Hydrocarbon processing

• US 9,790,147 B2
• Filed: 08/18/2014
• Issued: 10/17/2017
• Est. Priority Date: 09/11/2013
• Status: Active Grant

• Current Assignee: UOP Llc (Honeywell International Inc.), SME Products LP
• Original Assignee: Ortloff Engineers, Ltd. (Honeywell International Inc.), SME Products LP
• Inventors: Lynch, Joe T, Wilkinson, John D., Miller, Scott A., Hudson, Hank M., Cuellar, Kyle T., Johnke, Andrew F., Lewis, W. Larry
• Primary Examiner(s): Nguyen, Tam M
• Application Number:
  US14/462,069
• Publication Number:
  US 20150073195A1
• Time in Patent Office: 1,156 Days
• Field of Search: None
• CPC Class Codes: B01D 3/16 Fractionating columns in which vapour bubbles through liquid packing elements B01J19/30, B01J19/32
• CPC Class Codes: B01D 3/32 Other features of fractionating columns ; Constructional details of fractionating columns not provided for in groups B01D3/16 - B01D3/30
• CPC Class Codes: B01D 3/322 Reboiler specifications
• CPC Class Codes: B01D 3/42 Regulation; Control
• CPC Class Codes: B01D 5/0063 Reflux condensation
• CPC Class Codes: C07C 7/04 by distillation
• CPC Class Codes: C10G 7/08 Azeotropic or extractive distillation refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents C10G21/00
• CPC Class Codes: C10L 2290/06 Heat exchange, direct or indirect
• CPC Class Codes: C10L 2290/24 Mixing, stirring of fuel components
• CPC Class Codes: C10L 2290/541 Absorption of impurities during preparation or upgrading of a fuel
• CPC Class Codes: C10L 2290/543 Distillation, fractionation or rectification for separating fractions, components or impurities during preparation or upgrading of a fuel
• CPC Class Codes: C10L 3/06 Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04 liquefying by pressure and cold treatment F25J
• CPC Class Codes: C10L 3/12 Liquefied petroleum gas liquefying by pressure and cold treatment F25J
• CPC Class Codes: F25J 1/0022 Hydrocarbons, e.g. natural gas

Abstract

A process and an apparatus are disclosed for a compact processing assembly to fractionate lighter components from mixed hydrocarbon streams. The hydrocarbon stream is supplied to the processing assembly between an absorbing means and a mass transfer means. A distillation vapor stream is collected from the upper region of the absorbing means and cooled in a first heat and mass transfer means inside the processing assembly to partially condense it, forming a volatile stream and a condensed stream. The condensed stream is supplied to the absorbing means as its top feed. A distillation liquid stream is collected from the lower region of the mass transfer means and heated in a second heat and mass transfer means inside the processing assembly to strip out its volatile components, forming a relatively less volatile stream and a vaporized stream. The vaporized stream is supplied to the mass transfer means as its bottom feed.

Claims

1. A process for the separation of a mixed hydrocarbon stream containing at least a lighter hydrocarbon component and a heavier hydrocarbon component into a volatile fraction containing a major portion of said lighter hydrocarbon component and a relatively less volatile fraction containing a major portion of said heavier hydrocarbon component wherein

(1) said mixed hydrocarbon stream is supplied as a feed between a first heat and mass transfer means and a second heat and mass transfer means housed in a processing assembly, said first heat and mass transfer means being located above said second heat and mass transfer means;

(2) a first distillation vapor stream is collected from an upper region of said second heat and mass transfer means and combined with any vapor portion of said feed to form a combined vapor stream;

(3) said combined vapor stream is cooled in said first heat and mass transfer means to simultaneously condense the less volatile components from said combined vapor stream, thereby forming a first distillation liquid stream and a second distillation vapor stream, whereupon said second distillation vapor stream is discharged from said processing assembly as said volatile fraction;

(4) said first distillation liquid stream is collected from a lower region of said first heat and mass transfer means and combined with any liquid portion of said feed to form a combined liquid stream;

(5) said combined liquid stream is heated in said second heat and mass transfer means to simultaneously strip the more volatile components from said combined liquid stream, thereby forming said first distillation vapor stream and a second distillation liquid stream, whereupon said second distillation liquid stream is discharged from said processing assembly as said relatively less volatile fraction; and

(6) a control means is adapted to maintain the temperature of said volatile fraction at a temperature whereby the major portion of said heavier hydrocarbon component is recovered in said relatively less volatile fraction and to maintain the temperature of said relatively less volatile fraction at a temperature whereby the major portion of said lighter hydrocarbon component is recovered in said volatile fraction.

2. The process according to claim 1 wherein

(1) an absorbing means is housed in said processing assembly below said first heat and mass transfer means and above said second heat and mass transfer means;

(2) said combined vapor stream and said first distillation liquid stream are directed to said absorbing means to condense the less volatile components from said combined vapor stream, thereby forming a third distillation liquid stream and a third distillation vapor stream;

(3) said third distillation vapor stream is collected from an upper region of said absorbing means and cooled in said first heat and mass transfer means to simultaneously condense the less volatile components from said third distillation vapor stream, thereby forming said first distillation liquid stream and said second distillation vapor stream; and

(4) said third distillation liquid stream is collected from a lower region of said absorbing means and combined with said any liquid portion of said feed to form said combined liquid stream.

3. The process according to claim 1 wherein

(1) a mass transfer means is housed in said processing assembly below said first heat and mass transfer means and above said second heat and mass transfer means;

(2) said combined liquid stream and said first distillation vapor stream are directed to said mass transfer means to strip the more volatile components from said combined liquid stream, thereby forming a third distillation liquid stream and a third distillation vapor stream;

(3) said third distillation vapor stream is collected from an upper region of said mass transfer means and combined with said any vapor portion of said feed to form said combined vapor stream; and

(4) said third distillation liquid stream is collected from a lower region of said mass transfer means and heated in said second heat and mass transfer means to simultaneously strip the more volatile components from said third distillation liquid stream, thereby forming said first distillation vapor stream and said second distillation liquid stream.

4. The process according to claim 2 wherein

(1) a mass transfer means is housed in said processing assembly below said absorbing means and above said second heat and mass transfer means;

(2) said combined liquid stream and said first distillation vapor stream are directed to said mass transfer means to strip the more volatile components from said combined liquid stream, thereby forming a fourth distillation liquid stream and a fourth distillation vapor stream;

(3) said fourth distillation vapor stream is collected from an upper region of said mass transfer means and combined with said any vapor portion of said feed to form said combined vapor stream; and

(4) said fourth distillation liquid stream is collected from a lower region of said mass transfer means and heated in said second heat and mass transfer means to simultaneously strip the more volatile components from said fourth distillation liquid stream, thereby forming said first distillation vapor stream and said second distillation liquid stream.

5. The process according to claim 1 wherein

(1) said combined vapor stream is cooled in said first heat and mass transfer means sufficiently to substantially condense it, thereby forming a condensed stream;

and

(2) said condensed stream is divided into said first distillation liquid stream and a third distillation liquid stream, whereupon said third distillation liquid stream is discharged from said processing assembly as said volatile fraction.

6. The process according to claim 2 wherein

(1) said third distillation vapor stream is cooled in said first heat and mass transfer means sufficiently to substantially condense it, thereby forming a condensed stream;

and

(2) said condensed stream is divided into said first distillation liquid stream and a fourth distillation liquid stream, whereupon said fourth distillation liquid stream is discharged from said processing assembly as said volatile fraction.

7. The process according to claim 3 wherein

(1) said combined vapor stream is cooled in said first heat and mass transfer means sufficiently to substantially condense it, thereby forming a condensed stream;

and

(2) said condensed stream is divided into said first distillation liquid stream and a fourth distillation liquid stream, whereupon said fourth distillation liquid stream is discharged from said processing assembly as said volatile fraction.

8. The process according to claim 4 wherein

(1) said third distillation vapor stream is cooled in said first heat and mass transfer means sufficiently to substantially condense it, thereby forming a condensed stream;

and

(2) said condensed stream is divided into said first distillation liquid stream and a fifth distillation liquid stream, whereupon said fifth distillation liquid stream is discharged from said processing assembly as said volatile fraction.