LIBS analysis system

• US 9,714,864 B2
• Filed: 04/28/2016
• Issued: 07/25/2017
• Est. Priority Date: 01/21/2013
• Status: Active Grant

• Current Assignee: SciAps, Inc.
• Original Assignee: SciAps, Inc.
• Inventors: Day, David R., Derman, Konstantin, Egan, John Francis, Soucy, Paul Edward
• Primary Examiner(s): Nur, Abdullahi
• Application Number:
  US15/140,816
• Publication Number:
  US 20160238448A1
• Time in Patent Office: 453 Days
• CPC Class Codes: G01J 2003/2879 Calibrating scan, e.g. Fabry Perot interferometer
• CPC Class Codes: G01J 3/0208 using focussing or collimating elements, e.g. lenses or mirrors; performing aberration correction
• CPC Class Codes: G01J 3/0272 Handheld
• CPC Class Codes: G01J 3/0291 Housings; Spectrometer accessories; Spatial arrangement of elements, e.g. folded path arrangements
• CPC Class Codes: G01J 3/10 Arrangements of light sources specially adapted for spectrometry or colorimetry
• CPC Class Codes: G01J 3/2823 Imaging spectrometer
• CPC Class Codes: G01J 3/443 Emission spectrometry
• CPC Class Codes: G01N 21/718 Laser microanalysis, i.e. with formation of sample plasma
• CPC Class Codes: G01N 2201/0221 Portable; cableless; compact; hand-held
• CPC Class Codes: G01N 2201/06113 Coherent sources; lasers
• CPC Class Codes: G01N 2201/0633 Directed, collimated illumination

Abstract

A handheld LIBS spectrometer includes an optics stage movably mounted to a housing and including a laser focusing lens and a detection lens. One or more motors advance and retract the optics stage, move the optics stage left and right, and/or move the optics stage up and down. A laser source in the housing is oriented to direct a laser beam to the laser focusing lens. A spectrometer subsystem in the housing is configured to receive electromagnetic radiation from the detection lens and to provide an output. A controller subsystem is responsive to the output of the spectrometer subsystem and is configured to control the laser source and motors. In this way, auto-calibration, auto-clean, and auto-focus, and/or moving spot functionality is possible.

Claims

1. A handheld LIBS system comprising:

a housing;

an optics stage movably mounted to the housing, the optics stage including an optical head with a laser focusing lens and one or more motors configured to move the optical head and laser focus lens relative to the housing;

a laser source in the housing oriented to direct a laser beam to a sample via the laser focusing lens; and

a spectrometer subsystem in the housing configured to receive electromagnetic radiation from the sample and provide an output, the spectrometer subsystem including a plurality of spectrometers with spectrometer enclosures coupled to each other in the housing, each spectrometer tailored to a different wavelength range.

2. The handheld LIBS system of claim 1 in which each spectrometer enclosure includes a floor and an open top, the floor of one enclosure configured to cover the open top of an adjacent enclosure.

3. The handheld LIBS system of claim 2 in which an outer spectrometer enclosure in the array includes a lid covering its open top.

4. The handheld LIBS system of claim 1 in which each spectrometer enclosure includes optical devices directing electromagnetic radiation from an optical bundle to a sensor.

5. The handheld LIBS system of claim 4 in which said sensor is a CCD sensor.

6. The handheld LIBS system of claim 4 in which one or more said optical devices are adjustable with respect to the spectrometer enclosure.

7. The handheld LIBS system of claim 4 in which said optical devices include a grating with different spectrometer enclosures having different gratings and/or gratings at different angles.

8. The handheld LIBS system of claim 4 in which the optical devices of each spectrometer enclosure are in a Czerny-Turner configuration.

9. The handheld LIBS system of claim 1 in which the optics stage includes one or more motors configured to advance and retract the optical head, move the optical head left and right, and/or move the optical head up and down.

10. The handheld LIBS system of claim 9 further including a controller subsystem responsive to the output of the spectrometer subsystem and configured to control the laser source and said one or more motors.

11. The handheld LIBS system of claim 10 in which the controller subsystem is configured to control said one or more motors to move said optical head to initiate an auto-focus routine, an auto-clean routine, a moving spot cycle, and/or a purge cycle.

12. The handheld LIBS system of claim 11 in which said moving spot cycle includes computer instructions which control said one or more motors to move said optical head to a plurality of locations and at each location to:

power the laser to produce a laser beam, and

process the output of the spectrometer subsystem.

13. The handheld LIBS system of claim 12 in which the controller subsystem is configured to initiate the auto-focus routine and the auto-clean routine at each said location.

14. The handheld LIBS system of claim 13 in which the controller subsystem is configured to initiate said purge cycle during said moving spot cycle.

15. The handheld LIBS system of claim 1 in which said laser source has an output wavelength of approximately 1.5μ

.

16. The handheld LIBS system of claim 1 in which the laser source is a class one or class two laser.

17. The handheld LIBS system of claim 1 in which the laser focusing lens is configured to produce a laser spot size equal to or less than 100μ

on a sample.

18. The handheld LIBS system of claim 1 in which the spectrometer subsystem includes a plurality of optical bundles optically coupled between said optics stage and the plurality of spectrometers.

19. The handheld LIBS system of claim 1 further including an end plate with an aperture and an optically transparent shield in front of the optics stage and spaced from the end plate defining a purge chamber.

20. The handheld LIBS system of claim 19 further including a purge gas source fluidly coupled to the purge chamber.

21. A handheld LIBS system comprising:

a housing;

a movable laser focusing lens;

a laser source in the housing oriented to direct a laser beam to a sample via the laser focusing lens; and

a spectrometer subsystem in the housing configured to receive electromagnetic radiation from the sample and provide an output, the spectrometer subsystem including a plurality of spectrometers with spectrometer enclosures coupled to each other in the housing, each spectrometer tailored to a different wavelength range;

each spectrometer enclosure including a floor and an open top, the floor of one enclosure configured to cover the open top of an adjacent enclosure; and

a controller subsystem responsive to an output of the spectrometer subsystem and configured to adjust the position of the moveable focusing lens.