as to penetrate the more penetrable regions to create porous feedstock with open pores in the plant cell walls; and

pressing the porous feedstock with conditions that include an adjustable compaction pressure versus time profile and compaction time duration, and between pressure plates configured to prevent felt from forming and blocking escape from the reaction chamber of intracellular and intercellular water, and intracellular water-soluble salts, and to create processed biomass that has a water content of less than 20 wt % and a water-soluble intracellular salt content that is decreased by at least 60 wt % on a dry basis from that of unprocessed organic-carbon-containing feedstock,

wherein the coal cleaning sub-system process comprises;

sizing the coal particles to increase the amount of coal that remains with the cleaned coal; and

passing the un-cleaned coal through a first chamber to remove minerals and paramagnetic material from the un-cleaned coal to form cleaned coal,

wherein the blending sub-system process comprises;

sizing particles to reduce the size of cleaned coal and processed biomass to a similar size for blending;

combining properly sized particles of processed biomass/cleaned coal blended compact aggregate and processed biomass; and

compressing the blended powder into a multitude of blended compact aggregates, and

wherein the pelletizing sub-system process comprises;

compressing the processed organic-carbon-containing feedstock to separate it into pellets with discrete units of mass having a longest length of at least 0.16 inch (0.41 cm) and a density of at least 37.5 pounds per cubic foot (0.60 grams per cubic centimeter) and collecting an aggregate of processed biomass pellet feedstock.

12. The process of claim 11, wherein the beneficiation sub-system process further comprises:

removing and cleaning of microparticles of unprocessed organic-carbon-containing feedstock, lignin fragments, and hemicellulosic fragments from the vapor explosion section into a fine, sticky mass of biomass with high lignin content in the removing the pressure step, and

wherein the blending sub-system further comprises;

adding the fine, sticky mass of biomass to at least one of the blending sub-system to permit lower temperatures in the compressing step during formation of processed biomass/cleaned coal blended compact aggregate or the pelletizing sub-system to permit lower temperatures in the compressing step during formation of processed biomass pellets.

13. The process of claim 10, wherein the processed biomass that is passed through the blending sub-system process is processed biochar with an energy density of at least 21 MMBTU/ton (25 GJ/MT) and the process comprises:

passing the processed organic-carbon-containing feedstock through another sub-system, a heating sub-system, to form processed biochar.

14. The process of claim 12, wherein the beneficiation sub-system process further comprises:

inputting into a beneficiation sub-system reaction chamber unprocessed organic-carbon-containing feedstock comprising free water, intercellular water, intracellular water, intracellular water-soluble salts, and at least some plant cells comprising cell walls that include lignin, hemicellulose, and microfibrils within fibrils;

exposing the feedstock to hot solvent under pressure for a time at conditions specific to the feedstock to make some regions of the cell walls comprising crystallized cellulosic fibrils, lignin, and hemicellulose more able to be penetrable by water-soluble salts without dissolving more than 25 percent of the lignin and hemicellulose;

removing the pressure so as to penetrate the more penetrable regions to create porous feedstock with open pores in the plant cell walls; and

pressing the porous feedstock with conditions that include an adjustable compaction pressure versus time profile and compaction time duration, and between pressure plates configured to prevent felt from forming and blocking escape from the reaction chamber of intracellular and intercellular water, and intracellular water-soluble salts, and to create processed organic-carbon-containing feedstock that has a water content of less than 20 wt % and a water-soluble intracellular salt content that is decreased by at least 60 wt % on a dry basis from that of unprocessed organic-carbon-containing feedstock, and

wherein the heat generating sub-system process comprises;

inputting processed organic-carbon-containing feedstock into an oxygen-deprived reaction chamber configured to heat the processed organic-carbon-containing feedstock in an atmosphere that contains less than 4 percent oxygen to a temperature sufficient to convert at least some processed organic-carbon-containing feedstock into processed biogas and processed biochar,

wherein the coal cleaning sub-system process comprises;

sizing the coal particles to increase the amount of coal that remains with the cleaned coal; and

passing the un-cleaned coal through a first chamber to remove minerals and paramagnetic material from the un-cleaned coal to form cleaned coal, and

wherein the blending sub-system process comprises;

sizing the particles by reducing the size of coal and processed biochar to a similar size for blending;

combining properly sized particles of coal and processed biochar into a blended powder of a predetermined weight ratio of coal to processed biochar that ranges from 1 to 9 to 9 to 1; and

compressing the blended powder into a multitude of blended compact aggregates comprising cleaned coal and processed biochar, and

wherein the pelletizing sub-system process comprises;

compressing the processed organic-carbon-containing feedstock to separate it into pellets with discrete units of mass having a longest length of at least 0.16 inch (0.41 cm) and a density of at least 37.5 pounds per cubic foot (0.60 grams per cubic centimeter) and collecting an aggregate of processed biomass pellet feedstock.

15. The process of claim 14, wherein the beneficiation sub-system process further comprises:

removing and cleaning of microparticles of unprocessed organic-carbon-containing feedstock, lignin fragments, and hemicellulosic fragments from the vapor explosion section into a fine, sticky mass of biomass with high lignin content in the removing the pressure step, and

the blending sub-system further comprises;

adding the fine, sticky mass of biomass to the blended powder to permit lower temperatures in the compressing step during formation of blended compact aggregates.

16. The process of claim 14, wherein the heating sub-system is an oxygen-deprived thermal sub-system process comprises:

inputting processed organic-carbon-containing feedstock into a horizontal sublimating reaction chamber largely contained within a hot box and configured to be able to heat from an ambient temperature to an operating sublimation temperature, operate at a sublimation temperature, and cool from a operating sublimation temperature to an ambient temperature without leaking any hot product gas fuel from the reaction chamber into the hot box or atmosphere, or leaking any oxygen from outside the hot box into the hot box;

heating the processed organic-carbon-containing feedstock to a sublimating temperature before it is able to form a liquid phase;

maintaining the temperature at a sublimation temperature for a residence time that is as long a time as needed to convert the processed organic-carbon-containing feedstock to processed biogas and processed biochar; and

separating the processed biogas from the processed biochar.

17. The process of claim 14, wherein the wherein the heating sub-system is an oxygen-deprived thermal sub-system process that comprises:

inputting processed organic-carbon-containing feedstock into a vertical sublimating reaction chamber;

heating processed organic-carbon-containing feedstock to a sublimating temperature before it is able to form a liquid phase;

maintaining the temperature at a sublimation temperature for a residence time that is as long a time as needed to convert the processed organic-carbon-containing feedstock to processed biogas and processed biochar; and

separating the processed biogas from the processed biochar.

18. The process of claim 14, wherein the heating sub-system is a microwave sub-system process that comprises:

inputting processed organic-carbon-containing feedstock into a microwave-transparent reaction chamber containing no externally supplied oxygen and within a microwave reflective enclosure;

directing microwaves from a microwave source through walls of the reaction chamber to impinge on the feedstock;

providing relative motion between the microwave-transparent reaction chamber and the microwave source; and

microwaving the feedstock until the feedstock reacts to produce processed biochar further comprising a water-soluble salt content that is a decrease of more than 60 wt % on a dry basis for the processed organic-carbon-containing feedstock from that of unprocessed organic-carbon-containing feedstock and a water content of less than 10 wt %.

19. The process of claim 10, wherein the beneficiation sub-system process and the pelletizing sub-system process comprises:

inputting into a reaction chamber unprocessed organic-carbon-containing feedstock comprising free water, intercellular water, intracellular water, intracellular water-soluble salts, and at least some plant cells comprising cell walls that include lignin, hemicellulose, and microfibrils within fibrils;

exposing the feedstock to hot solvent under pressure for a time at conditions specific to the feedstock to make some regions of the cell walls comprising crystallized cellulosic fibrils, lignin, and hemicellulose more able to be penetrable by water-soluble salts without dissolving more than 25 percent of the lignin and hemicellulose;

removing the pressure so as to penetrate the more penetrable regions to create porous feedstock with open pores in the plant cell walls; and

pressing the porous feedstock with conditions that include an adjustable compaction pressure versus time profile and compaction time duration, and between pressure plates configured to prevent felt from forming and blocking escape from the reaction chamber of intracellular and intercellular water, and intracellular water-soluble salts and to create processed biomass that has a water content of less than 20 wt %, a water-soluble intracellular salt content that is decreased by at least 60 wt % on a dry basis over that of unprocessed organic-carbon-containing feedstock, and a cost per weight of removing the water and water-soluble salt that is reduced to less than 60% of the cost per weight of similar water removal from known mechanical, known physiochemical, or known thermal processes,

wherein the coal cleaning sub-system process comprises;

sizing the coal particles to increase the amount of coal that remains with the cleaned coal; and

passing the un-cleaned coal through a first chamber to remove minerals and paramagnetic material from the un-cleaned coal to form cleaned coal,

wherein the blending sub-system process comprises;

sizing the particles by reducing the size of coal and processed biomass to a similar size for blending;

combining properly sized particles of coal and processed biomass into a blended powder of a predetermined ratio of coal to processed biomass; and

compressing the blended powder into a multitude of blended compact aggregates, and

wherein the pelletizing sub-system process comprises;

compressing the processed organic-carbon-containing feedstock to separate it into pellets with discrete units of mass having a longest length of at least 0.16 inch (0.41 cm) and a density of at least 37.5 pounds per cubic foot (.60 grams per cubic centimeter) and collecting an aggregate of processed biomass pellets.