Method for producing high strength ceramic matrix composites

• US 9,708,226 B2
• Filed: 03/11/2014
• Issued: 07/18/2017
• Est. Priority Date: 03/15/2013
• Status: Active Grant

• Current Assignee: Rolls-Royce Corporation (Rolls-Royce Holdings Plc)
• Original Assignee: Rolls-Royce Corporation (Rolls-Royce Holdings Plc)
• Inventors: Lazur, Andrew J.
• Primary Examiner(s): Chen, Bret
• Application Number:
  US14/204,714
• Publication Number:
  US 20160159702A1
• Time in Patent Office: 1,225 Days
• Field of Search: 4272492
• CPC Class Codes: C04B 2235/3826 Silicon carbides
• CPC Class Codes: C04B 2235/428 Silicon
• CPC Class Codes: C04B 2235/5244 Silicon carbide
• CPC Class Codes: C04B 2235/5252 having a specific pre-form
• CPC Class Codes: C04B 2235/614 Gas infiltration of green bodies or pre-forms
• CPC Class Codes: C04B 35/565 based on silicon carbide
• CPC Class Codes: C04B 35/62863 Silicon carbide
• CPC Class Codes: C04B 35/62868 Boron nitride
• CPC Class Codes: C04B 35/62871 Silicon nitride
• CPC Class Codes: C04B 35/62873 Carbon
• CPC Class Codes: C04B 35/62884 by gas phase techniques
• CPC Class Codes: C04B 35/62894 with more than one coating layer
• CPC Class Codes: C04B 35/62897 Coatings characterised by their thickness
• CPC Class Codes: C04B 35/80 Fibres, filaments, whiskers, platelets, or the like
• CPC Class Codes: C04B 41/87 Ceramics

Abstract

A high strength ceramic matrix composite and method for same is provided. A fiber preform is provided that is either self-supporting or is constrained by a tool for subsequent processing. The preform is coated with about 0.1 μm to about 5 μm of silicon carbide. The silicon carbide is coated with about 0.05 μm to about 2 μm boron nitride, carbon, or other interface layer. The interface layer is coated with at least about 0.2 μm to about 40 μm of silicon carbide.

Claims

1. A method of making a high strength ceramic matrix composite, the method comprising the steps of:

forming a fiber preform that is either self supporting or is constrained by a tool for subsequent processing, wherein the fiber preform comprises fibers that each have a diameter and that define a fiber volume;

coating the fiber preform with about 0.1 μ

m to about 5 μ

m of silicon carbide to form a structural coating on the fibers that increases the diameters of the fibers and effectively increasing the fiber volume, wherein the method further comprises cleaning the fiber preform including the fibers after forming the fiber preform and prior to coating the fiber preform to enhance bonding between the fibers and the structural coating;

coating the structural coating of silicon carbide with about 0.05 μ

m to about 2 μ

m boron nitride, carbon or other interface layer to form an interface layer overlying the structural coating; and

coating the interface layer with about 0.2 μ

m to about 40 μ

m of silicon carbide.

2. The method of making the high strength ceramic matrix composite of claim 1, wherein forming the fiber preform comprises forming the fiber preform with the fiber volume of from about 10% to about 45%.

3. The method of making the high strength ceramic matrix composite of claim 1, wherein forming the fiber preform comprises forming the fiber preform comprising a silicon carbide fiber.

4. The method of making the high strength ceramic matrix composite of claim 1, wherein the structural coating includes one or more of the following elements (by volume);

from 0 to 70% silicon, carbon, nitrogen, boron, oxygen, and from 0 to 40% zirconium, titanium, tantalum, hafnium, erbium, ytterbium, dysprosium, gadolinium, niobium, molybdenum, tantalum, Rhenium, Germanium, Tin, or Selenium.

5. The method of making the high strength ceramic matrix composite of claim 1, wherein the fiber preform is self supporting having an integrally woven and angled interlock architecture.

6. The method of making the high strength ceramic matrix composite of claim 1, wherein coating the preform comprises forming the structural coating by a method selected from the group consisting of chemical vapor infiltration, physical vapor deposition, and directed vapor deposition.

7. The method of making the high strength ceramic matrix composite of claim 1, wherein coating the interface layer with silicon carbide comprises forming a silicon carbide layer overlaying the interface layer, and wherein the method further comprises the step of:

coating the silicon carbide layer that overlays the interface layer with one or more additional layers.

8. The method of making the high strength ceramic matrix composite of claim 1, wherein the fiber preform has the fiber volume of about 36%, and wherein coating the preform comprises forming the structural coating on the fibers to effectively increase the fiber volume to about 39% to about 41%.

9. A method of making a high strength ceramic matrix composite, the method comprising the steps of:

forming a fiber preform that is either self supporting or is constrained by a tool for subsequent processing, wherein the fiber preform comprises fibers that each have a diameter and that define a fiber volume;

coating the fiber preform with about 0.1 μ

m to about 5 μ

m of silicon carbide to form a structural coating on the fibers that increases the diameters of the fibers and effectively increasing the fiber volume, wherein the method further comprises cleaning the fiber preform including the fibers after forming the fiber preform and prior to coating the fiber preform to enhance bonding between the fibers and the structural coating; and

coating the structural coating of silicon carbide with about 0.2 μ

m to about 40 μ

m of silicon carbide.

10. The method of making the high strength ceramic matrix composite of claim 9, wherein coating the structural coating comprises coating the structural coating with about 0.5 μ

m of silicon carbide.

11. The method of making the high strength ceramic matrix composite of claim 9, wherein forming the fiber preform comprises forming the fiber preform with the fiber volume of from about 10% to about 45%.

12. The method of making the high strength ceramic matrix composite of claim 9, wherein the fiber preform is self supporting having an integrally woven and angled interlock architecture.

13. The method of making the high strength ceramic matrix composite of claim 9, wherein the fiber preform has the fiber volume of about 36%, and wherein coating the preform comprises forming the structural coating on the fibers to effectively increase the fiber volume to about 39% to about 41%.

14. The method of making the high strength ceramic matrix composite of claim 13, wherein coating the preform with the structural coating effectively increases the fiber volume to about 39%.

15. The method of making the high strength ceramic matrix composite of claim 9, further comprising the step of:

forming the high strength ceramic matrix composite by applying a process selected from the group consisting of at least one of chemical vapor infiltration, physical vapor deposition, tape casting, particulate infiltration, pre-ceramic polymer infiltration and pyrolysis, and metal infiltration to form a ceramic matrix.

16. A method of making a high strength ceramic matrix composite, the method comprising the steps of:

forming a silicon carbide fiber preform comprising fibers that each have a diameter and that define a fiber volume of about 36% and assembling the silicon carbide fiber preform in a tool for chemical vapor infiltration;

coating the silicon carbide fiber preform with about 1 μ

m to about 5 μ

m of silicon carbide to form a structural coating on the fibers that increases the diameters of the fibers and effectively increasing the fiber volume, wherein the method further comprises cleaning the silicon carbide fiber preform including the fibers after forming the silicon carbide fiber preform and prior to coating the silicon carbide fiber preform to enhance bonding between the fibers and the structural coating;

coating the structural coating of silicon carbide with about 0.5 μ

m boron nitride interface layer; and

coating the boron nitride interface layer with about 2 μ

m of silicon carbide.

17. The method of making the high strength ceramic matrix composite of claim 16, further comprising the step of:

forming the ceramic matrix composite through slurry and melt infiltration to form a ceramic matrix.

18. The method of making the high strength ceramic matrix composite of claim 16, wherein coating the silicon carbide fiber preform comprises coating the silicon carbide fiber preform with about 1 μ

m to about 5 μ

m of silicon carbide by chemical vapor infiltration.

19. The method of making the high strength ceramic matrix composite of claim 16, wherein coating the boron nitride interface layer comprises coating the boron nitride interface layer with about 2 μ

m of silicon carbide by chemical vapor infiltration.

20. The method of making the high strength ceramic matrix composite of claim 16, wherein coating the silicon carbide fiber preform comprises forming the structural coating on the fibers to effectively increase the fiber volume to about 39% to about 41%.