Ink-jet ink printing system and method

• US 9,738,102 B2
• Filed: 09/03/2009
• Issued: 08/22/2017
• Est. Priority Date: 09/03/2009
• Status: Active Grant

• Current Assignee: Hewlett-Packard Development Company, L.P. (HP Inc.)
• Original Assignee: Hewlett-Packard Development Company, L.P. (HP Inc.)
• Inventors: Ganapathiappan, Sivapackia, Tom, Howard S., Ng, Hou T.
• Primary Examiner(s): Shah, Manish S
• Application Number:
  US13/383,691
• Publication Number:
  US 20120147108A1
• Time in Patent Office: 2,910 Days
• Field of Search: 347100, 347102, 347 95, 347 96, 347101, 347 20, 347 21, 347 88, 347 99, 106 316, 106 3127, 106 3113, 523160, 523161
• CPC Class Codes: B41J 11/002 Curing or drying the ink on the copy materials, e.g. by heating or irradiating
• CPC Class Codes: B41J 2/2107 characterised by the ink properties supplying ink in a solid state B41J2/17593
• CPC Class Codes: B41M 5/0047 by ink-jet printing
• CPC Class Codes: B41M 5/0064 on plastics, horn, rubber, or other organic polymers
• CPC Class Codes: B41M 7/0027 using protective coatings or layers by lamination or by fusion of the coatings or layers
• CPC Class Codes: B41M 7/009 using thermal means, e.g. infrared radiation, heat
• CPC Class Codes: C09D 11/033 characterised by the solvent
• CPC Class Codes: C09D 11/322 Pigment inks

Abstract

An ink-jet ink printing method and associated system can have a printer including an ink-jet ink. The ink includes an aqueous liquid vehicle, 1 wt % to 5 wt % pigment, 1 wt % to 5 wt % acrylic polymer particles, 0.3 wt % to 3 wt % urethane polymer particles, and is formulated to print on a vinyl medium. The system also includes a heating device. Upon applying heat to the ink-jet ink printed on the vinyl medium, the polymer particles in the printed ink fuse, and form a film encapsulating at least a portion of the pigment on the vinyl print medium.

Claims

1. An ink-jet ink printing system, comprising:

an ink-jet printer;

at least one ink-jet ink loaded in the ink-jet printer, the ink-jet ink comprising an aqueous liquid vehicle, a pigment present at from about 1 wt % to about 5 wt %, acrylic polymer particles present at from about 1 wt % to about 5 wt %, and urethane polymer particles present at from about 0.3 wt % to about 3 wt %, said ink-jet ink formulated to print on a vinyl medium; and

a heating device adapted to apply heat to the ink-jet ink after printing on the vinyl medium,

wherein upon applying the heat from the heating device to the ink-jet ink after printing on the vinyl medium, the acrylic polymer particles and urethane polymer particles fuse, thereby forming a printed image with a film encapsulating at least a portion of the pigment on the vinyl medium.

2. The system of claim 1, wherein the acrylic polymer particles and the urethane polymer particles comprise a total polymer particles content, wherein the pigment to total polymer particles content weight ratio is about 1:

1 to about 1;

2, said polymer particles having an acrylic polymer particles to urethane polymer particles weight ratio of about 1;

0.2 to about 1;

1.

3. The system of claim 2, wherein the acrylic polymer particles to urethane polymer particles weight ratio is about 1.3:

0.3 to about 1;

0.5.

4. The system of claim 1, wherein the acrylic polymer particles comprise at least one polymerized hydrophobic monomer selected from the group consisting of:

methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, hexyl acrylate, lauryl acrylate, octadecyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate, hexyl methacrylate, lauryl methacrylate, octadecyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, methylstyrene, vinylbenzyl chloride, acrylonitrile, methacrylonitrile, styrene, and combinations thereof.

5. The system of claim 4, wherein the acrylic polymer particles comprise a copolymer of at least two of styrene, butyl acrylate, and methacrylonitrile.

6. The system of claim 1, wherein the acrylic polymer particles comprise from 0.1 wt % to about 30 wt % polymerized acidic monomer.

7. The system of claim 6, wherein the polymerized acidic monomer is selected from the group of acrylic acid, methacrylic acid, itaconic acid, maleic acid, vinyl benzoic acid, styrenesulfonates, and combinations thereof.

8. The system of claim 1, wherein the acrylic polymer particles comprise a crosslinker in an amount of up to about 25 wt % of the acrylic polymer particles.

9. The system of claim 8, wherein the crosslinker is selected from the group consisting of:

ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, ethylene glycol diacrylate, diethylene glycol diacrylate, 1,6-hexanediol diacrylate, tetraethylene glycol diacrylate, tripropylene glycol diacrylate, ethoxylated bisphenol A diacrylate, pentaerythritol triacrylate, pentaerythritol tetraacrylate, N,N′

-methylenebisacrylamide, divinylbenzene, and combinations thereof.

10. The system of claim 1, wherein the heat from the heating device at which the acrylic polymer particles and urethane polymer particles fuse is from 50-100°

C.

11. The system of claim 1, wherein the liquid vehicle further includes at least one organic co-solvent that evaporates more quickly than water upon application of heat from the heating device.

12. The system of claim 1, wherein the printed image has increased rubfastness compared to a comparative printed image, said comparative printed image being prepared identically to the printed image except that in the ink-jet ink used to generate the comparative printed image, the urethane polymer particles are replaced by an equal amount of acrylic polymer particles.

13. The system of claim 1, wherein the system further comprises the vinyl medium.

14. The system of claim 13, wherein upon applying the heat from the heating device, at least a portion of the aqueous liquid vehicle evaporates, the vinyl medium plasticizes, and the ink-jet ink flows.

15. A method of forming in a printed image with the system of claim 1, comprising:

a) jetting the ink-jet ink onto the vinyl medium to form the printed image; and

b) applying about 50°

C. to 100°

C. heat to the printed image to cause the acrylic polymer particles and urethane polymer particles to fuse, thereby forming a film that encapsulates at least a portion of the pigment on the vinyl medium.

16. The method of claim 15, wherein the ink-jet ink is jetted onto the vinyl medium at a temperature within 10°

C. below the temperature of the heat applied to the printed image.