Submerged combustion glass manufacturing system and method

• US 9,776,901 B2
• Filed: 07/30/2015
• Issued: 10/03/2017
• Est. Priority Date: 10/07/2011
• Status: Active Grant

• Current Assignee: Johns Manville Corporation (Berkshire Hathaway Incorporated)
• Original Assignee: Johns Manville Corporation (Berkshire Hathaway Incorporated)
• Inventors: Huber, Aaron Morgan, Martin, Marlon Keith
• Primary Examiner(s): Szewczyk, Cynthia
• Application Number:
  US14/813,531
• Publication Number:
  US 20150344343A1
• Time in Patent Office: 796 Days
• CPC Class Codes: C03B 2211/22 by direct combustion in the melt
• CPC Class Codes: C03B 2211/23 using oxygen, i.e. pure oxygen or oxygen-enriched air
• CPC Class Codes: C03B 2211/40 using oxy-fuel burners
• CPC Class Codes: C03B 5/167 Means for preventing damage to equipment, e.g. by molten glass, hot gases, batches C03B5/20, C03B5/42 take precedence
• CPC Class Codes: C03B 5/183 using thermal means, e.g. for creating convection currents
• CPC Class Codes: C03B 5/193 using gas, e.g. bubblers
• CPC Class Codes: C03B 5/2353 by combustion with pure oxygen or oxygen-enriched air, e.g. using oxy-fuel burners or oxygen lances
• CPC Class Codes: C03B 5/2356 Submerged heating, e.g. by using heat pipes, hot gas or submerged combustion burners bubblers C03B5/193
• CPC Class Codes: C03B 5/237 Regenerators or recuperators specially adapted for glass-melting furnaces

Abstract

Submerged combustion glass manufacturing systems include a melter having a floor, a roof, a wall structure connecting the floor and roof, and an exhaust passage through the roof. One or more submerged combustion burners are mounted in the floor and/or wall structure discharging combustion products under a level of material being melted in the melter and create turbulent conditions in the material. The melter exhausts through an exhaust structure connecting the exhaust passage with an exhaust stack. The exhaust structure includes a barrier defining an exhaust chamber having an interior surface, the exhaust chamber having a cross-sectional area greater than that of the exhaust stack but less than the melter. The barrier maintains temperature and pressure in the exhaust structure at values sufficient to substantially prevent condensation of exhaust material on the interior surface.

Claims

1. A submerged combustion glass manufacturing system comprising:

a melter comprising a floor, a roof, a wall structure connecting the floor and roof, an exhaust passage through the roof, and at least one baffle plate extending from the roof and configured to extend at least partially between the exhaust passage and material being melted in the melter;

one or more submerged combustion burners mounted in the floor and/or wall structure, the submerged combustion burners configured to discharge combustion products under a level of material being melted in the melter and create turbulent conditions in substantially all of the material; and

an exhaust structure fluidly connecting only the exhaust passage with an exhaust stack, the exhaust structure comprising a barrier preventing exhaust material from contacting the atmosphere, the barrier defining an exhaust chamber having an interior surface, the exhaust chamber having a cross-sectional area greater than that of the exhaust stack but less than the melter, the barrier configured to maintain temperature and pressure in the exhaust structure at values sufficient to substantially prevent condensation of exhaust material on the interior surface.

2. The system of claim 1 comprising a feed inlet in a feed end of the wall structure, a molten glass outlet in an exit end of the wall structure, wherein the exhaust passage through the roof is positioned substantially centrally between the feed and exit ends.

3. The system of claim 1 wherein the submerged combustion burners are configured to discharge combustion products primarily non-laterally under the level of material being melted in the melter.

4. The system of claim 1 wherein the submerged combustion burners are configured to discharge combustion products primarily vertically under the level of material being melted in the melter.

5. The system of claim 1 wherein the wall structure comprises a feed end wall, an exit end wall, and two side walls, with each side wall connected to both the feed end wall and the exit end wall.

6. The system of claim 1 wherein the barrier of the exhaust structure is constructed of materials selected from the group consisting of refractory, metal, and combinations thereof, with the proviso that if metal, the service temperature of the metal is higher than the temperature of the exhaust materials.

7. The system of claim 1 comprising a fluid-cooled transition structure fluidly connecting the exhaust passage and the exhaust structure.

8. The system of claim 7 wherein the fluid is a liquid selected from the group consisting of water, organic liquids, inorganic liquids, and combinations thereof.

9. The system of claim 1 comprising an air inspirator fluidly connecting the barrier and the exhaust stack.

10. The system of claim 9 wherein the air inspirator is selected from the group consisting of one or more adjustable panels, and one or more adjustable hoods.

11. The system of claim 1 wherein the exhaust structure has a cross-sectional shape selected from the group consisting of rectangular, round, oval, trapezoidal, triangular, U-shaped, quadrangular, hexagonal, octagonal, parabolic.

12. The system of claim 1 wherein the barrier of the exhaust structure comprises a refractory lined metal layer wherein the refractory comprises the interior surface of the barrier, the metal layer having one or more air-cooled surfaces.

13. The system of claim 12 wherein the metal layer is one or more austenitic nickel-chromium super alloys, and the air-cooled surfaces are steel.

14. A submerged combustion glass manufacturing system comprising:

a melter comprising a floor, a roof, a wall structure connecting the floor and roof, a feed inlet in a feed end, a molten glass outlet in an exit end, an exhaust passage through the roof positioned substantially centrally between the feed and exit ends, and at least one baffle plate extending from the roof and configured to extend at least partially between the exhaust passage and material being melted in the melter;

one or more submerged combustion burners mounted in the floor and/or wall structure, the submerged combustion burners configured to discharge combustion products under a level of material being melted in the melter and create turbulent conditions in substantially all of the material; and

an exhaust structure fluidly connecting only the exhaust passage with an exhaust stack, the exhaust structure comprising;

a barrier preventing exhaust material from contacting the atmosphere, the barrier defining an exhaust chamber having an interior surface, the exhaust chamber having a cross-sectional area greater than that of the exhaust stack but less than the melter, the barrier configured to maintain temperature and pressure in the exhaust structure at values sufficient to substantially prevent condensation of exhaust material on the interior surface;

a liquid-cooled transition structure fluidly connecting the exhaust passage and the exhaust structure; and

an air inspirator fluidly connecting the barrier and the exhaust stack.

15. The system of claim 14 wherein the liquid used in the liquid-cooled transition structure is selected from the group consisting of water, organic liquids, inorganic liquids, and combinations thereof.

16. The system of claim 14 wherein the exhaust structure has a cross-section selected from the group consisting of rectangular, round, oval, triangular, trapezoidal, U-shaped, quadrangular, hexagonal, octagonal, parabolic.

17. The system of claim 14 wherein the barrier of the exhaust structure comprises a refractory lined metal layer wherein the refractory comprises the interior surface of the barrier, the metal layer having air-cooled supports.

18. The system of claim 14 wherein the air inspirator is selected from the group consisting of one or more adjustable panels, and one or more adjustable hoods.

19. A submerged combustion glass manufacturing method comprising:

melting glass-forming materials in a submerged combustion melter, the melter comprising a floor, a roof, and a wall structure connecting the floor and roof, an exhaust passage through the roof, and at least one baffle plate extending from the roof and configured to extend at least partially between the exhaust passage and material being melted in the melter;

combusting a fuel in one or more submerged combustion burners mounted in the floor and/or wall structure, the submerged combustion burners discharging combustion products under a level of the glass-forming material being melted in the melter and creating turbulent conditions in substantially all of the material; and

exhausting exhaust material from the melter through an exhaust structure fluidly connecting only the exhaust passage with an exhaust stack, the exhaust structure comprising a barrier preventing the exhaust material from contacting the atmosphere, the barrier defining an exhaust chamber having an interior surface, the barrier configured to maintain temperature and pressure in the exhaust structure at values sufficient to substantially prevent the exhaust material from condensing on the interior surface.

20. The method of claim 19 wherein the exhaust passage is substantially centrally located between a feed end and an exit end of the melter, and the exhausting of the exhaust material through the exhaust structure comprises exhausting the exhaust material substantially centrally between the feed end and the exit end of the melter.

21. The method of claim 19 comprising cooling the exhaust material prior to the exhaust chamber by flowing the exhaust material through a liquid-cooled transition structure fluidly connecting the exhaust passage and the barrier.

22. The method of claim 19 comprising inspiring air into the exhaust material through an air inspirator fluidly connecting the barrier and the exhaust stack.

23. The method of claim 22 comprising adjusting the air inspirator to allow more or less air to enter the stack.

24. A submerged combustion method of manufacturing glass comprising:

melting glass-forming materials in a submerged combustion melter, the melter comprising a floor, a roof, and a wall structure connecting the floor and roof, an exhaust passage through the roof, and at least one baffle plate extending from the roof and configured to extend at least partially between the exhaust passage and material being melted in the melter;

combusting a fuel in one or more submerged combustion burners mounted in the floor and/or wall structure, the submerged combustion burners discharging combustion products under a level of the glass-forming material being melted in the melter and creating turbulent conditions in substantially all of the material; and

exhausting exhaust material from the melter through an exhaust structure fluidly connecting only the exhaust passage with an exhaust stack, wherein the exhaust passage is substantially centrally located between a feed end and an exit end of the melter, and the exhausting of the exhaust material through the exhaust structure comprises exhausting the exhaust material substantially centrally between the feed end and the exit end of the melter, wherein the exhaust structure comprises;

a barrier preventing the exhaust material from contacting the atmosphere, the barrier defining an exhaust chamber having an interior surface, the barrier configured to maintain temperature and pressure in the exhaust structure at values sufficient to substantially prevent the exhaust material from condensing on the interior surface;

a liquid-cooled transition structure fluidly connecting the exhaust passage and the exhaust structure; and

an air inspirator fluidly connecting the barrier and the exhaust stack.

25. A submerged combustion glass manufacturing system comprising:

a melter comprising a floor, a roof, a wall structure connecting the floor and roof, at least one exhaust passage through the roof, and at least one baffle plate extending from the roof and configured to extend at least partially between the exhaust passage and material being melted in the melter;

one or more submerged combustion burners mounted in the floor and/or wall structure, the submerged combustion burners configured to discharge combustion products under a level of material being melted in the melter and create turbulent conditions in substantially all of the material; and

at least one exhaust structure fluidly connecting only the at least one exhaust passage with at least one exhaust stack, each of the at least one exhaust structures comprising a respective barrier preventing exhaust material from contacting the atmosphere, each of the barriers defining respective exhaust chambers each having a respective interior surface, each of the exhaust chambers having cross-sectional area greater than that of any of the exhaust stacks to which it is attached but less than the melter, each of the barriers configured to maintain temperature and pressure in the exhaust structures at values sufficient to substantially prevent condensation of exhaust material on the interior surface.