Process for improving the operations of a polymerisation plant

• US 9,790,293 B2
• Filed: 09/30/2013
• Issued: 10/17/2017
• Est. Priority Date: 10/02/2012
• Status: Expired due to Fees

• Current Assignee: Ineos Europe AG (Ineos AG)
• Original Assignee: Ineos Europe AG (Ineos AG)
• Inventors: Betton, Fabrice, Ramsay, Kevin Peter
• Primary Examiner(s): Teskin, Fred M
• Application Number:
  US14/428,758
• Publication Number:
  US 20150246981A1
• Time in Patent Office: 1,478 Days
• Field of Search: 422131, 526 70, 526 68, 585329, 585809
• CPC Class Codes: B01J 19/24 Stationary reactors without moving elements inside B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02
• CPC Class Codes: B01J 19/245 placed in series
• CPC Class Codes: B01J 2219/24 Stationary reactors without moving elements inside
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 110/02 Ethene
• CPC Class Codes: C08F 2/00 Processes of polymerisation
• CPC Class Codes: C08F 2/14 Organic medium
• CPC Class Codes: C08F 210/16 Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
• CPC Class Codes: C08G 85/008 Cleaning reaction vessels using chemicals mechanical methods B08B9/08
• CPC Class Codes: C08J 11/02 of solvents, plasticisers or unreacted monomers

Abstract

Petrochemical complex containing an olefin monomer polymerization plant having at least one polymerization reactor and an optional degassing section. The polymerization reactor contains process hydrocarbons consisting of the monomer, the optional comonomer(s) and optionally at least one inert hydrocarbon diluent, together with aluminum containing compound(s). The polymerization plant includes liquid purge stream(s) which contain aluminum containing compounds and optionally polymer fines, together with accumulated hydrocarbons which are different from the process hydrocarbons and which are hydrocarbons containing at least 4 carbon atoms. The petrochemical complex also contains a multipurpose hydrocarbon treatment unit which separates the liquid purge stream(s) into one stream having substantially all of the aluminum containing compounds and optional polymer fines, and one stream containing the accumulated hydrocarbons. The petrochemical complex also contains an upgrading unit for the treatment of the accumulated hydrocarbons which also produces the fresh monomer and/or comonomer for the polymerization reaction.

Claims

1. Petrochemical complex comprising an olefin monomer polymerisation plant comprising at least one polymerisation reactor and an optional degassing section, wherein

the polymerisation reactor comprises process hydrocarbons consisting of the monomer, the optional comonomer(s) and optionally at least one inert hydrocarbon diluent, together with aluminium containing compound(s);

and

the polymerisation plant comprises liquid purge stream(s) which comprises aluminium containing compounds and optionally polymer fines, together with accumulated hydrocarbons which are different from the said process hydrocarbons and which are hydrocarbons containing at least 4 carbon atoms,

wherein the petrochemical complex also comprises a multipurpose hydrocarbon treatment unit which separates the liquid purge stream(s) into

one stream comprising substantially all of the aluminium containing compounds and optional polymer fines, and

one stream comprising the accumulated hydrocarbons; and

further wherein the petrochemical complex also comprises an upgrading unit for the treatment of the accumulated hydrocarbons which also produces the fresh monomer and/or comonomer for the polymerisation reaction.

4. Petrochemical complex according to claim 1 further comprising a hydrocarbon upgrading plant which is a thermal oxidation unit and/or a boiler unit and/or a cracking unit, characterised in that the separated accumulated hydrocarbons are recycled into the said hydrocarbon upgrading plant.

6. Complex according to claim 1 wherein the accumulated hydrocarbons are butene-2, butane, hexene-2, hexane, octene-2, octane, n-hexane, n-octane, or n-decane.

7. Complex according to claim 1 wherein the liquid purge(s) represent more than 0.3 kg per ton of polymer produced.

8. Complex according to claim 1 wherein at least 500 kilograms of aluminium containing compounds are recovered per year.

9. Complex according to claim 1 wherein the aluminium containing compounds are selected from organoaluminium compounds.

10. Complex according to claim 1 wherein the catalyst used in the polymerisation plant is a Ziegler-Natta type catalyst.

11. Complex according to claim 1 wherein the hydrocarbon treatment unit is a distillation unit.

12. Complex according to claim 1 wherein the liquid purges are separated into

one stream comprising substantially all of the aluminium containing compounds and optional polymer fines,

one stream comprising the accumulated hydrocarbons, and

one stream comprising process hydrocarbons.

13. Complex according to claim 1 wherein the accumulated hydrocarbons are upgraded into valuable products which comprise at least one of the monomer and/or comonomer contained in the process hydrocarbons.

14. Complex according to claim 1 wherein the upgrading unit for the treatment of the accumulated hydrocarbons is a cracking unit.

2. Process for the polymerisation of an olefin monomer, said process comprising the polymerisation in the polymerisation reactor of an olefin monomer polymerisation plant of the monomer and the optional comonomer(s) optionally in the presence of at least one inert hydrocarbon diluent (the “

process hydrocarbons”

) and at least one aluminium containing compound, said process comprising at least one liquid purge stream which comprises aluminium containing compounds and optionally polymer fines, together with accumulated hydrocarbons which are different from the said process hydrocarbons and which are hydrocarbons containing at least 4 carbon atoms,

wherein the liquid purge stream is separated into

one stream comprising substantially all of the aluminium containing compounds and optional polymer fines, and

one stream comprising the accumulated hydrocarbons.

3. Process according to claim 2 wherein the accumulated inert hydrocarbons are maintained below an acceptable level in the polymerisation reactor of the olefin monomer polymerisation plant, the acceptable level of accumulated hydrocarbons in the reactor being a level above which its absorption on the polymer powder will overload the degassing capabilities of the degassing section.

5. Process according to claim 2 wherein the polymerisation plant is integrated in a petrochemical complex comprising a hydrocarbon upgrading plant which is a thermal oxidation unit and/or a boiler unit and/or a cracking unit, wherein the separated accumulated hydrocarbons are recycled into the hydrocarbon upgrading plant.

15. Process according to claim 2 wherein the accumulated hydrocarbons are butene-2, butane, hexene-2, hexane, octene-2, octane, n-hexane, n-octane, or n-decane.

16. Process according to claim 2 wherein the liquid purge(s) represent more than 0.3 kg per ton of polymer produced.

17. Process according to claim 2 wherein at least 500 kilograms of aluminium containing compounds are recovered per year.

18. Process according to claim 2 wherein the aluminium containing compounds are selected from organoaluminium compounds.

19. Process according to claim 2 wherein the catalyst used in the polymerisation plant is a Ziegler-Natta type catalyst.

20. Process according to claim 2 wherein the separation of the liquid purge stream takes place in a hydrocarbon treatment unit which is a distillation unit.

21. Process according to claim 2 wherein the liquid purges are separated into

one stream comprising substantially all of the aluminium containing compounds and optional polymer fines,

one stream comprising the accumulated hydrocarbons, and

one stream comprising process hydrocarbons.

22. Process according to claim 2 wherein the accumulated hydrocarbons are upgraded into valuable products which comprise at least one of the monomer and/or comonomer contained in the process hydrocarbons.

23. Process according to claim 2 wherein there is further provided an upgrading unit for the treatment of the accumulated hydrocarbons which upgrading unit also produces the fresh monomer and/or comonomer for the polymerisation reactor.