Charge control of a metal-air battery

• US 9,742,211 B2
• Filed: 07/22/2015
• Issued: 08/22/2017
• Est. Priority Date: 07/23/2014
• Status: Active Grant

• Current Assignee: Electricitã© De France
• Original Assignee: Electricitã© De France
• Inventors: Stevens, Philippe, Lhermenault, Julien, Toussaint, Gwenaelle
• Primary Examiner(s): Rodas, Richard Isla
• Assistant Examiner(s): Henze-Gongola, David V
• Application Number:
  US15/328,156
• Publication Number:
  US 20170214265A1
• Time in Patent Office: 762 Days
• Field of Search: 429402-407, 320128, 320134, 320164
• CPC Class Codes: H01M 10/44 Methods for charging or discharging circuits for charging H02J7/00
• CPC Class Codes: H01M 12/08 composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
• CPC Class Codes: H02J 7/0013 acting upon several batteries simultaneously or sequentially H02J7/1423 takes precedence
• CPC Class Codes: H02J 7/00304 Overcurrent protection
• CPC Class Codes: H02J 7/0068 Battery or charger load switching, e.g. concurrent charging and load supply H02J7/0013 takes precedence
• CPC Class Codes: H02J 7/0069 Charging or discharging for charge maintenance, battery initiation or rejuvenation
• CPC Class Codes: H02J 7/007 Regulation of charging or discharging current or voltage
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A method for managing the charge of a metal-air battery comprising at least one cell. The cell comprises a negative electrode, a first positive air electrode and a second positive oxygen-release electrode. For each cell, during the application of a charge current circulating in the cell between the negative electrode and the second positive oxygen-release electrode, the absolute value of a potential of the negative electrode is compared with a critical threshold value, the potential of the negative electrode being determined relative to the first positive air electrode. When the absolute value of the potential of the negative electrode reaches the threshold value, a surplus charging current, depending on the difference between the current applied to the cell and the charging current, is diverted.

Claims

1. A method for managing charge of a metal-air battery comprising at least one cell, the at least one cell comprising at least a negative electrode, a first positive air electrode, and a second positive oxygen-release electrode, the method comprising, for each cell, during application of a current to the at least one cell that results, during charging, in the flow of charging current between the negative electrode and the second positive oxygen-release electrode:

comparing an absolute value of a potential of the negative electrode to a critical threshold value, the potential of the negative electrode being determined relative to the first positive air electrode;

when the absolute value of the potential of the negative electrode reaches the critical threshold value, diverting an excess charging current that is a function of a difference between a current applied to the at least one cell and the charging current.

2. The method of claim 1, wherein the excess charging current of the at least one cell is diverted to a neighboring cell or to a charger.

3. The method of claim 1, wherein, for each cell, the critical threshold value is set based on the potential of the negative electrode when charging begins.

4. The method of claim 1, wherein the critical threshold value is re-evaluated at regular time intervals.

5. The method of claim 1, wherein an analog circuit comprising a component of variable impedance is provided, the diverting of excess charging current being implemented by modifying impedance of said component of variable impedance.

6. The method of claim 5, wherein the impedance of the component of variable impedance varies at least as a function of a quantity representative of a difference between the potential of the negative electrode and said critical threshold value, in order to deliver said excess charging current as output from the component of variable impedance.

7. The method of claim 1, wherein measurement of the potential of the negative electrode comprises voltage stabilization filtering between the negative electrode and the first air electrode.

8. A charge manager for a cell of a metal-air battery comprising at least one cell, the cell comprising at least a negative electrode, a first positive air electrode, and a second positive oxygen-release electrode, the charge manager comprising an electronic circuit for each cell, arranged so as to, during application of a current to the cell that results, during charging, in the flow of charging current between the negative electrode and the second positive oxygen-release electrode:

comparing an absolute value of a potential of the negative electrode to a critical threshold value, the potential of the negative electrode being determined relative to the first positive air electrode;

when the absolute value of the potential of the negative electrode reaches the threshold value, diverting an excess charging current that is a function of difference between current applied to the cell and the charging current.

9. The charge manager of claim 8, wherein the electronic circuit diverts the excess charging current to a neighboring cell or to a charger, via a respective connection to said neighboring cell or charger.

10. The charge manager of claim 8, wherein the electronic circuit comprises a component of variable impedance, the diverting of the excess charging current being implemented by changing the impedance of said component of variable impedance.

11. The charge manager of claim 10, wherein the component of variable impedance is a power transistor.

12. The charge manager of claim 11, wherein the power transistor is a Darlington transistor.

13. The charge manager of claim 9, further comprising an electronic circuit for measuring the difference in potential between the negative electrode and the first positive air electrode.

14. The charge manager of claim 13, wherein the electronic measurement circuit comprises a voltage stabilization filter.

15. A battery comprising at least one cell, the at least one cell comprising at least a negative electrode, a first positive air electrode, a second positive oxygen-release electrode, and the charge manager of claim 8.