Composite having semiconductor structure including a nanocrystalline core and shell embedded in a matrix

• US 9,793,446 B2
• Filed: 04/13/2015
• Issued: 10/17/2017
• Est. Priority Date: 11/09/2011
• Status: Active Grant

• Current Assignee: Osram Opto Semiconductors GmbH (Ams-Osram AG)
• Original Assignee: Pacific Light Technologies Corp. (Ams-Osram AG)
• Inventors: Kurtin, Juanita, Theobald, Brian, Carillo, Matthew J., Park, Oun-Ho, Masson, Georgeta, Hughes, Steven M.
• Primary Examiner(s): Gordon, Matthew
• Assistant Examiner(s): SWAN, GARDNER W.S
• Application Number:
  US14/685,570
• Publication Number:
  US 20150221838A1
• Time in Patent Office: 918 Days
• Field of Search: 257 13, 257 17, 257 22, 257E2109, 257E29071, 257E29082, 313498, 313499
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: B82Y 40/00 Manufacture or treatment of nanostructures
• CPC Class Codes: C01B 19/007 Tellurides or selenides of metals C01B19/002 takes precedence
• CPC Class Codes: C01P 2002/84 by UV- or VIS- data
• CPC Class Codes: C01P 2004/04 obtained by TEM, STEM, STM or AFM
• CPC Class Codes: C01P 2004/10 extending in one dimension, e.g. needle-like
• CPC Class Codes: C01P 2004/54 Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension
• CPC Class Codes: C01P 2004/64 Nanometer sized, i.e. from 1-100 nanometer
• CPC Class Codes: C01P 2004/80 Particles consisting of a mixture of two or more inorganic phases
• CPC Class Codes: C09K 11/02 Use of particular materials as binders, particle coatings or suspension media therefor
• CPC Class Codes: C09K 11/025 non-luminescent particle coatings or suspension media
• CPC Class Codes: C09K 11/565 with zinc cadmium
• CPC Class Codes: C09K 11/883 with zinc or cadmium
• CPC Class Codes: H01L 2933/0033 relating to semiconductor body packages
• CPC Class Codes: H01L 2933/0041 relating to wavelength conversion elements
• CPC Class Codes: H01L 2933/005 relating to encapsulations
• CPC Class Codes: H01L 2933/0083 Periodic patterns for optical field-shaping in or on the semiconductor body or semiconductor body package, e.g. photonic bandgap structures
• CPC Class Codes: H01L 33/005 Processes
• CPC Class Codes: H01L 33/06 within the light emitting region, e.g. quantum confinement structure or tunnel barrier
• CPC Class Codes: H01L 33/502 : Wavelength conversion materials
• CPC Class Codes: H01L 33/56 : Materials, e.g. epoxy or silicone resin
• CPC Class Codes: Y10S 977/744 : having atoms interior to the carbon cage
• CPC Class Codes: Y10S 977/774 : Exhibiting three-dimensional carrier confinement, e.g. quantum dots
• CPC Class Codes: Y10S 977/824 : Group II-VI nonoxide compounds, e.g. CdxMnyTe
• CPC Class Codes: Y10S 977/89 : Deposition of materials, e.g. coating, cvd, or ald
• CPC Class Codes: Y10S 977/95 : Electromagnetic energy

Abstract

Composites having semiconductor structures embedded in a matrix are described. In an example, a composite includes a matrix material. A plurality of semiconductor structures is embedded in the matrix material. Each semiconductor structure includes an anisotropic nanocrystalline core composed of a first semiconductor material. Each semiconductor structure also includes a nanocrystalline shell composed of a second, different, semiconductor material at least partially surrounding the anisotropic nanocrystalline core. An insulator layer encapsulates each nanocrystalline shell and anisotropic nanocrystalline core pairing.

Claims

1. A composite, comprising:

a matrix material; and

a plurality of semiconductor structures embedded in the matrix material, each semiconductor structure comprising;

an anisotropic nanocrystalline core comprising a first semiconductor material;

a nanocrystalline shell comprising a second, different, semiconductor material completely surrounding the anisotropic nanocrystalline core, wherein the nanocrystalline shell has a center, wherein the nanocrystalline shell extends in a first direction along a first axis and the anisotropic nanocrystalline core is disposed off-center with respect to the nanocrystalline shell in the first direction along the first axis, wherein the nanocrystalline shell extends in a second direction along a second axis orthogonal to the first axis and the anisotropic nanocrystalline core is further disposed off-center with respect to the nanocrystalline shell in the second direction along the second axis, wherein the nanocrystalline shell is longer in the first direction than in the second direction, and wherein the anisotropic nanocrystalline core and the nanocrystalline shell form a quantum dot; and

an insulator layer encapsulating the nanocrystalline shell and anisotropic nanocrystalline core.

2. The composite of claim 1, wherein each of the plurality of semiconductor structures is cross-linked with, polarity bound by, or tethered to the matrix material.

3. The composite of claim 1, wherein each of the plurality of semiconductor structures is bound to the matrix material by a covalent, dative, or ionic bond.

4. The composite of claim 1, wherein one or more of the semiconductor structures further comprises a coupling agent covalently bonded to an outer surface of the insulator layer.

5. The composite of claim 4, wherein the insulator layer comprises a layer of silica (SiOx), and the coupling agent is a silane coupling agent.

6. The composite of claim 5, wherein the silane coupling agent has the formula XnSiY4-n, where X is a functional group capable of bonding with the matrix material and is selected from the group consisting of hydroxyl, alkoxy, isocyanate, carboxyl, epoxy, amine, urea, vinyl, amide, aminoplast and silane, Y is a functional group selected from the group consisting of hydroxyl, phenoxy, alkoxy, hydroxyl ether, silane and aminoplast, and n is 1, 2 or 3.

7. The composite of claim 4, wherein the coupling agent is selected from the group consisting of a titanate coupling agent and a zirconate coupling agent.

8. The composite of claim 1, wherein the insulator layer comprises a layer of silica (SiOx), and the matrix material comprises a siloxane copolymer.

9. The composite of claim 1, wherein the matrix material has a UV-Vis spectroscopy transmission of greater than 90% for light in the range of 400-700 nanometers.

10. The composite of claim 1, wherein the matrix material has a refractive index approximately in the range of 1-2 for light in the range of 400-700 nanometers.

11. The composite of claim 1, wherein the matrix material is thermally stable in a temperature range of −

40-250 degrees Celsius.

12. The composite of claim 1, wherein the matrix material comprises a polymer selected from the group consisting of polypropylene, polyethylene, polyesters, polyacetals, polyamides, polyacrylamides, polyimides, polyethers, polyvinylethers, polystyrenes, polyoxides, polycarbonates, polysiloxanes, polysulfones, polyanhydrides, polyamines, epoxies, polyacrylics, polyvinylesters, polyurethane, maleic resins, urea resins, melamine resins, phenol resins, furan resins, polymer blends, polymer alloys, and mixtures thereof.

13. The composite of claim 12, wherein the matrix material comprises a polysiloxane selected from the group consisting of polydimethylsiloxane (PDMS), polymethylphenylsiloxane, polydiphenylsiloxane and polydiethylsiloxane.

14. The composite of claim 1, wherein the matrix material comprises a siloxane selected from the group consisting of dimethylsiloxane and methylhydrogen siloxane.

15. The composite of claim 1, wherein the plurality of semiconductor structures are embedded homogeneously in the matrix material.

16. The composite of claim 1, further comprising:

a compounding agent embedded in the matrix material, the compounding agent selected from the group consisting of an antioxidant, a pigment, a dye, an antistatic agent, a filler, a flame retardant, an ultra-violet (UV) stabilizer, and an impact modifier.

17. The composite of claim 1, further comprising:

a catalyst embedded in the matrix material, the catalyst selected from the group consisting of a thiol catalyst and a platinum (Pt) catalyst.

18. The composite of claim 1, wherein the insulator layer is bonded directly to the nanocrystalline shell, passivates an outermost surface of the nanocrystalline shell, and provides a barrier for the nanocrystalline shell.

19. The composite of claim 1, wherein the insulator layer encapsulates only a single nanocrystalline shell/anisotropic nanocrystalline core pairing.

20. The composite of claim 1, wherein the insulator layer comprises a layer of silica (SiOx).

21. The composite of claim 1, wherein the quantum dot has a photoluminescence quantum yield (PLQY) of at least 90%.

22. The composite of claim 1, wherein the anisotropic nanocrystalline core has an aspect ratio between, but not including, 1.0 and 2.0.

23. A method of fabricating a composite, the method comprising:

forming a plurality of semiconductor structures, the forming of each semiconductor structure comprising;

forming an anisotropic nanocrystalline core comprising a first semiconductor material;

forming a nanocrystalline shell from a second, different, semiconductor material to completely surround the anisotropic nanocrystalline core, wherein the nanocrystalline shell has a center, wherein the nanocrystalline shell extends in a first direction along a first axis and the anisotropic nanocrystalline core is disposed off-center with respect to the nanocrystalline shell in the first direction along the first axis, wherein the nanocrystalline shell extends in a second direction along a second axis orthogonal to the first axis and the anisotropic nanocrystalline core is further disposed off-center with respect to the nanocrystalline shell in the second direction along the second axis, wherein the nanocrystalline shell is longer in the first direction than in the second direction, and wherein the anisotropic nanocrystalline core and the nanocrystalline shell form a quantum dot; and

forming an insulator layer encapsulating the nanocrystalline shell and anisotropic nanocrystalline core; and

embedding the plurality of semiconductor structures in a matrix material.

24. The method of claim 23, wherein embedding the plurality of semiconductor structures in the matrix material comprises cross-linking, reactive tethering, or ionic bonding the plurality of semiconductor structures with the matrix material.

25. The method of claim 23, wherein forming the insulator layer comprises forming a layer of silica (SiOx).

26. The method of claim 23, wherein embedding the plurality of semiconductor structures in the matrix material comprises embedding homogeneously in the matrix material.

27. The method of claim 23, wherein forming the anisotropic nanocrystalline core comprises:

forming the anisotropic nanocrystalline core having an aspect ratio between, but not including, 1.0 and 2.0.