Polyelectrolyte complexes

• US 9,796,872 B2
• Filed: 01/25/2016
• Issued: 10/24/2017
• Est. Priority Date: 03/29/2010
• Status: Active Grant

• Current Assignee: Clorox Company
• Original Assignee: Clorox Company
• Inventors: Scheuing, David R., Lestage, David J., Bennett, Carl W., Knock, Mona M., Scales, Charles W., Smith, William L., Zhang, Rui
• Primary Examiner(s): WEBB, GREGORY E
• Application Number:
  US15/005,366
• Publication Number:
  US 20160137871A1
• Time in Patent Office: 638 Days
• CPC Class Codes: A01N 25/10 Macromolecular compounds
• CPC Class Codes: A01N 33/12 Quaternary ammonium compounds
• CPC Class Codes: A01N 59/00 Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
• CPC Class Codes: A01N 59/16 Heavy metals; Compounds thereof
• CPC Class Codes: C09D 133/02 Homopolymers or copolymers of acids; Metal or ammonium salts thereof
• CPC Class Codes: C09D 5/14 Paints containing biocides, e.g. fungicides, insecticides or pesticides C09D5/16 takes precedence
• CPC Class Codes: C11D 1/62 Quaternary ammonium compounds
• CPC Class Codes: C11D 3/3769 (Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
• CPC Class Codes: C11D 3/3953 Inorganic bleaching agents C11D3/3951 takes precedence

Abstract

The present invention relates to aqueous compositions of associative polyelectrolyte complexes (PECs), optionally containing surfactants, biocidal agents and/or oxidants, which can provide surface protection to treated articles including reduced soiling tendency, reduced cleaning effort and improved soil repellancy, as well as providing bacteriostatic properties to treated surfaces that thereby gain resistance to water, environmental exposure and microbial challenge. Treatment means and compositions are provided that employ associative polyelectrolyte complexes formed by combining a water soluble cationic first polyelectrolyte with a water soluble second polyelectrolyte bearing groups of opposite charge to the first polyelectrolyte under suitable mixing conditions where the one polyelectrolyte present in molar excess is added in the form of a first aqueous solution during a mixing step to a second aqueous solution comprising the oppositely charged polyelectrolyte present in molar deficiency. Also provided are means to form stable associative polyelectrolyte complexes in aqueous solutions having R values from about 0.10 to 20, including near stoichiometric R values approaching 1, being the ratio of charged groups present on the component polyelectrolytes employed.

Claims

1. An aqueous composition comprising:

(a) water;

(b) a water soluble cationic first polyelectrolyte selected from a homopolymer of poly(diallyl dimethyl ammonium chloride);

(c) a water soluble anionic second polyelectrolyte comprising at least one of a homopolymer or a copolymer comprising at least one of the following anionic monomers;

acrylic acid, methacrylic acid, maleic acid, maleic anhydride, itaconic acid, styrene sulfonic acid, acrylamide propane sulfonic acid, or mixtures thereof; and

(d) one or more surfactants;

wherein a total polymer concentration of the water soluble cationic first polyelectrolyte and the water soluble anionic second polyelectrolyte in the aqueous composition is at a concentration of less than or equal to about 50 mM with respect to a total concentration of charged associating groups present on the first and second polyelectrolytes;

wherein the first polyelectrolyte and the second polyelectrolyte are not block copolymers.

2. The composition according to claim 1, further comprising an oxidant selected from the group consisting of hydrogen peroxide, alkaline metal salts of hypochlorous acid, alkaline earth metal salts of hypochlorous acid, hypochlorous acid, acidic sodium chlorite, active chlorine generating compounds, active oxygen generating compounds, sodium potassium peroxysulfate, sodium perborate, and combinations thereof.

3. The composition according to claim 2, wherein the oxidant is present in the composition at a level of from about 0.001 wt % to about 10 wt %.

4. The composition according to claim 1, wherein the cationic first polyelectrolyte is present in the composition at a level of from about 0.001 wt % to about 5.0 wt %.

5. The composition according to claim 1, wherein the anionic second polyelectrolyte is present in the composition at a level of from about 0.001 wt % to about 5.0 wt %.

6. The composition according to claim 1, wherein the total polymer concentration is at a concentration of less than or equal to about 10 mM with respect to a total concentration of charged associating groups present on the first and second polyelectrolytes.

7. The composition according to claim 1, further comprising a buffering agent selected from the group consisting of sodium carbonate, potassium carbonate, sodium silicate, sodium succinate, citric acid, citrate salts, boric acid and borate salts.

8. The composition according to claim 1, further comprising an antimicrobial agent selected from the group consisting of water-soluble quaternary ammonium salts, chlorhexidine salts, alpha-hydroxy acids, and water-soluble salts of silver, copper or zinc.

9. The composition according to claim 1, wherein the one or more surfactants are selected from the group consisting of an amine oxide, an alkyl poly(glucoside), an alkyl poly(pentoside), an alkyl sulfate, a secondary alkane sulfophonate, an alkyl benzene sulfonate, an alkyl polyethylene oxide, an alkyl betaine, an alkyl sulfo-betaine, and mixtures thereof.

10. An article comprising the composition according to claim 1, wherein the composition is disposed on or within a carrier substrate selected from the group consisting of a woven material, a non-woven material, a roller, a pad, a sponge, and combinations thereof.

11. An aqueous composition comprising:

(a) water;

(b) a water soluble cationic first polyelectrolyte selected from a homopolymer of poly(diallyl dimethyl ammonium chloride);

(c) a water soluble anionic second polyelectrolyte comprising at least one of a homopolymer or a copolymer comprising at least one of the following anionic monomers;

acrylic acid, methacrylic acid, maleic acid, maleic anhydride, itaconic acid, styrene sulfonic acid, acrylamide propane sulfonic acid, or mixtures thereof; and

(d) one or more surfactants;

(e) one or more oxidants selected from the group consisting of alkaline metal salts of hypochlorous acid, alkaline earth metal salts of hypochlorous acid, hypochlorous acid, and mixtures thereof;

wherein a total polymer concentration of the water soluble cationic first polyelectrolyte and the water soluble anionic second polyelectrolyte in the aqueous composition is at a concentration of less than or equal to about 50 mM with respect to a total concentration of charged associating groups present on the first and second polyelectrolytes;

wherein the first polyelectrolyte and the second polyelectrolyte are not block copolymers.

12. The composition according to claim 11, wherein the oxidant is present in the composition at a level of from about 0.001 wt % to about 10 wt %.

13. The composition according to claim 11, wherein the cationic first polyelectrolyte is present in the composition at a level of from about 0.001 wt % to about 5.0 wt %.

14. The composition according to claim 11, wherein the anionic second polyelectrolyte is present in the composition at a level of from about 0.001 wt % to about 5.0 wt %.

15. The composition according to claim 11, wherein the total polymer concentration is at a concentration of less than or equal to about 10 mM with respect to a total concentration of charged associating groups present on the first and second polyelectrolytes.

16. The composition according to claim 11, wherein the one or more surfactants are selected from the group consisting of an amine oxide, an alkyl poly(glucoside), an alkyl poly(pentoside), an alkyl sulfate, a secondary alkane sulfophonate, an alkyl benzene sulfonate, an alkyl polyethylene oxide, an alkyl betaine, an alkyl sulfo-betaine, and mixtures thereof.

17. An article comprising the composition according to claim 11, wherein the composition is disposed on or within a carrier substrate selected from the group consisting of a woven material, a non-woven material, a roller, a pad, a sponge, and combinations thereof.

18. An aqueous composition comprising:

(a) water;

(b) a water soluble cationic first polyelectrolyte comprising at least one of a homopolymer or a copolymer of a diallyl dimethyl ammonium chloride monomer;

(c) a water soluble anionic second polyelectrolyte comprising at least one of a homopolymer or a copolymer comprising at least one of the following anionic monomers;

acrylic acid, methacrylic acid, maleic acid, maleic anhydride, itaconic acid, styrene sulfonic acid, acrylamide propane sulfonic acid, or mixtures thereof;

wherein a total polymer concentration of the water soluble cationic first polyelectrolyte and the water soluble anionic second polyelectrolyte in the aqueous composition is at a concentration of less than or equal to about 50 mM with respect to a total concentration of charged associating groups present on the first and second polyelectrolytes;

wherein the first polyelectrolyte and the second polyelectrolyte are not block copolymers.

19. An article comprising the composition according to claim 18, wherein the composition is disposed on or within a carrier substrate selected from the group consisting of a woven material, a non-woven material, a roller, a pad, a sponge, and combinations thereof.