Test kit for detecting acids in refrigerant lubricating oils and method of use

• US 9,733,229 B1
• Filed: 03/13/2014
• Issued: 08/15/2017
• Est. Priority Date: 03/15/2013
• Status: Active Grant

• Current Assignee: Zynon Technologies, LLC
• Original Assignee: Zynon Technologies, LLC
• Inventors: Cunningham, Wells, Tourigny, Jay S.
• Primary Examiner(s): Fitzgerald, John
• Assistant Examiner(s): Kidanu, Gedeon M
• Application Number:
  US14/208,790
• Time in Patent Office: 1,251 Days
• CPC Class Codes: G01N 1/2035 by deviating part of a fluid stream, e.g. by drawing-off or tapping
• CPC Class Codes: G01N 2001/205 using a valve
• CPC Class Codes: G01N 21/80 Indicating pH value
• CPC Class Codes: G01N 31/22 using chemical indicators G01N31/02 takes precedence
• CPC Class Codes: G01N 31/221 for investigating pH value
• CPC Class Codes: G01N 33/2888 Lubricating oil characteristics, e.g. deterioration lubricating properties G01N33/30

Abstract

A test kit (110) includes an at least partially transparent or translucent tubular collection chamber (122) which has a flow control valve (111) at the inlet end (122a) thereof. Flow control valve (111) has a mouth (112a) that is used to engage a Schrader valve (132) of a HVACR system to flow pressurized refrigerant fluid into the collection chamber (122) via flow control valve (111). The flow of the pressurized refrigerant fluid is throttled by flow control valve (111) to ensure that sufficient lubricating oil is separated from the refrigerant fluid and remains within the collection chamber (122), even as refrigerant is expelled from collection chamber (122) via vent holes (124). A collector (126) serves to accumulate separated lubricating oil. A frangible ampoule (128) which contains a liquid pH indicator (130) is crushed to contact the pH indicator with the separated lubricating oil to test the pH of the oil by color change of the pH indicator.

Claims

1. A test kit for separating from a pressurized refrigerant withdrawn from a refrigerant system at least a portion of a lubricating oil entrained in the refrigerant to provide a lubricating oil sample, and then testing the lubricating oil sample for acidity, the test kit comprising:

a collection chamber having an interior wall and an observation location, and comprising an inlet end having an inlet-end opening and an outlet end having an outlet-end opening, the collection chamber defining a fluid flow path extending therethrough to the outlet-end opening, the inlet-end opening being configured to operate a system access valve of such pressurized refrigerant system to flow such refrigerant and its entrained lubricating oil via the inlet-end opening along the fluid flow path;

a flow control valve disposed in the fluid flow path and configured to automatically throttle the flow of such pressurized refrigerant through the collection chamber to thereby enhance both (1) separation of some of the entrained lubricating oil from the pressurized refrigerant to provide the lubricating oil sample as a liquid lubricating oil, and (2) retention of the liquid lubricating oil sample within the collection chamber;

the collection chamber being configured to have dispensed therein a pH indicator to mix with such liquid oil sample to thereby form at the observation location a test liquid comprising a mixture of such liquid oil sample and such pH indicator, the collection chamber being sufficiently transparent at least at the observation location whereby visual observation of any color change which takes place in the test liquid may be observed from exteriorly of the test kit.

2. The test kit of claim 1 further comprising a collector body disposed within the collection chamber in the fluid flow path downstream of the flow control valve, the collector body being configured to collect thereon at least a portion of the liquid lubricating oil sample.

3. The test kit of claim 1 further comprising a filler body disposed within the collection chamber at the observation location and spaced from the interior wall of the collection chamber to thereby define between the interior wall and the filler body an annular well which is configured to receive such test liquid.

4. The test kit of claim 1 wherein such system access valve comprises a core pin which, when displaced, serves to open such system valve, and the flow control valve is disposed at the inlet end of the collection chamber and comprises a spring-loaded valve plunger which is configured to contact and displace such core pin when the inlet end of the collection chamber is placed over such system valve.

6. The test kit of claim 1 or claim 2 wherein the outlet-end opening is comprised of a plurality of gas vent holes formed in the outlet end.

7. The test kit of claim 6 wherein the collection chamber has a longitudinal axis and the outlet end is disposed at an acute angle to the longitudinal axis whereby to direct refrigerant discharged through the outlet end at a right angle direction relative to the longitudinal axis.

8. The test kit of claim 1 or claim 2 wherein the flow control valve comprises a mouth which is configured to engage such system access valve and a soft, resilient blow-back seal disposed in the mouth, the blow-back seal being sufficiently compressible and configured so as to accommodate both vertical movement and angular orientation of the test kit relative to the system access valve while establishing and maintaining a gas-tight seal between the test kit and the system access valve.

9. The test kit of claim 8 wherein the blow-back seal has a durometer Shore A hardness of from about 2 to about 12.

10. The test kit of claim 8 wherein the blow-back seal has a durometer Shore A hardness of from about 2.5 to about 5.

11. The test kit of claim 1 or claim 2 further comprising a pH indicator disposed within the collection chamber.

12. The test kit of claim 11 wherein the flow control valve is disposed at the inlet end of the collection chamber and the collector body is disposed between the flow control valve and the outlet end.

13. The test kit of claim 11 further comprising a frangible ampoule disposed within the collection chamber, which ampoule contains the pH indicator in liquid form, and wherein the collection chamber has a collapsible portion at least in the location thereof within which the ampoule is disposed, whereby the ampoule may be crushed by squeezing the collapsible portion of the collection chamber to release the pH indicator within the collection chamber.

14. The test kit of claim 1 or claim 2 wherein the collection chamber comprises a closeable access opening through which such pH indicator may be introduced into the collection chamber.

15. The test kit of claim 14 wherein the closeable access opening is closeable by a cap having therein a plurality of gas vent holes which gas vent holes serve as the outlet-end opening.

16. The test kit of claim 14 further comprising a storage receptacle disposed exteriorly of the collection chamber and such pH indicator comprises a quantity of a liquid pH indicator disposed within the storage receptacle, and wherein the storage receptacle is configured to enable deposition therefrom of the liquid pH indicator into the collection chamber.

17. The test kit of claim 1 or claim 2 wherein the flow control valve comprises a control member which is displaceable by the flow of such refrigerant through the flow control valve from a closed position which prevents flow through the valve to open positions which permit flow through the valve, the control member being operatively associated with a spring member which is configured to resist such displacement towards the open positions with a force which is proportional to the amount of such displacement towards the open positions, whereby the flow rate of such pressurized refrigerant through the flow control valve is attenuated.

18. The test kit of claim 17 wherein the flow control valve has a nose portion and the filler body is comprised of the nose portion and the control member.

19. The test kit of claim 17 wherein the control member is operatively associated with a coil spring which is compressed upon displacement of the control member towards the open positions whereby the spring force of the coil spring resists such displacement of the control member towards the open positions.

20. The test kit of claim 19 wherein the control member has a plate-like configuration and is so disposed in the flow path to deflect such pressurized refrigerant flowing through the flow control valve into a change of flow direction.

21. The test kit of claim 1, claim 2 or claim 5 wherein the pH indicator comprises a liquid pH indicator.

5. A method for separating lubricating oil from a pressurized refrigerant in which the lubricating oil is entrained, and testing the separated oil for acidity, the method comprising:

(a) introducing the pressurized refrigerant into a test kit comprising a collection chamber having an inlet-end opening at or adjacent to which a flow-throttling flow control valve is disposed, and an outlet-end opening, the test kit defining a fluid flow path for the pressurized refrigerant, the fluid flow path extending from the inlet-end opening to the outlet-end opening;

(b) flowing the pressurized refrigerant along the flow path and discharging the pressurized refrigerant from the outlet-end opening, and throttling the flow of the pressurized refrigerant through the test kit by flowing the pressurized refrigerant through the flow control valve, to thereby enhance retention within the collection chamber of a liquid lubricating oil sample disentrained from the pressurized refrigerant;

(c) contacting a pH indicator with the liquid lubricating oil sample to form a test liquid; and

(d) observing any color change taking place in the test liquid.

22. The method of claim 5 wherein the collection chamber is sufficiently transparent at least at an observation location thereof and further comprising the steps of:

(e) after step (b), positioning the collection chamber to both (1) cause the lubricating oil sample to drain by gravity to the observation location, and (2) to carry out step (c) by causing the pH indicator to also drain by gravity to the observation location.

23. The method of claim 5 or claim 22 wherein a collector body is disposed within the collection chamber downstream of the flow control valve and the method further comprises passing the pressurized refrigerant past the collector body to deposit at least some of the disentrained lubricating oil sample on the collector body.

24. The method of claim 5 or claim 22 wherein the pH indicator is a liquid pH indicator.

25. The method of claim 5 or claim 22 wherein the collection chamber has thereon a contact member adjacent the inlet-end opening, and employing the contact member to operate the core pin of a valve of a pressurized refrigerant system to discharge the pressurized refrigerant into the collection chamber.

26. The method of claim 25 further comprising employing the control valve as the contact member.