Apparatus for measuring RF voltage from a quadrupole in a mass spectrometer

• US 9,714,960 B2
• Filed: 10/07/2010
• Issued: 07/25/2017
• Est. Priority Date: 10/09/2009
• Status: Expired due to Fees

• Current Assignee: DH Technologies Development Pte. Ltd. (Danaher Corporation)
• Original Assignee: DH Technologies Development Pte. Ltd. (Danaher Corporation)
• Inventors: Vandermey, John
• Primary Examiner(s): Astacio-Oquendo, Giovanni
• Application Number:
  US12/899,672
• Publication Number:
  US 20110084690A1
• Time in Patent Office: 2,483 Days
• Field of Search: 324 72, 324 725, 324 7611, 324119, 324149, 324316, 324318, 324321, 324322
• CPC Class Codes: G01R 19/003 Measuring mean values of current or voltage during a given time interval
• CPC Class Codes: G01R 19/0084 measuring voltage only all subgroups of G01R19/00 take precedence
• CPC Class Codes: G01R 21/10 by using square-law characteristics of circuit elements, e.g. diodes, to measure power absorbed by loads of known impedance G01R21/02 takes precedence
• CPC Class Codes: G01R 33/32 Excitation or detection systems, e.g. using radio frequency signals
• CPC Class Codes: G01R 33/36 Electrical details, e.g. matching or coupling of the coil to the receiver
• CPC Class Codes: H01J 49/022 Circuit arrangements, e.g. for generating deviation currents or voltages regulating electric or magnetic variables in general, e.g. current, magnetic field G05F; Components associated with high voltage supply high voltage supply per se H02M

Abstract

An apparatus for measuring RF voltage from a quadrupole in a mass spectrometer are provided. The apparatus comprises at least one rectifying diode circuit for rectifying the RF voltage of the quadrupole to produce a rectified RF voltage. The apparatus further comprises at least one operational amplifier configured as a current to voltage converter, a negative input of the at least one operational amplifier connected to the output of at least one diode in the at least one rectifying diode circuit, a positive input of the at least one operational amplifier at ground, and an output of the at least one operational amplifier in a feedback loop with the negative input, to reduce reverse leakage current from the at least one diode.

Claims

1. An apparatus for measuring a sinusoidal RF voltage from a quadrupole in a mass spectrometer, comprising:

at least one rectifying diode circuit for rectifying said RF voltage of said quadrupole to produce and measure a rectified RF voltage by providing an average of the rectified RF voltage;

at least one operational amplifier configured as a current to voltage converter, a negative input of said at least one operational amplifier connected to the output of at least one diode in said at least one rectifying diode circuit, a positive input of said at least one operational amplifier at ground, and an output of said at least one operational amplifier in a feedback loop with said negative input, to continuously convert the diode current to a voltage and to reduce reverse leakage current across the at least one diode;

a second diode in the at least one rectifying circuit, the second diode connected in opposite polarity to the at least one diode; and

the at least one and the second diodes connected to the at least one operational amplifier.

2. The apparatus of claim 1, further comprising at least one capacitor, of a given capacitance, for isolating said quadrupole from said at least one rectifying diode circuit such that said RF voltage is reduced by a given amount.

3. The apparatus of claim 1, further comprising an RC filter, following said at least one operational amplifier, for providing an average of said rectified RF voltage.

4. The apparatus of claim 1, wherein said at least one rectifying diode circuit is enabled to rectify RF voltage of one RF power supply, said RF power supply for supplying RF voltage to said quadrupole.

5. The apparatus of claim 1, wherein said at least one rectifying diode circuit is enabled to rectify RF voltage of at least two RF power supplies, said RF power supplies for supplying RF voltage to at least one quadrupole, including said quadrupole.

6. The apparatus of claim 1, further comprising at least one connector for connection to at least one of:

said quadrupole; and

at least one RF power supply for supplying said RF voltage to said quadrupole.

7. The apparatus of claim 1, further comprising at least one connector for connection to a feedback loop for controlling an RF power supply for supplying said RF voltage to said quadrupole, said at least one connector in communication with an output of said operational amplifier such that a measured rectified RF voltage can be determined.

8. A method for measuring sinusoidal RF voltage from a quadrupole in a mass spectrometer, comprising:

providing a circuit comprising;

at least one rectifying diode circuit for rectifying said RF voltage of said quadrupole to produce and measure a rectified RF voltage by providing an average of the rectified RF voltage;

at least one operational amplifier configured as a current to voltage converter, a negative input of said at least one operational amplifier connected to the output of at least one diode in said at least one rectifying diode circuit, a positive input of said at least one operational amplifier at ground, and an output of said at least one operational amplifier in a feedback loop with said negative input, to continuously convert the diode current to a voltage and to reduce reverse leakage current across the at least one diode;

a second diode in the at least one rectifying circuit, the second diode connected in opposite polarity to the at least one diode;

the at least one and the second diodes connected to the at least one operational amplifier; and

measuring said RF voltage via said circuit.

9. The method of claim 8, wherein said circuit further comprises at least one capacitor, of a given capacitance, for isolating said quadrupole from said at least one rectifying diode circuit such that said RF voltage is reduced by a given amount.

10. The method of claim 8, wherein said circuit further comprises an RC filter, following said at least one operational amplifier, for providing an average of said rectified RF voltage.

11. The method of claim 8, wherein said at least one rectifying diode circuit is enabled to rectify RF voltage of one RF power supply, said RF power supply for supplying RF voltage to said quadrupole.

12. The method of claim 8, wherein said at least one rectifying diode circuit is enabled to rectify RF voltage of at least two RF power supplies, said RF power supplies for supplying RF voltage to at least one quadrupole, including said quadrupole.

13. The method of claim 8, wherein said circuit further comprises at least one connector for connection to at least one of:

said quadrupole; and

at least one RF power supply for supplying said RF voltage to said quadrupole.

14. The method of claim 8, wherein said circuit further comprises at least one connector for connection said circuit to a feedback loop for controlling an RF power supply for supplying said RF voltage to said quadrupole, said at least one connector in communication with an output of said operational amplifier such that a measured rectified RF voltage can be determined.