NGL recovery from natural gas using a mixed refrigerant

• US 9,777,960 B2
• Filed: 12/01/2011
• Issued: 10/03/2017
• Est. Priority Date: 12/01/2010
• Status: Active Grant

• Current Assignee: Black & Veatch International Company (Black & Veatch Corporation)
• Original Assignee: Black & Veatch International Company (Black & Veatch Corporation)
• Inventors: Currence, Kevin L., Mortko, Robert A.
• Primary Examiner(s): Pettitt, John F
• Application Number:
  US13/308,982
• Publication Number:
  US 20120137726A1
• Time in Patent Office: 2,133 Days
• Field of Search: 62611, 62613, 62614, 62616, 62617, 62618, 62619, 62620, 62625, 62630, 62632
• CPC Class Codes: F25J 2200/02 in a single pressure main column system
• CPC Class Codes: F25J 2200/72 Refluxing the column with at least a part of the totally condensed overhead gas
• CPC Class Codes: F25J 2200/74 Refluxing the column with at least a part of the partially condensed overhead gas
• CPC Class Codes: F25J 2205/04 in the feed line, i.e. upstream of the fractionation step
• CPC Class Codes: F25J 2210/12 Refinery or petrochemical off-gas
• CPC Class Codes: F25J 2230/30 Compression of the feed stream
• CPC Class Codes: F25J 2245/02 Recycle of a stream in general, e.g. a by-pass stream
• CPC Class Codes: F25J 2270/04 Internal refrigeration with work-producing gas expansion loop
• CPC Class Codes: F25J 2270/12 External refrigeration with liquid vaporising loop
• CPC Class Codes: F25J 2270/66 Closed external refrigeration cycle with multi component refrigerant [MCR], e.g. mixture of hydrocarbons
• CPC Class Codes: F25J 3/0209 Natural gas or substitute natural gas
• CPC Class Codes: F25J 3/0219 Refinery gas, cracking gas, coke oven gas, gaseous mixtures containing aliphatic unsaturated CnHm or gaseous mixtures of undefined nature
• CPC Class Codes: F25J 3/0233 separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 separation of CnHm with 2 carbon atoms or more
• CPC Class Codes: F25J 3/0242 separation of CnHm with 3 carbon atoms or more

Abstract

An NGL recovery facility utilizing a single, closed-loop mixed refrigerant cycle for recovering a substantial portion of the C₂ and heavier or C₃ and heavier NGL components from the incoming gas stream. Less severe operating conditions, including a warmer refrigerant temperature and a lower feed gas pressure, contribute to a more economical and efficient NGL recovery system.

Claims

1. A process for recovering a natural gas liquids (NGL) stream from a feed gas stream, said process comprising:

(a) cooling and at least partially condensing said feed gas stream from which said NGL stream is to be recovered via indirect heat exchange with a mixed refrigerant stream in a primary heat exchanger of a single, closed-loop mixed refrigeration cycle to thereby provide a cooled feed gas stream, all constituents of said NGL stream being contained within said feed gas stream;

(b) introducing the entire cooled feed gas stream into a first vapor-liquid separation vessel;

(c) separating said cooled feed gas stream introduced into said first vapor-liquid separation vessel into a first residue gas stream enriched in methane and lighter components and a first liquid product stream enriched in C₂ and heavier components and withdrawing each of said first residue gas stream and said first liquid product stream from said first vapor-liquid separation vessel;

(d) dividing said first liquid product stream into a first liquid portion and a second liquid portion each having the same composition as said first liquid product stream;

(e) introducing said second liquid portion into a second vapor-liquid separation vessel;

(f) separating said second liquid portion into a second residue gas stream and a second liquid product stream in said second vapor-liquid separation vessel and withdrawing each of said second residue gas stream and said second liquid product stream from said second vapor-liquid separation vessel;

(g) condensing said second residue gas steam that is withdrawn from said second vapor-liquid separation vessel to form a two-phase fluid stream;

(h) separating said two-phase fluid stream in a third vapor-liquid separator to form a liquid reflux stream and a second residue gas vapor stream and combining at least a portion of said liquid reflux stream with said first liquid portion to provide a combined liquid stream;

(i) introducing said combined liquid stream into an upper portion of said first vapor-liquid separation vessel;

(j) recovering at least a portion of said second liquid product stream withdrawn from said second vapor-liquid separation vessel in step (h) as said NGL stream;

(k) combining the entire first residue gas stream and at least a portion of said second residue gas vapor stream withdrawn from said third vapor-liquid separation vessel to form a combined residue gas stream that comprises said entire first residue gas stream and said at least a portion of said second residue gas vapor stream withdrawn from said third vapor-liquid separation vessel; and

(l) heating said combined residue gas stream to thereby provide a heated residue gas stream, wherein at least a portion of said heating is carried out in said primary heat exchanger to provide at least a portion of said cooling of step (a).

2. The process of claim 1, wherein said feed gas stream has a pressure less than 600 psig prior to said cooling of step (a).

3. The process of claim 1, wherein said cooled feed gas stream has a temperature of no less than −

165°

F. prior to said separating of step (c).

4. The process of claim 1, wherein the temperature of said mixed refrigerant stream has a temperature of not less than −

175°

F. prior to said cooling of step (a).

5. The process of claim 1, further comprising, compressing a stream of mixed refrigerant to thereby provide a compressed mixed refrigerant stream;

cooling said compressed mixed refrigerant stream to thereby provide a cooled mixed refrigerant stream; and

expanding said cooled mixed refrigerant stream to thereby provide an expanded mixed refrigerant stream, wherein said mixed refrigerant stream utilized to perform said cooling of step (a) comprises at least a portion of said expanded mixed refrigerant stream.

6. The process of claim 5, wherein the pressure of said compressed mixed refrigerant stream is no more than 550 psig.

7. The process of claim 1, further comprising expanding at least a portion of said heated residue gas stream to thereby provide an expanded heated residue gas stream and further heating said expanded heated residue gas stream to provide a further heated residue gas stream.

8. The process of claim 7, wherein said first residue gas stream comprises at least about 80 percent of the total amount of methane and lighter components originally present in said feed gas stream prior to said cooling of step (a) and wherein said further heated residue gas stream has a vapor fraction greater than 0.85.

9. The process of claim 1, wherein said NGL stream comprises at least 80 percent of the total amount of C₃ and heavier components originally present in said feed gas stream prior to said cooling of step (a) and wherein said NGL stream comprises less than 20 mole percent of C₂ and lighter components.

10. The process of claim 1, wherein said NGL stream comprises at least 50 percent of the total amount of C₂ and heavier components originally present in said feed gas stream prior to said cooling of step (a).

11. The process of claim 1, wherein said mixed refrigerant comprises two or more components selected from the group consisting of methane, ethylene, ethane, propylene, propane, isobutane, n-butane, isopentane, and n-pentane.

12. The process of claim 1, wherein said recovering of step (j) comprises subjecting said NGL stream to further fractionation in one or more distillation columns to thereby produce one or more additional product streams enriched in C₂, C₃, and/or C₄ and heavier components.

13. A natural gas liquids (NGL) recovery facility for recovering a stream of ethane and heavier components from a hydrocarbon-containing feed gas stream using a single closed-loop mixed refrigeration cycle, said facility comprising:

a feed gas compressor defining a feed suction port and a feed discharge port, said feed gas compressor compressing said hydrocarbon-containing feed gas stream and delivering a compressed feed gas stream at a pressure of not more than 600 prig;

a primary heat exchanger defining a first cooling pass, through which the compressed feed gas stream is directed, wherein said first cooling pass cools the compressed feed gas stream to provide a cooled feed gas stream that includes all constituents of said stream of ethane and heavier components;

a first vapor-liquid separation vessel defining a first fluid inlet, a first upper vapor outlet, and a first lower liquid outlet, wherein said first fluid inlet is coupled in fluid flow communication with said first cooling pass, wherein said first vapor-liquid separation vessel separates the entire cooled feed gas stream into a first residue gas stream withdrawn via said first upper vapor outlet and a first liquid stream withdrawn via said first lower liquid outlet;

a dividing conduit to divide said first liquid stream withdrawn from said first vapor-liquid separation vessel into a first liquid portion and a second liquid portion each having the same composition as said first liquid stream;

a second vapor-liquid separation vessel defining a second fluid inlet, a second upper vapor outlet, and a second lower liquid outlet, wherein said second fluid inlet is coupled in fluid flow communication with said dividing conduit and receives said second liquid portion of said first liquid stream, wherein said second-vapor liquid separation vessel separates said second liquid portion of said first liquid stream withdrawn from said first vapor-liquid separation vessel into a second residue gas stream withdrawn via said second upper vapor outlet and an NGL stream withdrawn via said second lower liquid outlet;

a condenser having an inlet and an outlet, wherein said condenser is configured to cool and partially condense said second residue gas stream withdrawn from said second upper vapor outlet of said second vapor-liquid separation vessel;

a third vapor-liquid separation vessel having an inlet, a vapor outlet, and a liquid outlet, wherein said third vapor-liquid separation vessel is configured to separate the partially condensed second residue gas stream to form a liquid reflux stream and a second residue gas vapor stream, wherein said condenser outlet is coupled in fluid flow communication with said inlet of said third vapor-liquid separation vessel,

wherein said first vapor-liquid separation vessel further defines an upper absorber liquid inlet, wherein said upper absorber liquid inlet is coupled in fluid flow communication with a combined liquid stream conduit configured to transport a combined liquid stream into an upper portion of said first vapor-liquid separation vessel, wherein said combined liquid stream conduit is configured to combine said first liquid portion of said first liquid stream with a portion of said liquid reflux stream to form said combined liquid stream and to introduce said combined liquid stream into said upper absorber liquid inlet;

a first vapor conduit configured to transport the entire first residue gas stream from said first vapor-liquid separation vessel, wherein said first vapor conduit is in fluid flow communication with said first upper vapor outlet of said first vapor-liquid separation vessel;

a second vapor conduit configured to transport at least a portion of said second residue gas vapor stream from said third vapor-liquid separation vessel, wherein said second vapor conduit is in fluid flow communication with said vapor outlet of said third vapor-liquid separation vessel;

a combined gas conduit configured to receive and combine said first residue gas stream and at least a portion of said second residue gas vapor stream withdrawn from said third vapor-liquid separation vessel to form a combined residue gas stream, wherein said combined gas conduit is in fluid flow communication with said first and said second vapor conduits;

a first warming pass disposed within said primary heat exchanger, wherein said first warming pass warms the combined residue gas stream, wherein said first warming pass is in fluid flow communication with said combined gas conduit; and

a single closed-loop mixed refrigeration cycle, said cycle comprising—

a refrigerant compressor defining a suction inlet and a discharge outlet for compressing a stream of mixed refrigerant;

a first refrigerant cooling pass in fluid flow communication with said discharge outlet of said refrigerant compressor, said first refrigerant cooling pass being disposed in said primary heat exchanger and cools at least a portion of the compressed stream of mixed refrigerant;

an expansion device defining a high pressure inlet and a low pressure outlet for expanding the cooled mixed refrigerant stream, wherein said high pressure inlet is coupled in fluid flow communication with said first refrigerant cooling pass;

a first refrigerant warming pass in fluid flow communication with said low pressure outlet of said expansion device, said first refrigerant warming pass being disposed within said primary heat exchanger and warms the expanded mixed refrigerant stream via indirect heat exchange with the compressed mixed refrigerant stream in said first refrigerant cooling pass and/or the compressed feed gas stream in said first cooling pass, wherein said first refrigerant warming pass is in fluid flow communication with said suction inlet of said refrigerant compressor.

14. The facility of claim 13, further comprising a refrigerant condenser defining a warm refrigerant inlet and a cool refrigerant outlet;

a refrigerant separator defining a fluid inlet, a vapor outlet, and a liquid outlet; and

a refrigerant mixing point, wherein said discharge outlet of said refrigerant compressor is coupled in fluid flow communication with said warm refrigerant inlet of said refrigerant condenser and said fluid inlet of said refrigerant separator is coupled in fluid flow communication with said cool refrigerant outlet of said refrigerant condenser, wherein said refrigerant separator separates an at least partially condensed refrigerant stream introduced into said refrigerant separator via said fluid inlet into a refrigerant vapor stream withdrawn from said vapor outlet and a refrigerant liquid stream withdrawn from said liquid outlet, wherein said refrigerant mixing point combines at least a portion of said refrigerant vapor stream with at least a portion of said refrigerant liquid stream prior to or within said first refrigerant cooling pass.

15. The facility of claim 13, further comprising a cracking unit located upstream of said NGL recovery facility, wherein at least a portion of said hydrocarbon-containing feed gas originates from said cracking unit.