Configurations and methods of high pressure acid gas removal in the production of ultra-low sulfur gas

• US 9,776,124 B2
• Filed: 03/04/2016
• Issued: 10/03/2017
• Est. Priority Date: 02/17/2010
• Status: Active Grant

• Current Assignee: Fluor Technologies Corporation (Fluor Corporation)
• Original Assignee: Fluor Technologies Corporation (Fluor Corporation)
• Inventors: Mak, John
• Primary Examiner(s): Orlando, Amber R
• Assistant Examiner(s): SHAO, PHILLIP Y
• Application Number:
  US15/061,421
• Publication Number:
  US 20160184767A1
• Time in Patent Office: 578 Days
• Field of Search: None
• CPC Class Codes: B01D 2252/202 Alcohols or their derivatives
• CPC Class Codes: B01D 2252/2021 Methanol
• CPC Class Codes: B01D 2252/2023 Glycols, diols or their derivatives
• CPC Class Codes: B01D 2252/2025 Ethers or esters of alkylene glycols, e.g. ethylene or propylene carbonate
• CPC Class Codes: B01D 2252/20431 Tertiary amines
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1462 Removing mixtures of hydrogen sulfide and carbon dioxide
• CPC Class Codes: B01D 53/18 Absorbing units; Liquid distributors therefor B01D3/16, B01D3/26, B01D3/30 take precedence; packing elements B01J19/30, B01J19/32
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

Acid gas is removed from a high pressure feed gas that contains significant quantities of CO2 and H2S. In especially preferred configurations and methods, feed gas is contacted in an absorber with a lean and an ultra-lean solvent that are formed by flashing rich solvent and stripping a portion of the lean solvent, respectively. Most preferably, the flash vapors and the stripping overhead vapors are recycled to the feed gas/absorber, and the treated feed gas has a CO2 concentration of less than 2 mol % and a H2S concentration of less than 10 ppmv, and more typically less than 4 ppmv.

Claims

1. A method of treating a rich physical solvent, comprising:

producing the rich solvent in an absorber, wherein the absorber receives a feed gas and produces a treated gas;

flashing the rich solvent in multiple successive stages from a first pressure to a second pressure to generate a hydrocarbon-containing flash gas and a flashed solvent, wherein flashing the rich solvent in the multiple successive stages occurs in a plurality of flash vessels, wherein the rich solvent passes through the multiple successive stages in series;

heating and further flashing the flashed solvent from the second pressure to a third pressure to generate a CO₂-containing flash gas and a lean solvent; and

stripping a first portion of the lean solvent in a stripping column using a portion of the treated gas as a stripping gas to produce a stripping column overhead product and an ultra-lean solvent; and

feeding a second portion of the lean solvent and the ultra-lean solvent into the absorber at different positions.

2. The method of claim 1, further comprising:

combining the hydrocarbon-containing flash gas and the stripping column overhead product.

3. The method of claim 1, wherein heating the flashed solvent comprises using heat content of at least one of an absorber feed gas or the lean solvent to heat the flashed solvent.

4. The method of claim 1, wherein the first pressure is at least about 1000 psig, the second pressure is at least about 75 psig, and the third pressure is equal or less than about 40 psig.

5. The method of claim 1, wherein the first portion of the lean solvent is between 20% and 50% of the lean solvent.

6. The method of claim 1 wherein the treated gas is fed to the feed gas or the absorber.

7. The method of claim 1, further comprising:

expanding the portion of the treated gas prior to using the portion of the treated gas to strip the first portion of the lean solvent in the striping column, wherein a refrigeration content from the expansion of the portion of the treated gas cools the ultra-lean physical solvent.

8. The method of claim 1, wherein heating and further flashing the flashed solvent from the second pressure to the third pressure to generate the CO₂-containing flash gas uses a heat content of a feed gas.

9. The method of claim 8, wherein the feed gas has a CO₂ content of at least 20 mol % and an H₂S content of at least 0.1 mol %, and wherein the treated gas has an H₂S content of equal or less than 4 ppmv.

10. The method of claim 1, wherein the absorber is operated at a pressure of at least 500 psig.

11. A method of treating a rich physical solvent, comprising:

flashing the rich solvent in multiple successive stages from a first pressure to a second pressure to generate a hydrocarbon-containing flash gas and a flashed solvent, wherein flashing the rich solvent in the multiple successive stages occurs in a plurality of flash vessels, wherein the rich solvent passes through the multiple successive stages in series;

heating and further flashing the flashed solvent from the second pressure to a third pressure to generate a CO₂-containing flash gas and a lean solvent; and

stripping a portion of the lean solvent in a stripping column to produce a stripping column overhead product and an ultra-lean solvent;

feeding the lean solvent and the ultra-lean solvent into an absorber at different positions, wherein feeding the lean solvent and the ultra-lean solvent into an absorber at different positions produces a treated gas;

feeding a portion of the treated gas to the stripping column;

expanding the portion of the treated gas prior to feeding the portion of the treated gas to the stripping column, wherein a refrigeration content from the expansion of the portion of the treated gas cools the ultra-lean physical solvent.

12. The method of claim 11, further comprising:

combining the hydrocarbon-containing flash gas and the stripping column overhead product.

13. The method of claim 11, wherein heating the flashed solvent comprises using heat content of at least one of an absorber feed gas or the lean solvent to heat the flashed solvent.

14. The method of claim 11, wherein the first pressure is at least about 1000 psig, the second pressure is at least about 75 psig, and the third pressure is equal or less than about 40 psig.

15. The method of claim 11, wherein stripping the portion of the lean solvent is performed using treated feed gas from an absorber as a stripping gas.

16. The method of claim 11, wherein the portion of the lean solvent is between 20% and 50% of the lean solvent.

17. The method of claim 11, wherein heating and further flashing the flashed solvent from the second pressure to the third pressure to generate the CO₂-containing flash gas uses a heat content of a feed gas.

18. The method of claim 17, wherein the feed gas has a CO₂ content of at least 20 mol % and an H₂S content of at least 0.1 mol %, and wherein the treated gas has an H₂S content of equal or less than 4 ppmv.

19. The method of claim 11, further comprising:

chilling a feed gas to the absorber to a temperature sufficient to condense C5+ hydrocarbons from the feed gas; and

separating the condensed C5+ hydrocarbons from the feed gas prior to introducing the feed gas to the absorber.

20. The method of claim 11, wherein the absorber is operated at a pressure of at least 500 psig.