Regeneratable ion exchange material for reducing the amount of CO2

• US 9,724,641 B2
• Filed: 07/16/2013
• Issued: 08/08/2017
• Est. Priority Date: 08/08/2012
• Status: Active Grant

• Current Assignee: Omya International AG
• Original Assignee: Omya International AG
• Inventors: Gantenbein, Daniel, Schoelkopf, Joachim, Gane, Patrick A. C., Schenker, Michel
• Primary Examiner(s): Jones, Christopher P
• Application Number:
  US14/414,797
• Publication Number:
  US 20150165372A1
• Time in Patent Office: 1,484 Days
• CPC Class Codes: B01D 2251/402 of magnesium
• CPC Class Codes: B01D 2251/404 of calcium
• CPC Class Codes: B01D 2251/406 of strontium
• CPC Class Codes: B01D 2252/10 Inorganic absorbents chemical reactants B01D2251/00
• CPC Class Codes: B01D 2253/108 Zeolites
• CPC Class Codes: B01D 2253/11 Clays
• CPC Class Codes: B01D 2253/206 Ion exchange resins
• CPC Class Codes: B01D 2255/804 Enzymatic
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B01D 53/12 according to the "fluidised technique"
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: B01D 53/78 with gas-liquid contact
• CPC Class Codes: B01D 53/82 with stationary reactants
• CPC Class Codes: B01D 53/83 with moving reactants
• CPC Class Codes: B01D 53/85 with gas-solid contact
• CPC Class Codes: B01D 53/96 Regeneration, reactivation or recycling of reactants
• CPC Class Codes: B01J 20/12 Naturally occurring clays or bleaching earth
• CPC Class Codes: B01J 39/02 Processes using inorganic exchangers
• CPC Class Codes: B01J 39/04 Processes using organic exchangers
• CPC Class Codes: B01J 39/14 : Base exchange silicates, e.g. zeolites
• CPC Class Codes: B01J 39/18 : Macromolecular compounds B01J39/17 takes precedence
• CPC Class Codes: B01J 47/02 : Column or bed processes
• CPC Class Codes: C01F 11/18 : Carbonates
• CPC Class Codes: C01F 5/24 : Magnesium carbonates
• CPC Class Codes: Y02C 20/40 : of CO2
• CPC Class Codes: Y02P 20/151 : Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Abstract

The present invention relates to a method for reducing the amount of CO₂ in a carbon dioxide-containing source by using a regeneratable ion exchange material.

Claims

1. A method for reducing the amount of CO₂ in a carbon dioxide-containing source by using a regeneratable ion exchange material, comprising the following steps of:

a) providing at least one ion exchange material comprising at least one earth alkali metal cation,

b) providing at least one carbon dioxide-containing source,

c) providing at least one source of at least one cation which is capable of replacing the at least one earth alkali metal cation of the at least one ion exchange material,

d) providing at least one source of at least one earth alkali metal cation,

e) contacting the at least one ion exchange material of step a) with the at least one source of at least one cation of step c) such as to obtain a mixture comprising

i) at least one ion exchange material, and

ii) at least one earth alkali metal cation released from the at least one ion exchange material of step a),

f) separating the at least one earth alkali metal cation of step ii) from the at least one ion exchange material of step i),

g) contacting the at least one earth alkali metal cation obtained in step f) with the at least one carbon dioxide-containing source of step b) such as to obtain a carbonate salt of the at least one earth alkali metal cation, and

h) contacting the at least one ion exchange material obtained in step f) with the at least one source of at least one earth alkali metal cation of step d) such as to regenerate the at least one ion exchange material of step a).

2. The method of claim 1, wherein the at least one ion exchange material of step a) is selected from the group consisting of a natural ion exchange material, a modified ion exchange material, a synthetic ion exchange material, and any mixture thereof.

3. The method of claim 1, wherein the at least one ion exchange material of step a) comprises a natural ion exchange material selected from the group consisting of phyllosilicates, zeolite, mica, montmorillonite, mauritzite, and any mixture thereof, and/or a synthetic ion exchange material selected from the group consisting of eDTA, ion exchange resins, and any mixture thereof.

4. The method of claim 1, wherein the at least one ion exchange material of step a) comprises a phyllosilicate.

5. The method of claim 1, wherein the at least one ion exchange material of step a) comprises at least one earth alkali metal cation selected from the group consisting of magnesium, calcium, strontium, and any mixture thereof.

6. The method of claim 1, wherein the at least one ion exchange material of step a) comprises calcium and/or magnesium as an earth alkali metal cation.

7. The method of claim 1, wherein the at least one ion exchange material of step a) is provided in form of a solid or an aqueous suspension or an emulsion or a filter material or a fluidized bed.

8. The method of claim 1, wherein the at least one ion exchange material of step a) is provided in form of an aqueous suspension having an ion exchange material content of from 2 to 50 wt.-%, based on the total weight of the aqueous suspension.

9. The method of claim 1, wherein the at least one ion exchange material of step a) is provided in form of an aqueous suspension having an ion exchange material content of from 5 to 30 wt.-%, based on the total weight of the aqueous suspension.

10. The method of claim 1, wherein the at least one ion exchange material of step a) consists of bentonite comprising clay minerals selected from the group consisting of montmorillonites, concomitant minerals, quartz, mica, kaolinite, feldspar, pyrite, calcite, cristobalite, and any mixture thereof.

11. The method of claim 1, wherein the at least one ion exchange material of step a) consists of bentonite having a montmorillonite content of at least 60 wt.-%, based on the total weight of the bentonite.

12. The method of claim 1, wherein the at least one ion exchange material of step a) consists of bentonite having a montmorillonite content of at least 80 wt.-%, based on the total weight of the bentonite.

13. The method of claim 1, wherein the ion exchange material of step a) consists of bentonite whose interlayer spaces are occupied primarily with calcium and/or magnesium ions.

14. The method of claim 1, wherein the at least one ion exchange material of step a) consists of bentonite having a weight median particle size d₅₀ from 0.02 to 100 μ

m.

15. The method of claim 1, wherein the at least one ion exchange material of step a) consists of bentonite having a weight median particle size d₅₀ from 0.075 to 50 μ

m.

16. The method of claim 1, wherein the at least one ion exchange material of step a) consists of bentonite having a weight median particle size d₅₀ from 0.1 to 5 μ

m.

17. The method of claim 1, wherein the at least one carbon dioxide-containing source of step b) is selected from a gas, liquid, solid, complex, ion exchange material, and any mixture thereof.

18. The method of claim 1, wherein the at least one carbon dioxide-containing source of step b) is a gas.

19. The method of claim 1, wherein the at least one carbon dioxide-containing source of step b) is selected from air, industrial exhaust gas streams, waste gas streams, volcanic outgassing, and any mixture thereof.

20. The method of claim 1, wherein the at least one carbon dioxide-containing source of step b) comprises carbon dioxide providing a partial pressure of at least 0.02 Pa.

21. The method of claim 1, wherein the at least one source of at least one cation of step c) and/or the at least one source of at least one earth alkali metal cation of step d) is an aqueous solution comprising at least 50 wt.-%, based on the total weight of the aqueous solution, of water.

22. The method of claim 1, wherein the at least one source of at least one cation of step c) is a naturally occurring source of at least one monovalent and/or divalent cation capable of replacing the at least one earth alkali metal cation of the at least one ion exchange material.

23. The method of claim 1, wherein the at least one source of at least one cation of step c) is sea water.

24. The method of claim 1, wherein the at least one carbon dioxide-containing source of step b) and/or the at least one source of at least one cation which is capable of replacing the at least one earth alkali metal cation of the at least one ion exchange material of step c) and/or the at least one source of at least one earth alkali metal cation are provided in form of an aqueous solution having a pH of between 5 and 12.

25. The method of claim 1, wherein the at least one cation of the at least one source of at least one cation of step c) is selected from the group comprising lithium, sodium, potassium, magnesium, strontium, and any mixture thereof.

26. The method of claim 1, wherein the at least one cation of the at least one source of at least one cation of step c) is sodium.

27. The method of claim 1, wherein the at least one source of at least one cation of step c) comprises the at least one cation in an amount of from 0.1 to 150 g/l.

28. The method of claim 1, wherein the at least one source of at least one earth alkali metal cation of step d) is a naturally occurring source of at least one earth alkali metal cation.

29. The method of claim 1, wherein the at least one source of at least one earth alkali metal cation of step d) is fresh hard water having a hardness of from 5 to 130°

dH.

30. The method of claim 1, wherein the at least one earth alkali metal cation of the at least one source of at least one earth alkali metal cation of step d) is selected from magnesium, calcium, strontium, and any mixture thereof.

31. The method of claim 1, wherein the at least one earth alkali metal cation of the at least one source of at least one earth alkali metal cation of step d) is calcium.

32. The method of claim 1, wherein the at least one source of at least one earth alkali metal cation of step d) comprises the at least one earth alkali metal cation in an amount from 0.1 to 200 mg/l.

33. The method of claim 1, wherein contacting step g) is carried out in that the at least one carbon dioxide-containing source of step b) is introduced into an aqueous solution obtained in step f).

34. The method according to claim 33, wherein the aqueous solution obtained in step f) is further contacted with at least one catalyst for enhancing the hydratisation of carbon dioxide.

35. The method according to claim 34, wherein the at least one catalyst for enhancing the hydratisation of carbon dioxide is at least one enzyme.

36. The method according to claim 35, wherein the at least one enzyme is carbonic anhydrase.

37. The method of claim 1, wherein contacting step e) and/or separating step f) and/or contacting step g) and/or contacting step h) is/are carried out at a temperature from 2°

C. to 80°

C.

38. The method of claim 1, wherein contacting step e) and/or separating step f) and/or contacting step g) and/or contacting step h) is/are carried out at a pH of between 4 and 12.

39. The method of claim 1, wherein contacting step g) is carried out under pressure of at least 100 Pa.

40. The method of claim 1, wherein contacting step h) is carried out before and/or during and/or after contacting step g).

41. The method of claim 1, wherein separating step f) is carried out by filtration, centrifugation, cycloning, sedimentation, or any mixture thereof.

42. The method of claim 1, which further comprises step k) of separating the carbonate salt of the at least one earth alkali metal cation obtained in step g).

43. The method of claim 42, wherein separating step k) is carried out by filtration, centrifugation, cycloning, concentrating, evaporation, sedimentation, or any mixture thereof.