LIBS analysis system

• US 9,719,853 B2
• Filed: 04/28/2016
• Issued: 08/01/2017
• Est. Priority Date: 01/21/2013
• Status: Active Grant

• Current Assignee: SciAps, Inc.
• Original Assignee: SciAps, Inc.
• Inventors: Day, David R., Derman, Konstantin, Egan, John Francis, Soucy, Paul Edward
• Primary Examiner(s): Geisel, Kara E
• Assistant Examiner(s): SMITH, MAURICE C
• Application Number:
  US15/140,707
• Publication Number:
  US 20160238535A1
• Time in Patent Office: 460 Days
• CPC Class Codes: G01J 2003/2879 Calibrating scan, e.g. Fabry Perot interferometer
• CPC Class Codes: G01J 3/0208 using focussing or collimating elements, e.g. lenses or mirrors; performing aberration correction
• CPC Class Codes: G01J 3/0272 Handheld
• CPC Class Codes: G01J 3/0291 Housings; Spectrometer accessories; Spatial arrangement of elements, e.g. folded path arrangements
• CPC Class Codes: G01J 3/10 Arrangements of light sources specially adapted for spectrometry or colorimetry
• CPC Class Codes: G01J 3/2823 Imaging spectrometer
• CPC Class Codes: G01J 3/443 Emission spectrometry
• CPC Class Codes: G01N 21/718 Laser microanalysis, i.e. with formation of sample plasma
• CPC Class Codes: G01N 2201/0221 Portable; cableless; compact; hand-held
• CPC Class Codes: G01N 2201/06113 Coherent sources; lasers
• CPC Class Codes: G01N 2201/0633 Directed, collimated illumination

Abstract

A handheld LIBS spectrometer includes an optics stage movably mounted to a housing and including a laser focusing lens and a detection lens. One or more motors advance and retract the optics stage, move the optics stage left and right, and/or move the optics stage up and down. A laser source in the housing is oriented to direct a laser beam to the laser focusing lens. A spectrometer subsystem in the housing is configured to receive electromagnetic radiation from the detection lens and to provide an output. A controller subsystem is responsive to the output of the spectrometer subsystem and is configured to control the laser source and motors. In this way, auto-calibration, auto-clean, and auto-focus, and/or moving spot functionality is possible.

Claims

1. A handheld LIBS system comprising:

a housing;

an optics stage movably mounted to the housing including an optics head with a laser focusing lens;

a spectrometer subsystem in the housing configured to receive electromagnetic radiation from a sample and provide an output;

a nose section including;

the laser focusing lens, an apertured end plate removably fastened to the nose section via at least one fastener, and an optically transparent shield spaced from the end plate and in front of the laser focusing lens protecting the laser focusing lens and defining a purge chamber between the shield and the removable end plate;

a laser source in the housing oriented to direct a laser beam to the sample via the laser focusing lens, the shield, and the aperture in the end plate; and

a purge gas source fluidly coupled to the purge chamber.

2. The handheld LIBS system of claim 1 in which the end plate is made of or includes a portion made of a calibration standard.

3. The handheld LIBS system of claim 1 in which the housing includes a handle and the gas source includes a gas cartridge disposed in the housing.

4. The handheld LIBS system of claim 3 in which the gas cartridge is pivotably disposed in the housing handle.

5. The handheld LIBS system of claim 4 in which the gas source cartridge is fluidly coupled to the purge chamber via a regulator, the regulator is rotatably coupled to the housing, and the gas source cartridge is coupled to the rotating regulator.

6. The handheld LIBS system of claim 1 in which the gas source is fluidly connected to the purge chamber via a controllable valve.

7. The handheld LIBS system of claim 6 further including a controller subsystem configured to automatically control said valve.

8. The handheld LIBS system of claim 1 further including a controller subsystem responsive to the output of the spectrometer subsystem and configured to control the laser source.

9. The handheld LIBS system of claim 8 in which said controller subsystem is configured to control the optics stage to initiate a calibration routine.

10. The handheld LIBS system of claim 9 in which said calibration routine includes computer instructions which move said optics stage to aim the laser beam at the calibration standard, to power the laser to produce a laser beam, to process the output of the spectrometer subsystem, and to calibrate the spectrometer based on the output of the spectrometer subsystem.

11. The handheld LIBS system of claim 10 in which said computer instructions which calibrate the spectrometer include instructions which determine wavelength and/or intensity calibration constants based on the output of the spectrometer subsystem.

12. The handheld LIBS system of claim 1 in which the optics stage moveably mounted to the housing includes an optical head with the laser focusing lens and the optics stage includes one or more motors configured to advance and retract the optical head and move the optical head left and right and/or move the optical head up and down.

13. The handheld LIBS system of claim 12 further including a controller subsystem responsive to the output of the spectrometer subsystem and configured to control the laser source and said one or more motors.

14. The handheld LIBS system of claim 13 in which the controller subsystem is configured to control said one or more motors to move said optical head to initiate an auto-focus routine, an auto-clean routine, a moving spot cycle, and/or a purge cycle.

15. The handheld LIBS system of claim 14 in which said moving spot cycle includes computer instructions which control said one or more motors to move said optical head to a plurality of locations and at each location to:

power the laser to produce a laser beam, and

process the output of the spectrometer subsystem.

16. The handheld LIBS system of claim 15 in which the controller subsystem is configured to initiate the auto-focus routine and the auto-clean routine at each said location.

17. The handheld LIBS system of claim 15 in which the controller subsystem is configured to initiate said purge cycle during said moving spot cycle.

18. The handheld LIBS system of claim 1 in which said laser source has an output wavelength of approximately 1.5 μ

.

19. The handheld LIBS system of claim 1 in which the laser source is a class one or class two laser.

20. The handheld LIBS system of claim 1 in which the laser focusing lens is configured to produce a laser spot size equal to or less than 100 μ

on a sample.

21. The handheld LIBS system of claim 1 in which the spectrometer subsystem includes a plurality of optical bundles optically coupled between said optics stage and a plurality of spectrometer enclosures coupled to each other in the housing.

22. A handheld LIBS system comprising:

a housing;

an optics stage movably mounted to the housing including an optics head with a laser focusing lens;

a spectrometer subsystem in the housing configured to receive electromagnetic radiation from a sample and provide an output;

a nose section including;

the laser focusing lens, an apertured end plate including a calibration standard and removable from the nose section via at least one fastener, an optically transparent shield spaced from the end plate and in front of the optics head protecting the laser focusing lens, and a purge chamber between the end plate and the shield;

a laser source in the housing oriented to direct a laser beam to the sample via the laser focusing lens, the shield, and the aperture in the end plate;

a purge gas source fluidly coupled to the purge chamber;

a controller subsystem responsive to the output of the spectrometer subsystem and configured to control the laser source and to control the optics stage to initiate a calibration routine including computer instructions which move said optics stage to aim the laser source at the calibration standard, to power the laser source to produce a laser beam, to process the output of the spectrometer subsystem, and to calibrate the spectrometer based on the output of the spectrometer subsystem; and

and a purge gas source coupled to the purge chamber.