Analytical system and method for detecting volatile organic compounds in water

• US 9,766,215 B2
• Filed: 09/07/2012
• Issued: 09/19/2017
• Est. Priority Date: 09/07/2011
• Status: Active Grant

• Current Assignee: Parker Intangibles LLC (Parker-Hannifin Corporation)
• Original Assignee: Parker-Hannifin Corporation
• Inventors: Cost, William M., Morse, John Arthur, Doutt, Michael L., Geis, Glenn Stacey, Hassan, Kazi Z. A.
• Primary Examiner(s): West, Paul
• Assistant Examiner(s): Shabman, Mark A
• Application Number:
  US14/343,138
• Publication Number:
  US 20150143872A1
• Time in Patent Office: 1,838 Days
• CPC Class Codes: G01N 1/10 in the liquid or fluent state burettes, pipettes B01L3/02; sampling of ground water E02D1/06; metering by volume of fluids or fluent solid material G01F11/00, G01F13/00
• CPC Class Codes: G01N 1/4055 by solubility techniques
• CPC Class Codes: G01N 2001/4066 using difference of solubility between liquid and gas, e.g. bubbling, scrubbing or sparging
• CPC Class Codes: G01N 2030/025 Gas chromatography
• CPC Class Codes: G01N 2291/021 Gases
• CPC Class Codes: G01N 29/022 Fluid sensors based on microsensors, e.g. quartz crystal-microbalance [QCM], surface acoustic wave [SAW] devices, tuning forks, cantilevers, flexural plate wave [FPW] devices microdevices per se B81B
• CPC Class Codes: G01N 30/76 Acoustical detectors measurement of mechanical vibrations or ultrasonic, sonic or infrasonic waves G01H

Abstract

An analytical system and method for detecting volatile organic chemicals in water including a coated SAW detector that provides for improved reduction of moisture at the coating of the SAW detector. A stabilized SAW sensitivity and long lasting calibration is achieved. The analytical system further includes an improved sample vessel and sparger that allow for easy grab sample analysis, while also providing efficient purging of the volatile organic compounds from the water sample. In addition, an improved preconcentrator provides a stabilized sorbent bed.

Claims

1. A system for detecting organic compounds in water including:

a surface acoustic wave detector configured to detect a mass of organic compounds separated by a gas chromatograph column, the surface acoustic wave detector having a sensing surface with a coating;

a vacuum pump for lowering pressure at the coating of the surface acoustic wave detector; and

a controller configured to control operation of the vacuum pump to lower pressure at the coating of the surface acoustic wave detector to remove moisture from the coating.

2. A system according to claim 1, wherein the controller is further configured to cause carrier gas to flow from a carrier gas supply across the coating of the surface acoustic wave detector while the pressure at the coating is lowered.

3. A system according to claim 1, wherein the pressure at the coating is lowered without flow of carrier gas across the coating of the surface acoustic wave detector.

4. A system according to claim 1, wherein the controller is configured to control operation of the vacuum pump to lower the pressure at the coating of the surface acoustic wave detector to about the vapor pressure of water.

5. A system according to claim 1, wherein the pressure at the coating is lowered without application of heat at the coating.

6. A system according to claim 1, wherein controller is configured to control the operation of the vacuum pump after execution of a gas chromatography process in which the surface acoustic wave detector detects the mass of the organic compounds.

7. A system according to claim 1, further including:

a sample vessel configured to contain a water sample from which the organic compounds are purged;

a preconcentrator configured to collect the organic compounds; and

a gas chromatograph column configured to separate the organic compounds as desorbed from the preconcentrator.

8. A system according to claim 7, wherein the controller is configured to control the operation of the vacuum pump after execution of a purging process in which the organic compounds are purged from the water sample and collected at the preconcentrator.

9. A method for detecting organic compounds in water including:

purging the organic compounds from a water sample contained in a sample vessel;

collecting the organic compounds with a preconcentrator;

desorbing the organic compounds from the preconcentrator;

separating the organic compounds as desorbed from the preconcentrator with a gas chromatograph column;

detecting the mass of organic compounds separated by a gas chromatograph column with the acoustic wave detector; and

lowering pressure at a coating of the surface acoustic wave detector to remove moisture from the coating.

10. A method according to claim 9, further including passing carrier gas across the coating of the surface acoustic wave detector while the pressure at the coating is lowered.

11. A method according to claim 9, wherein the pressure at the coating is lowered without passing carrier gas across the coating of the surface acoustic wave detector.

12. A method according to claim 9, wherein the pressure at the coating of the surface acoustic wave detector is lowered to about the vapor pressure of water.

13. A method according to claim 9, wherein the pressure at the coating is lowered without application of heat at the coating.

14. A method according to claim 9, wherein the pressure is lowered at the coating of the surface acoustic wave detector to remove moisture from the coating after the step of detecting the mass of the organic compounds.

15. A method according to claim 9, wherein the pressure is lowered at the coating of the surface acoustic wave detector to remove moisture from the coating during at least one of purging the organic compounds from the water sample or collecting the organic compounds with the preconcentrator.