Phosphor, light-emitting apparatus including the same, and phosphor production method

• US 9,705,049 B2
• Filed: 04/25/2014
• Issued: 07/11/2017
• Est. Priority Date: 04/26/2013
• Status: Active Grant

• Current Assignee: Nichia Corporation
• Original Assignee: Nichia Corporation
• Inventors: Kaide, Takashi, Hosokawa, Shoji
• Primary Examiner(s): Koslow, Carol M
• Application Number:
  US14/261,691
• Publication Number:
  US 20140321099A1
• Time in Patent Office: 1,173 Days
• CPC Class Codes: H01L 2224/48091 Arched
• CPC Class Codes: H01L 2224/48247 connecting the wire to a bond pad of the item
• CPC Class Codes: H01L 2224/48257 connecting the wire to a die pad of the item
• CPC Class Codes: H01L 2924/00014 the subject-matter covered by the group, the symbol of which is combined with the symbol of this group, being disclosed without further technical details
• CPC Class Codes: H01L 33/502 Wavelength conversion materials
• CPC Class Codes: Y10T 428/2982 Particulate matter [e.g., sphere, flake, etc.]

Abstract

A phosphor is provided which is represented by the general formula M_xCe_ySi_6-zB_zN_8+w. M is at least one element selected from the group consisting of La, Y, Tb and Lu. And w, x, y, and z satisfy 2.0<w<4.0, 2.0<x<3.5, 0<y<1.0, and 0<z<2.0, respectively. The phosphor can be efficiently excited by light in a range from near-ultraviolet to blue light, and emit light having components that widely extend mainly from green range to yellow range. A light-emitting apparatus includes the phosphor together with a light-emitting device that emits light in a range from near-ultraviolet to blue light, and can have improved light emission efficiency, good color rendering property, and good color reproduction range. In the case where a light-emitting apparatus includes an additional phosphor, it is possible to further improve its light emission spectrum.

Claims

1. A phosphor represented by the general formula M_xCe_ySi_6-zB_zN_8+w, wherein

M is at least one element selected from the group consisting of La, Y, Tb and Lu,

2.0<

w<

4.0,

2.0<

x<

3.5,

0<

y<

1.0, and

0<

z<

2.0.

2. The phosphor according to claim 1, wherein 2.0<

x<

3.0, 0<

y<

0.5, 0<

z<

1.2.

3. The phosphor according to claim 1, further comprising 10 to 10,000 ppm of fluorine.

4. The phosphor according to claim 1, further comprising 100 to 10,000 ppm of oxygen.

5. The phosphor according to claim 1, wherein the phosphor comprises a crystal phase, and wherein the percentage of the crystal phase is not less than 50% by weight.

6. The phosphor according to claim 1, wherein a mean particle diameter of the phosphor falls within a range from 2 to 30 μ

m.

7. A light emitting apparatus, comprising:

an excitation light source that can emit light in a range from ultraviolet to blue light;

the phosphor according to claim 1 as a first phosphor that can absorb a part of the light from said excitation light source, and can emit luminescent radiation; and

a wavelength conversion member in which said first phosphor is distributed.

8. The light emitting apparatus according to claim 7, wherein said wavelength conversion member comprises at least one second phosphor that can absorb at least a part of the light from said excitation light source, and can emit luminescent radiation with a peak wavelength different from that of said first phosphor.

13. The phosphor according to claim 1, wherein 2.0<

x <

3.3, 0<

y<

0.8, and 0<

z<

1.5.

14. The phosphor according to claim 1, wherein 2.33<

x<

3.0, 0.06<

y<

0.5, and 0<

z<

0.3.

15. The phosphor according to claim 1, further comprising less than 3,860 ppm of oxygen.

16. The phosphor according to claim 1, wherein the phosphor comprises a crystal phase, and wherein the percentage of the crystal phase is more 80% by weight.

17. The phosphor according to claim 1, wherein a mean particle diameter of the phosphor falls within a range from 1 to 50 μ

m.

9. A phosphor production method, comprising:

preparing, pulverizing and mixing materials for elements to compose a composition of phosphor the materials including the elements themselves, or oxide, nitride or carbonate of the elements, so as to provide obtained materials;

filling a crucible with the obtained materials, and burning the obtained materials in a reducing atmosphere, so as to form a burned product; and

pulverizing the burned product, thereby obtaining phosphor powder,

wherein said composition of phosphor is represented by the general formula M_xCe_ySi_6-zB_zN_8+w,

wherein M is at least one element selected from the group consisting of La, Y, Tb and Lu, and 2.0<

w<

4.0, 2.0<

x<

3.5, 0<

y<

1.0 and 0<

z<

2.0.

10. The phosphor production method according to claim 9, wherein the pulverized burned product is placed in an acid solution, thereby reducing the content of impurities contained in the pulverized burned product.

11. The phosphor production method according to claim 10, wherein said acid solution contains hydrochloric acid.

12. The phosphor production method according to claim 9, wherein, in said preparing, pulverizing and mixing step, said materials contain fluoride.