Method for treating dense deepwater from Lake Kivu

• US 9,718,702 B2
• Filed: 03/02/2016
• Issued: 08/01/2017
• Est. Priority Date: 03/02/2015
• Status: Active Grant

• Current Assignee: Harper Biotech, LLC
• Original Assignee: Harper Biotech, LLC
• Inventors: Harper, Jr., Charles L.
• Primary Examiner(s): Prince, Fred
• Application Number:
  US15/058,756
• Publication Number:
  US 20160257577A1
• Time in Patent Office: 517 Days
• Field of Search: 210602, 210631, 210188, 210252, 210259, 21017009, 2107475
• CPC Class Codes: B01D 19/0036 Flash degasification the other groups take precedence
• CPC Class Codes: B01D 19/0068 General arrangements, e.g. flowsheets B01D19/0063 takes precedence
• CPC Class Codes: C02F 1/20 by degassing, i.e. liberation of dissolved gases degasification of liquids in general B01D19/00; arrangement of degassing apparatus in boiler feed supply F22D
• CPC Class Codes: C02F 1/52 by flocculation or precipitation of suspended impurities C02F1/463 takes precedence
• CPC Class Codes: C02F 1/66 by neutralisation; pH adjustment for degassing C02F1/20; using ion-exchange C02F1/42; for flocculation or precipitation of suspended impurities C02F1/52; for removing dissolved compounds C02F1/58
• CPC Class Codes: C02F 2103/007 Contaminated open waterways, rivers, lakes or ponds
• CPC Class Codes: C02F 3/322 use of algae
• CPC Class Codes: F03B 17/06 using liquid flow with predominantly kinetic energy conversion, e.g. of swinging-flap type , "run-of-river", "ultra-low head" F03B13/264 takes precedence
• CPC Class Codes: Y02E 10/20 Hydro energy
• CPC Class Codes: Y02E 10/30 Energy from the sea, e.g. using wave energy or salinity gradient
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y02W 10/37 using solar energy

Abstract

A method and system are disclosed for total degassing (CH4+CO2) and density-reducing treatment of dense Lake Kivu deepwater. The invention allows hyper-efficient oxyfuel power generation with return flow water reinjection density-matched at or above ˜150 m without necessity to admix biozone (<80 m) water. This increases the CH4 resource and deflates the gas-rich deepwater layer over time, making Lake Kivu safe against a catastrophe threatening up to 2 million lives. Deepwater from the Main Resource Zone (MRZ, ˜480 m to ˜260 m) is de-densified, then reinjected above the Potential Resource Zone (PRZ, ˜260 m to ˜180 m) within the Intermediate Zone (IZ, ˜180 m to ˜80 m), avoiding wasteful resource dilution of the MRZ or PRZ reserves, and allowing methane extraction from the PRZ and IZ. The water treatment process produces valuable algal biomass and co-harvests Mg-hydroxide in vast amounts, allowing value expansion by massive production of bioproducts and CO₂-absorbing eco-cements, concretes and related products.

Claims

1. A method for treating water extracted from Lake Kivu, said method comprising the steps of:

(a) extracting water from an extraction depth of Lake Kivu to obtain extracted water;

(b) degassing the extracted water so as to remove at least a portion of carbon dioxide gas from the extracted water and provide degassed water having a density lower than the extracted water and having a pH higher than the extracted water;

(c) photosynthetic treatment of the degassed water by growth of an algal biomass to convert bicarbonate anions to carbon dioxide and hydroxyl anions, such that the pH of the degassed water is increased and magnesium and calcium precipitate out of the degassed water to provide de-densified water and precipitate;

(d) separating the de-densified water from the algal biomass and the precipitate;

(e) optionally adjusting the pH of the de-densified water by adding carbon dioxide thereto, wherein the carbon dioxide is obtained from the degassing step and by combustion of methane also obtained in the degassing step; and

(f) reinjecting into Lake Kivu a return flow of the de-densified water separated from the biomass and precipitate, wherein the de-densified water is reinjected into Lake Kivu at a reinjection depth which is shallower than the extraction depth and which is density-matched with the de-densified water.

2. The method of claim 1, wherein:

(i) the portion of carbon dioxide gas removed from the extracted water in the degassing step is selected to control the pH of the water and thereby to control degrees of magnesium and calcium precipitation; and

(ii) magnesium and calcium precipitates formed in the degassing step are separated from the degassed water.

3. The method of claim 1, wherein the extraction depth is at least within a main resource zone presently located more than about 260 meters below a surface of Lake Kivu and the reinjection depth is no deeper than 250 meters below the surface of Lake Kivu.

4. The method of claim 3, wherein the reinjection depth is no deeper than 200 meters below the surface of Lake Kivu.

5. The method of claim 3, wherein the reinjection depth is no deeper than 150 meters below the surface of Lake Kivu.

6. The method of claim 1, wherein the extracting step comprises extracting water from a plurality of different extraction depths, each of which is deeper than the reinjection depth.

7. The method of claim 1, wherein the degassing step comprises:

(i) extracting dissolved methane from the extracted water at a first pressure where the carbon dioxide remains preferentially in solution; and

subsequently (ii) extracting the carbon dioxide from the extracted water at a second pressure less than the first pressure.

8. The method of claim 1, wherein the degassing step comprises removing substantially all of the carbon dioxide gas from the extracted water.

9. The method of claim 1, wherein the degassing step comprises removing less than substantially all of the carbon dioxide gas from the extracted water and subsequently conducting the photosynthesis step at a pH lower than with total degassing of carbon dioxide.

10. The method of claim 9, wherein the photosynthesis step is conducted in at least two stages:

(i) a first stage conducted with a first algae that raises the pH of the degassed water but does not precipitate most of the magnesium and calcium; and

(ii) a second stage conducted with a second algae that consumes bicarbonate ions from the degassed water so as to facilitate full precipitation of magnesium and calcium therefrom, wherein the first and second stages are conducted in any order or simultaneously.

11. The method of claim 1, wherein the method promotes natural trophic stages which ultimately cultivate the growth of organisms that contain docosahexaenoic acid and/or eicosapentaenoic acid for harvesting.

12. The method of claim 1, wherein the method is staged to produce at least one crop of alkaline system algae and associated biomass.

13. A system for treating water extracted from Lake Kivu, said system comprising:

(a) a water degassing system configured to extract water from an extraction depth of Lake Kivu to obtain extracted water and degas the extracted water so as to remove at least a portion of carbon dioxide gas therefrom and provide degassed water;

(b) a water treatment system configured to;

(i) photosynthetically treat the degassed water in a biomass containing algae to convert bicarbonate anions to carbon dioxide and hydroxyl anions, such that a pH of the degassed water is increased and magnesium and calcium precipitate out of the degassed water to provide de-densified water and precipitate;

(ii) separate the de-densified water from the biomass and the precipitate; and

optionally (iii) adjust the pH of the de-densified water by adding carbon dioxide thereto, wherein the carbon dioxide is obtained from the degassing step and by combustion of methane also obtained in the degassing step; and

(c) a return flow system configured to reinject into Lake Kivu a return flow of the de-densified water separated from the biomass and precipitate, wherein the de-densified water is reinjected into Lake Kivu at a reinjection depth which is shallower than the extraction depth and which is density-matched with the de-densified water.

14. The system of claim 13, wherein the water degassing system comprises:

an intake pipe system;

at least one bubble capture unit positioned upwards along a system of degassing pipes;

at least one degassing catalyst unit positioned further upwards along the system of degassing pipes;

a bubbly flow turbine configured to capture and recycle power from jetting foam flow at a top of the system of degassing pipes, wherein the bubbly flow turbine is also configured to function as a foam separator;

at least one vacuum degassing unit positioned at the top of the system of degassing pipes; and

a water flow turbine capturing and recycling power in a downward outflow of degassed water from the at least one vacuum degassing unit.

15. The system of claim 13, wherein the return flow system comprises:

an outflow pipe from the water degassing system;

pipe systems connecting flow to the water treatment system;

a return flow pipe system and horizontal diffuser to reinject degassed water into Lake Kivu at a specified depth; and

flow control valve systems with emergency shut-off capabilities.

16. The system of claim 13, wherein the water treatment system is further configured to:

(i) control the portion of carbon dioxide gas removed from the extracted water in the degassing step to control the pH of the extracted water and thereby to control degrees of magnesium and calcium precipitation; and

(ii) separate from the degassed water and recover magnesium and calcium precipitates formed in the degassing step.