Laser-induced breakdown spectroscopy of oil sands

• US 9,719,933 B1
• Filed: 11/23/2016
• Issued: 08/01/2017
• Est. Priority Date: 04/25/2016
• Status: Active Grant

• Current Assignee: National Research Council Canada, Syncrude Canada Limited
• Original Assignee: National Research Council Canada, Syncrude Canada Limited
• Inventors: Blouin, Alain, Paproski, Richard, Harhira, Assa, Duford, David, El Haddad, Josette, Daugela, Darcy, Sabsabi, Mohamad
• Primary Examiner(s): Nur, Abdullahi
• Application Number:
  US15/360,706
• Time in Patent Office: 251 Days
• CPC Class Codes: G01N 21/274 Calibration, base line adjustment, drift correction
• CPC Class Codes: G01N 21/718 Laser microanalysis, i.e. with formation of sample plasma
• CPC Class Codes: G01N 2201/129 Using chemometrical methods
• CPC Class Codes: G01N 33/24 Earth materials G01N33/42 takes precedence

Abstract

A method of quantifying at least one property of interest of an oil sands ore sample is provided using a laser-induced breakdown spectroscopy (LIBS) method. The LIBS method may be applied to oil sands ore being conveyed prior to a slurry process to measure oil sand composition and provide information which may predict extraction characteristics. The LIBS method may be applied to oil sands core samples in a laboratory setting to reduce the cost and analysis time associated with conventional laboratory measurement techniques.

Claims

1. A method of determining at least one property of interest of a test oil sands ore sample, comprising the steps of:

(a) applying a plurality of pulsed laser shots focused on a surface of the test oil sand ore sample to ablate the test oil sands ore sample and create a plurality of short-lived plasmas;

(b) acquiring the emission spectra from at least some or all of the plasmas;

(c) repeating steps (a) and (b) on one or more ablation sites until a predetermined minimum ablation depth and total ablation volume have been achieved;

(d) averaging the acquired emission spectra together for the test oil sands ore sample to form a test emission spectrum;

(e) optionally, preprocessing the test emission spectrum; and

(f) applying at least one calibration loading to determine the at least one property of interest, wherein the at least one calibration loading is obtained from a chemometric model relating an emission spectrum, or a portion of an emission spectrum, obtained from a known oil sands ore sample to a reference value obtained from a physicochemical analysis method for determining the at least one property of interest of the known oil sands ore sample;

provided that the test or known oil sands ore sample is not an aqueous oil sands slurry; and

provided that the at least one property of interest measured chemometrically from acquired LIBS spectra comprises one or more of the following,

(a) properties related to oil sand bitumen extraction characteristic(s), comprising one or more of;

1. Primary bitumen recovery

2. Combined primary and secondary bitumen recovery

3. Primary froth bitumen content

4. Combined primary and secondary froth bitumen content

5. Primary froth water content

6. Combined primary and secondary froth water content

7. Primary froth solids content

8. Combined primary and secondary froth solids content

9. Optimal process aid dosage (including but not limited to caustic);

or

(b) properties conventionally measured in a laboratory comprising either or both;

10. Solids particle size information;

or

11. Solids methylene blue index;

and not % bitumen content in the original oil sands ore or elemental concentrations.

2. The method of claim 1 wherein the minimum depth of each ablation site is about 4 mm, and the minimum total ablation volume from all ablation sites is about 0.3 cm³.

3. The use of a laser induced breakdown plasma spectroscopic system comprising a laser ablator and a detector combined with one or more processors and a memory, wherein the memory stores machine-readable instructions that, when executed by the one or more processors, cause the system to carry out functions to implement the method of claim 1.

4. The method as claimed in claim 1, wherein the property measured is solids having a particle size less than 44 μ

m to determine optimal process aid dosage.

5. The method as claimed in claim 1, wherein the process aid is caustic.