Spectrophotometer and spectrophotometric measurement method

• US 9,746,374 B2
• Filed: 02/26/2014
• Issued: 08/29/2017
• Est. Priority Date: 02/28/2013
• Status: Active Grant

• Current Assignee: Otsuka Electronics Co., Ltd. (Otsuka Holdings Company Limited)
• Original Assignee: Otsuka Electronics Co., Ltd. (Otsuka Holdings Company Limited)
• Inventors: Shiraiwa, Hisashi
• Primary Examiner(s): Lee, John
• Application Number:
  US14/424,442
• Publication Number:
  US 20150241276A1
• Time in Patent Office: 1,280 Days
• CPC Class Codes: G01J 1/44 Electric circuits for command of an exposure part G03B7/02
• CPC Class Codes: G01J 2001/4406 Plural ranges in circuit, e.g. switchable ranges; Adjusting sensitivity selecting gain values
• CPC Class Codes: G01J 2001/444 Compensating; Calibrating, e.g. dark current, temperature drift, noise reduction or baseline correction; Adjusting
• CPC Class Codes: G01J 2001/448 Array [CCD]
• CPC Class Codes: G01J 3/02 Details
• CPC Class Codes: G01J 3/0232 using shutters
• CPC Class Codes: G01J 3/0262 Constructional arrangements for removing stray light
• CPC Class Codes: G01J 3/0264 Electrical interface; User interface
• CPC Class Codes: G01J 3/2803 using photoelectric array detector
• CPC Class Codes: G01J 3/42 Absorption spectrometry; Double beam spectrometry; Flicker spectrometry; Reflection spectrometry beam switching arrangements G01J3/08

Abstract

A spectrophotometer includes a photodetection unit configured to convert received light into an electric signal to output the electric signal; a circuit unit including a plurality of gain amplifiers and a plurality of AD converters configured to amplify an output signal from the photodetection unit by a plurality of gains using the plurality of gain amplifiers and configured to convert the amplified output signals into digital signals using the plurality of AD converters to output the digital signals as a plurality of pieces of light amount data; a saturation determination unit configured to determine whether or not each of the plurality of pieces of light amount data from the circuit unit has been saturated; and a measurement result calculation unit configured to calculate, in accordance with a result of the determination by the saturation determination unit, a measurement result of the received light using a part or all of the plurality of pieces of light amount data.

Claims

1. A spectrophotometer, comprising:

a photodetection unit configured to convert received light into an electric signal to output the electric signal;

a circuit unit comprising a plurality of gain amplifiers and a plurality of AD converters configured to amplify an output signal from the photodetection unit by a plurality of gains using the plurality of gain amplifiers and configured to convert the amplified output signals into digital signals using the plurality of AD converters to output the digital signals as a plurality of pieces of light amount data;

a saturation determination unit configured to determine whether or not each of the plurality of pieces of light amount data from the circuit unit has been saturated; and

a measurement result calculation unit configured to calculate, in accordance with a result of the determination by the saturation determination unit, a measurement result of the received light using a part or all of the plurality of pieces of light amount data;

wherein the measurement result calculation unit calculates the measurement result of the received light by dividing a sum of a part or all of the plurality of pieces of light amount data except for the light amount data that is determined to have been saturated by the saturation determination unit by a sum of the plurality of gains corresponding to the cart or all of the plurality of pieces of light amount data.

2. The spectrophotometer according to claim 1, wherein the measurement result calculation unit calculates the measurement result of the received light based on a part or all of the plurality of pieces of light amount data except for light amount data that is determined to have been saturated by the saturation determination unit.

3. The spectrophotometer according to claim 1, wherein the saturation determination unit determines whether or not each of the plurality of pieces of light amount data has been saturated by light amount data corresponding to a largest gain value among the plurality of gains.

4. The spectrophotometer according to claim 1, wherein:

the circuit unit further comprises a plurality of zero-point adjustment circuits connected to the plurality of gain amplifiers; and

each of the plurality of zero-point adjustment circuits outputs, to each of the plurality of gain amplifiers, a signal obtained by reducing a dark current component from an input signal.

5. The spectrophotometer according to claim 1, wherein, in the circuit unit, a part or all of the plurality of gain amplifiers are connected in a stepwise manner.

6. The spectrophotometer according to claim 4 , wherein the circuit unit further comprises an amplifier including an input terminal connected to the photodetection unit and an output terminal connected to a pan or all of the plurality of zero-point adjustment circuits.

7. The spectrophotometer according to claim 1, further comprising:

a light amount data acquisition unit configured to acquire pieces of light amount data from the plurality of AD conveners; and

a stray light correction unit configured to correct the measurement result calculated by the measurement result calculation unit based on each of the pieces of light amount data.

8. The spectrophotometer according to claim 1, wherein the photodetection unit comprises a plurality of light receiving elements each configured to convert the received light into an electric signal, and outputs each of the electric signals corresponding to respective wavelength bands.

9. The spectrophotometer according to claim 1, wherein the plurality of gains are different from one another.

10. The spectrophotometer according to claim 1, wherein the plurality of gains are the same as one another.

12. The spectrophotometer according to claim 2, wherein the saturation determination unit determines whether or not each of the plurality of pieces of light amount data has been saturated by light amount data corresponding to a largest gain value among the plurality of gains.

13. The spectrophotometer according to claim 2, wherein:

the circuit unit further comprises a plurality of zero-point adjustment circuits connected to the plurality of gain amplifiers; and

each of the plurality of zero-point, adjustment circuits outputs, to each of the plurality of gain amplifiers, a signal obtained by reducing a dark current component from an input signal.

14. The spectrophotometer according to claim 1, wherein:

the circuit unit further comprises a plurality of zero-point adjustment circuits connected to the plurality of gain amplifiers; and

each of the plurality of zero-point adjustment circuits outputs, to each of the plurality of gain amplifiers, a signal obtained by reducing a dark current component from an input signal.

15. The spectrophotometer according to claim 3, wherein:

the circuit unit further comprises a plurality of zero-point adjustment circuits connected to the plurality of gain amplifiers; and

each of the plurality of zero-point adjustment circuits outputs, to each of the plurality of gain amplifiers, a signal obtained by reducing a dark current component from an input signal.

16. The spectrophotometer according to claim 2, wherein in the circuit unit, a part or all of the plurality of gain amplifiers are connected in a stepwise manner.

17. The spectrophotometer, according to claim 1, wherein, in the circuit unit, a part or all of the plurality of gain amplifiers are connected in a stepwise manner.

18. The spectrophotometer according to claim 3, wherein, in the circuit unit, a part or all of the plurality of gain amplifiers are connected in a stepwise manner.

11. A spectrophotometric measurement method, comprising:

converting received light into an electric signal to output the electric signal;

amplifying an output signal from a photodetection unit by a plurality of gains using a plurality of gain amplifiers, and converting the amplified output signals into digital signals using a plurality of AD converters to output the digital signals as a plurality of pieces of light amount data;

determining whether or not each of the plurality of pieces of light amount data has been saturated; and

calculating a measurement result of the received light using a part or all of the plurality of pieces of light amount data in accordance with a result of the determination;

wherein the measurement result calculation unit calculates the measurement result of the received light by dividing a sum of a part or all of the plurality of pieces of light amount data except for the light amount data that is determined to have been saturated by the saturation determination unit by a sum of the plurality of gains corresponding to the part or all of the plurality of pieces of light amount data.