High-capacity electrodes with active material coatings on multilayered nanostructured templates

• US 9,780,365 B2
• Filed: 10/20/2011
• Issued: 10/03/2017
• Est. Priority Date: 03/03/2010
• Status: Active Grant

• Current Assignee: Amprius Technologies Incorporated (Amprius, Inc.)
• Original Assignee: Amprius, Inc.
• Inventors: Liu, Zuqin, Han, Song, Loveness, Ghyrn E.
• Primary Examiner(s): Ruddock, Ula C
• Assistant Examiner(s): CHUO, TONY SHENG HSIANG
• Application Number:
  US13/277,821
• Publication Number:
  US 20120070741A1
• Time in Patent Office: 2,175 Days
• Field of Search: None
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 4/0428 Chemical vapour deposition
• CPC Class Codes: H01M 4/134 Electrodes based on metals, Si or alloys
• CPC Class Codes: H01M 4/1395 of electrodes based on metals, Si or alloys
• CPC Class Codes: H01M 4/366 as layered products
• CPC Class Codes: H01M 4/38 of elements or alloys
• CPC Class Codes: H01M 4/386 Silicon or alloys based on silicon
• CPC Class Codes: H01M 4/387 Tin or alloys based on tin
• CPC Class Codes: H01M 4/587 for inserting or intercalating light metals
• CPC Class Codes: H01M 4/66 Selection of materials
• CPC Class Codes: H01M 4/662 Alloys collectors of lead alloys H01M4/685
• CPC Class Codes: H01M 4/667 in the form of layers, e.g. coatings
• CPC Class Codes: H01M 4/75 Wires, rods or strips
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

Provided are battery electrode structures that maintain high mass loadings (i.e., large amounts per unit area) of high capacity active materials in the electrodes without deteriorating their cycling performance. These mass loading levels correspond to capacities per electrode unit area that are suitable for commercial electrodes even though the active materials are kept thin and generally below their fracture limits. A battery electrode structure may include multiple template layers. An initial template layer may include nanostructures attached to a substrate and have a controlled density. This initial layer may be formed using a controlled thickness source material layer provided, for example, on a substantially inert substrate. Additional one or more template layers are then formed over the initial layer resulting in a multilayer template structure with specific characteristics, such as a surface area, thickness, and porosity. The multilayer template structure is then coated with a high capacity active material.

Claims

1. An electrode material comprising:

an electronically conductive layer;

a layer of first nanostructures positioned on the electronically conductive layer, the first nanostructures comprising one or more metal silicides;

a layer of second nanostructures positioned on the layer of the first nanostructures; and

a coating of electrode active material that covers at least a portion of the first nanostructures and the second nanostructures.

2. The electrode material of claim 1, wherein the one or more metal silicides are selected from the group consisting of nickel silicides, cobalt silicides, copper silicides, silver silicides, chromium silicides, titanium silicides, aluminum silicides, zinc silicides, and iron silicides.

3. The electrode material of claim 2, wherein the one or more metal silicides are selected from the group consisting of Ni₂Si, NiSi, and NiSi₂, and combinations thereof.

4. The electrode material of claim 1, wherein the electronically conductive layer comprises stainless steel.

5. The electrode material of claim 1, wherein the electrode active material comprises one or more materials selected from the group consisting of crystalline silicon, amorphous silicon, silicon oxides, silicon oxy-nitrides, tin-containing materials, germanium-containing materials, and carbon-containing materials.

6. The electrode material of claim 1, wherein the layer of the first nanostructures comprises a plurality of nanowires rooted to the electronically conductive layer.

7. The electrode material of claim 1, wherein the electrode material has porosity between about 30% and 50%.

8. The electrode material of claim 1, wherein the coating of the electrode active material comprises multiple layers.

9. The electrode material of claim 8, wherein the multiple layers comprise at least some layers that have different porosities.

10. The electrode material of claim 9, wherein the multiple layers comprise an inner layer and an outer layer, and wherein the inner layer has a lower porosity than the outer layer.

11. The electrode material of claim 8, wherein the multiple layers comprise at least some layers that have different hydrogen concentrations.

12. The electrode material of claim 8, wherein the multiple layers comprise at least some layers that have different compositions.

13. The electrode material of claim 8, wherein the multiple layers comprise at least some layers that have different morphologies.

14. The electrode material of claim 1, wherein the coating of the electrode active material is positioned between at least a portion of the layer of the first nanostructures and the layer of the second nanostructures.

15. The electrode material of claim 1, wherein the layer of the second nanostructures comprises carbon nanofibers.

16. The electrode material of claim 1, wherein the layer of the second nanostructures comprises multidimensional metal silicide structures.

17. The electrode material of claim 16, wherein the multidimensional metal silicide structures comprise support structures to which plurality of metal silicide nanowires are attached.

18. An electrode assembly comprising:

a conductive substrate for conducting electrical current between an electrode active material and battery terminal; and

an electrode material comprising;

a layer of first nanostructures attached to the conductive substrate, the first nanostructures comprising one or more metal silicides;

a layer of second nanostructures positioned on the layer of the first nanostructures; and

a coating of the electrode active material that covers at least a portion of the first nanostructures and the second nanostructures,

wherein the first nanostructures and the second nanostructures provide electronic communication between the electrode active material and conductive substrate.

19. An electrochemical cell comprising:

a first electrode comprising an electronically conductive layer, a layer of first nanostructures positioned on the electronically conductive layer, wherein the first nanostructures comprising one or more metal silicides, a layer of second nanostructures positioned on the layer of the first nanostructures, and a coating of electrode active material that covers at least a portion of the first nanostructures and the second nanostructures;

a second electrode; and

an electrolyte providing ionic communication between the first electrode and the second electrode.