Pre-reformer for selective reformation of higher hydrocarbons

• US 9,799,902 B2
• Filed: 02/22/2016
• Issued: 10/24/2017
• Est. Priority Date: 10/23/2013
• Status: Active Grant

• Current Assignee: Bloom Energy Corporation
• Original Assignee: Bloom Energy Corporation
• Inventors: Weingaertner, David, Kalika, Vlad, Perry, Martin
• Primary Examiner(s): DOVE, TRACY MAE
• Application Number:
  US15/049,219
• Publication Number:
  US 20160240876A1
• Time in Patent Office: 610 Days
• Field of Search: None
• CPC Class Codes: C01B 2203/066 with fuel cells
• CPC Class Codes: C01B 2203/1058 Nickel catalysts
• CPC Class Codes: C01B 2203/1064 Platinum group metal catalysts
• CPC Class Codes: C01B 3/38 using catalysts
• CPC Class Codes: H01M 2008/1293 Fuel cells with solid oxide electrolytes
• CPC Class Codes: H01M 8/004 Cylindrical, tubular or wound
• CPC Class Codes: H01M 8/0618 Reforming processes, e.g. autothermal, partial oxidation or steam reforming
• CPC Class Codes: H01M 8/0631 Reactor construction specially adapted for combination reactor/fuel cell hydrogen C01B3/00; reactors for physicochemical processes B01J19/00
• CPC Class Codes: H01M 8/0637 Direct internal reforming at the anode of the fuel cell
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

Systems and methods are provided integrating an annular pre-reformer as part of an anode recuperator of a fuel cell system.

Claims

1. An anode recuperator for a fuel cell system, comprising:

an annular pre-reformer configured to at least partially reform a fuel;

an annular first fuel passage configured to provide fuel to the pre-reformer; and

an annular anode exhaust passage surrounding the first fuel passage and the pre-reformer and located radially to the outside of the pre-reformer, the anode exhaust passage being thermally coupled to the first fuel passage, such that anode exhaust flowing through the anode exhaust passage provides heat to fuel in the first fuel passage,

wherein the pre-reformer is separated from the anode exhaust passage by the first fuel passage.

2. The anode recuperator of claim 1, wherein the pre-reformer comprises:

an annular first pre-reforming passage fluidly connected to the first fuel passage; and

an annular second pre-reforming passage fluidly connected to the first pre-reforming passage and disposed within the first pre-reforming passage.

3. The anode recuperator of claim 2, wherein the pre-reformer is configured such that fuel provided by the first fuel passage flows through the first pre-reforming passage in a first direction and then flows through the second pre-reforming passage in an opposing second direction.

4. The anode recuperator of claim 3, wherein the anode recuperator is configured such that fuel flows through the first fuel passage in the second direction.

5. The anode recuperator of claim 2, further comprising a pre-reforming catalyst disposed in the first pre-reforming passage, the second pre-reforming passage, or both the first pre-reforming passage and the second pre-reforming passage.

6. The anode recuperator of claim 2, further comprising an annular second fuel passage configured to receive reformed fuel from the pre-reformer,

wherein:

the anode exhaust passage is thermally coupled to the second fuel passage, such that anode exhaust flowing through the anode exhaust passage provides heat to fuel in the second fuel passage before providing heat to fuel in the first fuel passage;

the annular pre-reformer is located within a central plenum of the anode recuperator and separated from an inner wall of the annular anode exhaust passage by at least one of the first annular fuel passage and the second annular fuel passage; and

the annular pre-reformer is located axially inward of at least one of the first annular fuel passage and the second annular fuel passage.

7. The anode recuperator of claim 6, wherein:

the first and the second fuel passages are located between the annular pre-reformer and the anode exhaust passage;

an inner wall of the second pre-reforming passage forms a first plenum; and

an inner wall of the second fuel passage forms a second plenum that is fluidly connected to the first plenum.

8. The anode recuperator of claim 2, wherein:

the second pre-reforming passage is divided into sections; and

each section comprises separate pre-reformer catalyst puck.

9. An anode recuperator for a fuel cell system, comprising:

an annular pre-reformer configured to at least partially reform a fuel;

an annular first fuel passage configured to provide fuel to the pre-reformer;

an annular second fuel passage configured to receive fuel from the pre-reformer; and

an annular anode exhaust passage surrounding the first fuel passage, the second fuel passage, and the pre-reformer, and located radially to the outside of the pre-reformer,

wherein;

the anode exhaust passage is thermally coupled the second fuel passage, such that anode exhaust flowing through the anode exhaust passage provides heat to fuel in the second fuel passage, and

the pre-reformer is separated from the anode exhaust passage by at least one of the first fuel passage and the second fuel passage.

10. The anode recuperator of claim 9, wherein:

the first and the second fuel passages are located between the annular pre-reformer and the anode exhaust passage; and

the second fuel passage surrounds the pre-reformer and separates the pre-reformer from the anode exhaust passage.

11. The anode recuperator of claim 10, wherein the pre-reformer comprises:

an annular first pre-reforming passage fluidly connected to the first fuel passage; and

an annular second pre-reforming passage fluidly connected to the first pre-reforming passage and disposed within the first pre-reforming passage.

12. The anode recuperator of claim 11, wherein the pre-reformer is configured such that fuel provided by the first fuel passage flows through the first pre-reforming passage in a first direction and then flows through the second pre-reforming passage in an opposing second direction.

13. The anode recuperator of claim 12, wherein the anode recuperator is configured such that fuel flows through the first fuel passage in the second direction.

14. The anode recuperator of claim 11, further comprising a pre-reforming catalyst disposed in the first pre-reforming passage, the second pre-reforming passage, or both the first pre-reforming passage and the second pre-reforming passage.

15. The anode recuperator of claim 11, wherein:

an inner wall of the second pre-reforming passage forms a first plenum; and

an inner wall of the second fuel passage forms a second plenum that is fluidly connected to the first plenum.

16. The anode recuperator of claim 15, wherein the second fuel passage separates the second plenum from the anode exhaust passage.

17. The anode recuperator of claim 11, wherein:

the second pre-reforming passage is divided into sections; and

each section comprises separate pre-reformer catalyst puck.

18. The anode recuperator of claim 9, wherein the annular pre-reformer is a finned pre-reformer.

19. The anode recuperator of claim 9, wherein:

the annular pre-reformer is located within a central plenum of the anode recuperator and separated from an inner wall of the annular anode exhaust passage by at least one of the first annular fuel passage and the second annular fuel passage; and

the annular pre-reformer is located axially inward of at least one of the first annular fuel passage and the second annular fuel passage.

20. A method of operating a fuel cell system including a fuel cell stack and an anode recuperator of claim 9, the method comprising:

providing a fuel to the annular pre-reformer from the first fuel passage;

at least partially reforming the fuel in the annular pre-reformer to generate a reformed fuel;

providing the reformed fuel to the fuel cell stack using the second fuel passage; and

heating at least one of the fuel in the first fuel passage and the reformed fuel in the second fuel passage using anode exhaust flowing through the annular anode exhaust passage.

21. The method of claim 20, wherein the heating comprises using the anode exhaust to heat the reformed fuel in the first fuel passage and the second fuel passage.