Gel electrolytes and electrodes

• US 9,755,268 B2
• Filed: 03/25/2015
• Issued: 09/05/2017
• Est. Priority Date: 03/27/2014
• Status: Active Grant

• Current Assignee: Sion Power Corporation
• Original Assignee: BASF SE, Sion Power Corporation
• Inventors: Fleischmann, Sven, Bunte, Christine, Mikhaylik, Yuriy V., Viner, Veronika G.
• Primary Examiner(s): Godo, Olatunji
• Application Number:
  US14/668,102
• Publication Number:
  US 20150280277A1
• Time in Patent Office: 895 Days
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/0565 Polymeric materials, e.g. gel-type or solid-type
• CPC Class Codes: H01M 2300/0025 Organic electrolyte
• CPC Class Codes: H01M 2300/0085 Immobilising or gelification of electrolyte
• CPC Class Codes: H01M 4/136 Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
• CPC Class Codes: H01M 4/1397 of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
• CPC Class Codes: H01M 4/38 of elements or alloys
• CPC Class Codes: H01M 4/382 Lithium H01M4/405 takes precedence
• CPC Class Codes: H01M 4/622 being polymers
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

Gel electrolytes, especially gel electrolytes for electrochemical cells, are generally described. In some embodiments, the gel electrolyte layers comprise components a) to c). Component a) may be at least one layer of at least one polymer comprising polymerized units of: a1) at least one monomer containing an ethylenically unsaturated unit and an amido group and a2) at least one crosslinker. Component b) may be at least one conducting salt and component c) may be at least one solvent. Electrodes may comprise the components a), d) and e), wherein component a) may be at least one layer of at least one polymer as described herein. Component d) may be at least one electroactive layer and component e) may be at least one ceramic layer. Furthermore, electrochemical cells comprising component a) which may be at least one layer of at least one polymer as described herein, are also provided.

Claims

1. A gel electrolyte comprising components a) to c) with

a) at least one layer of at least one polymer comprising polymerized units of a1) and a2)

a1) at least one monomer containing i) an ethylenically unsaturated unit and ii) an amido group, wherein a carbon atom of the amido group is linked via a chemical bond to one of a carbon atom of the ethylenically unsaturated unit, and

a2) at least one crosslinker containing i) at least two ethylenically unsaturated units and ii) a spacer with at least two carbon atoms, wherein two of the ethylenically unsaturated units are linked together via the spacer;

b) at least one conducting salt;

c) at least one solvent,

wherein monomer a2) is selected from a compound as in formula (II)

2. The gel electrolyte according to claim 1, wherein the polymer additionally comprises polymerized units of a3):

a3) at least one further monomer containing an ethylenically unsaturated unit.

3. The gel electrolyte according to claim 2, wherein the monomer a3) is styrene, an anionic monomer selected from acrylic acid, methacrylic acid, itaconic acid or maleic acid, or a salt of said anionic monomer.

4. The gel electrolyte according to claim 1, wherein the monomer a1) is selected from a compound as in formula (I)

5. The gel electrolyte according to claim 4, wherein in the monomer a1) of the formula (I)

R¹ is —

(CHR⁴)_m—

O—

R⁵, —

(CHR⁶—

CHR⁷—

O)_m—

R⁵ or —

(CHR⁶—

CHR⁷—

O)_m—

(CHR⁸—

CHR⁹—

O)_m—

(CHR¹⁰—

CHR¹¹—

O)_o—

R⁵;

R² is H or C₁-C₅-alkyl;

R³, R⁴ and R⁶ to R¹¹ are each independently H or methyl;

R⁵ is C₁-C₅-alkyl;

m and n are each independently an integer from 1 to 10; and

o is an integer from 0 to 10.

6. The gel electrolyte according to claim 5, wherein

R¹ is —

(CH₂—

CH₂—

O)_m—

R⁵ or —

CH₂—

CHR⁷—

O—

(CH₂—

CHR⁹—

O)_m—

(CH₂—

CHR¹¹—

O)_o—

R⁵;

R² is H;

R³, R⁹ and R¹¹ are each independently H or methyl;

R⁵ C₁-C₅-alkyl; and

R⁷ is H or methyl;

m, n and o are each independently an integer from 2 to 8.

7. The gel electrolyte according to claim 1, wherein the conducting salt is a lithium salt.

8. The gel electrolyte according to claim 1, wherein the ratio of monomer a2) to monomer a1) is from 1:

1 to 1;

100 (% by weight/% by weight).

9. An electrochemical cell comprising a gel electrolyte according to claim 1.

10. The electrochemical cell according to claim 9, comprising a Li-anode or a sulfur cathode.

11. The electrochemical cell according to claim 10, wherein the electrode comprises at least one layer of at least one polymer according to component a).

12. The electrochemical cell according to claim 11, wherein the electrode further contains components d) and e) with

d) at least one electroactive layer;

e) at least one protective layer;

wherein the component a) is covered by i) component e) or ii) component d) and component e).

13. The electrochemical cell according to claim 12, wherein the protective layer comprises a ceramic layer.

14. The electrochemical cell according to claim 12, wherein the electrochemical cell is a Li/S battery.