Integrated process for NGL (natural gas liquids recovery) and LNG (liquefaction of natural gas)

• US 9,803,917 B2
• Filed: 12/30/2013
• Issued: 10/31/2017
• Est. Priority Date: 12/28/2012
• Status: Active Grant

• Current Assignee: Linde Engineering North America, Inc. (Linde Plc)
• Original Assignee: Linde Engineering North America, Inc. (Linde Plc)
• Inventors: Burmberger, Stephan, Goldbeck, Danielle R., Hertel, Christoph, Marty, Aleisha, Bauer, Heinz, Key, Ronald D.
• Primary Examiner(s): Raymond, Keith
• Application Number:
  US14/143,755
• Publication Number:
  US 20140182331A1
• Time in Patent Office: 1,401 Days
• Field of Search: 62630, 62631
• CPC Class Codes: F25J 1/0022 Hydrocarbons, e.g. natural gas
• CPC Class Codes: F25J 1/0035 by gas expansion with extraction of work
• CPC Class Codes: F25J 1/004 by flash gas recovery F25J1/0267 takes precedence
• CPC Class Codes: F25J 1/0045 by vaporising a liquid return stream
• CPC Class Codes: F25J 1/005 by expansion of a gaseous refrigerant stream with extraction of work
• CPC Class Codes: F25J 1/0052 by vaporising a liquid refrigerant stream
• CPC Class Codes: F25J 1/0072 Nitrogen
• CPC Class Codes: F25J 1/0204 as a single flow SCR cycle
• CPC Class Codes: F25J 1/0205 as a dual level SCR refrigeration cascade
• CPC Class Codes: F25J 1/0208 in combination with an internal quasi-closed refrigeration loop, e.g. with deep flash recycle loop F25J1/021 takes precedence
• CPC Class Codes: F25J 1/021 using a deep flash recycle loop
• CPC Class Codes: F25J 1/0212 as a single flow MCR cycle
• CPC Class Codes: F25J 1/0215 with one SCR cycle
• CPC Class Codes: F25J 1/0219 in combination with an internal quasi-closed refrigeration loop, e.g. using a deep flash recycle loop
• CPC Class Codes: F25J 1/023 for the combustion as fuels, i.e. integration with the fuel gas system
• CPC Class Codes: F25J 1/0241 wherein the overhead cooling comprises providing reflux for a fractionation step
• CPC Class Codes: F25J 2200/02 in a single pressure main column system
• CPC Class Codes: F25J 2200/30 using a side column in a single pressure column system
• CPC Class Codes: F25J 2200/70 Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
• CPC Class Codes: F25J 2200/74 Refluxing the column with at least a part of the partially condensed overhead gas
• CPC Class Codes: F25J 2200/76 : Refluxing the column with condensed overhead gas being cycled in a quasi-closed loop refrigeration cycle
• CPC Class Codes: F25J 2200/78 : Refluxing the column with a liquid stream originating from an upstream or downstream fractionator column
• CPC Class Codes: F25J 2205/04 : in the feed line, i.e. upstream of the fractionation step
• CPC Class Codes: F25J 2220/62 : Separating low boiling components, e.g. He, H2, N2, Air
• CPC Class Codes: F25J 2240/02 : Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
• CPC Class Codes: F25J 2245/90 : the recycled stream being boil-off gas from storage
• CPC Class Codes: F25J 2260/20 : Integration in an installation for liquefying or solidifying a fluid stream
• CPC Class Codes: F25J 2270/42 : Quasi-closed internal or closed external nitrogen refrigeration cycle
• CPC Class Codes: F25J 2270/66 : Closed external refrigeration cycle with multi component refrigerant [MCR], e.g. mixture of hydrocarbons
• CPC Class Codes: F25J 2270/90 : External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration
• CPC Class Codes: F25J 2290/40 : Vertical layout or arrangement of cold equipments within in the cold box, e.g. columns, condensers, heat exchangers etc.
• CPC Class Codes: F25J 3/0209 : Natural gas or substitute natural gas
• CPC Class Codes: F25J 3/0233 : separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 : separation of CnHm with 2 carbon atoms or more

Abstract

The invention relates to an integrated process and apparatus for liquefaction of natural gas and recovery of natural gas liquids. In particular, the improved process and apparatus reduces the energy consumption of a Liquefied Natural Gas (LNG) unit by using a portion of the already cooled overhead vapor from a fractionation column from an NGL (natural gas liquefaction) unit to, depending upon composition, provide, for example, reflux for fractionation in the NGL unit and/or a cold feed for the LNG unit, or by cooling, within the NGL unit, a residue gas originating from a fractionation column of the NGL unit and using the resultant cooled residue gas to, depending upon composition, provide, for example, reflux/feed for fractionation in the NGL and/or a cold feed for the LNG unit, thereby reducing the energy consumption of the LNG unit and rendering the process more energy-efficient.

Claims

1. A process for integrated liquefaction of natural gas and recovery of natural gas liquids, said process comprising:

cooling a feed stream containing light hydrocarbons in one or more heat exchangers, wherein said feed stream is cooled and partially condensed by indirect heat exchange;

introducing the partially condensed feed stream into a gas/liquid cold separator producing an overhead gaseous stream and bottoms liquid stream which are to be introduced into a fractionation system, said fractionation system comprising a light ends fractionation column and a heavy ends fractionation column;

expanding at least a portion of the overhead gaseous stream from the gas/liquid cold separator and introducing said expanded overhead gaseous stream into a lower region of said light ends fractionation column;

introducing at least a portion of the bottoms liquid stream from gas/liquid cold separator into said heavy ends fractionation column at an intermediate point thereof;

removing a first liquid product stream from the bottom of said heavy ends fractionation column;

removing a overhead gaseous stream from the top of said light ends fractionation column, and

said process further comprising;

(i) subjecting a first portion of the light ends fractionation column overhead gaseous stream to indirect heat exchange with an overhead gaseous stream removed from the top of said heavy ends fractionation column, whereby said overhead gaseous stream from the top of said heavy ends fractionation column is cooled and partially condensed, and introducing the cooled and partially condensed overhead gaseous stream from the top of said heavy ends fractionation column into the light ends fractionation column;

(ii) removing a second portion of the overhead gaseous stream from said light ends fractionation column as a side stream, and subjecting said side stream to indirect heat exchange for further cooling, partially liquefying said side stream via indirect heat exchange, wherein said side stream of the overhead gaseous stream from the light ends fractionation column is split off from the overhead gaseous stream prior to the indirect heat exchange between said first portion of the light ends fractionation column overhead gaseous stream and the overhead gaseous stream removed from the top of said heavy ends fractionation column;

(iii) introducing the partially liquefied side stream into a further separation means, recovering a liquid stream from said further separation means and introducing the recovered liquid stream into the light ends fractionation column as a liquid reflux stream and/or the heavy ends fractionation column as a liquid reflux stream, and

(iv) recovering an overhead vapor stream from said further separation means, subjecting said overhead vapor stream from said further separation means to indirect heat exchange for additional cooling and partial condensation, and feeding the resultant vapor and condensate to an LNG separator wherein a final LNG liquid product is produced.

2. A process according to claim 1, further comprising

cooling said feed stream containing light hydrocarbons in a main heat exchanger wherein the feed stream partially condensed by indirect heat exchange;

introducing said first liquid product stream from said heavy ends fractionation column into said main heat exchanger for indirect heat exchanger with said feed stream;

wherein after subjecting said first portion of said overhead gaseous stream from the top of said light ends fractionation column to indirect heat with said overhead gaseous stream removed from the top of said heavy ends fractionation column, removing said first portion of the overhead gaseous stream from said light ends fractionation column as residue gas;

wherein, before said side stream is subjected to said indirect heat exchange for further cooling, said side stream is partially liquefying across a flow-control valve.

3. A process according to claim 1, further comprising:

introducing said feed stream containing light hydrocarbons into a main heat exchanger wherein said feed stream is cooled and partially condensed by indirect heat exchange;

introducing the liquid product stream from the bottom of said heavy ends fractionation column into said main heat exchanger where it undergoes indirect heat exchanger with said feed stream; and

wherein the liquid stream recovered from said further separation means is introduced into said light ends fractionation column as reflux.

4. A process according to claim 2, wherein

said liquid stream recovered from said further separation means is introduced into said light ends fractionation column as said liquid reflux stream.

5. A process according to claim 1, wherein said liquid stream recovered from the further separation means is introduced into the heavy ends fractionation column as liquid reflux.

6. A process according to claim 1, wherein a portion of said bottoms liquid stream from the gas/liquid cold separator is delivered to a liquid/liquid heat exchanger for indirect heat exchange with said bottom liquid stream removed from the light ends fractionation column, and then said portion of bottoms liquid stream from the gas/liquid cold separator is fed to an intermediate region of the light ends fractionation column as a liquid reflux.

7. A process according to claim 1, wherein a a portion of the gaseous overhead stream removed from the top of cold separator and a portion of bottoms liquid stream from cold separator are combined and the resultant combined stream is subjected to indirect heat exchange with the overhead vapor from the light ends fractionation column, wherein the combined stream is cooled and partially liquefied, and the resultant cooled and partially liquefied combined stream is introduced into the top region of the light ends fractionation column to provide additional reflux.

8. An apparatus for integration of liquefaction of natural gas and recovery of natural gas liquids, said apparatus comprising:

one or more heat exchangers for cooling and partially condensing by indirect heat exchange a feed stream containing light hydrocarbons;

a gas/liquid cold separator and means for introducing a partially condensed feed stream from the one or more heat exchangers into the gas/liquid cold separator, the gas/liquid cold separator having upper outlet means for removing an overhead gaseous stream and lower outlet means for removing a bottoms liquid stream;

means for introducing the overhead gaseous stream and the bottoms liquid stream from the gas/liquid cold separator into a fractionation system comprising a light ends fractionation column and a heavy ends fractionation column, the means comprising an expansion device for expanding at least a portion of overhead gaseous stream from the gas/liquid cold separator and means for introducing expanded overhead gaseous stream into a lower region of said light ends fractionation column, and means for introducing at least a portion of the bottoms liquid stream from the gas/liquid cold separator into said heavy ends fractionation column at an intermediate point thereof;

means for removing a first liquid product stream from the bottom of the heavy ends fractionation column;

means for removing an overhead gaseous stream from the top of the light ends fractionation column, and

means for removing a bottoms liquid stream from a lower region of the light ends fractionation column, and introducing this bottoms liquid stream from the light ends fractionation column into an upper region of the heavy ends fractionation column;

said apparatus further comprising;

(i) a first heat exchanger for subjecting a first portion of the light ends fractionation column overhead gaseous stream to indirect heat exchange with an overhead gaseous stream removed from the top of the heavy ends fractionation column, whereby the overhead gaseous stream from the top of the heavy ends fractionation column is cooled and partially condensed, means for removing the cooled and partially condensed overhead gaseous stream from said first heat exchanger, and means for introducing this cooled and partially condensed overhead gaseous stream from the top of the heavy ends fractionation column into the light ends fractionation column;

(ii) means for removing a second portion of the overhead gaseous stream from the light ends fractionation column as a side stream, and a further heat exchanger for subjecting the side stream to indirect heat exchange to further cool, and partially liquefy the side stream, wherein said side stream of the overhead gaseous stream from the light ends fractionation column is split off from the overhead gaseous stream from the light ends fractionation column prior to the indirect heat exchange between said first portion of the light ends fractionation column overhead gaseous stream and the overhead gaseous stream removed from the top of said heavy ends fractionation column in said first heat exchanger;

(iii) means for introducing the partially liquefied side stream into a further separation means, means for recovering a liquid stream from the further separation means and means for introducing the recovered liquid stream into the light ends fractionation column as a liquid reflux stream and/or the heavy ends fractionation column as a liquid reflux stream,

(iv) means for recovering an overhead vapor stream from the further separation means, a further heat exchanger for subjecting this overhead vapor stream to indirect heat exchange for additional cooling and partial condensation, means for feeding the resultant vapor and condensate to an LNG separator, and means for recovering LNG liquid product from the LNG separator, and

(v) means for recovering an overhead vapor stream from the further separation means, a compressor for compressing this overhead vapor stream to form a residue gas.

9. An apparatus according to claim 8, said apparatus further comprising:

a main heat exchanger for cooling and partially condensing the feed stream by indirect heat exchange;

means for introducing the first liquid product stream from the bottom of the heavy ends fractionation column into the main heat exchanger for indirect heat exchange with the feed stream; and

a flow-control valve for partially liquefying the side stream before introducing said side stream into said further heat exchanger.

10. A process for integrated liquefaction of natural gas and recovery of natural gas liquids, said process comprising:

cooling a feed stream containing light hydrocarbons by indirect heat exchange in a feed heat exchanger;

introducing the cooled feed stream into a gas/liquid cold separator, removing from said gas/liquid cold separator an overhead gaseous stream and bottoms liquid stream, and introducing said overhead gaseous stream and bottoms liquid stream into a fractionation system, said fractionation system comprising a light ends fractionation column and a heavy ends fractionation column;

removing a liquid product stream from said fractionation system;

removing an overhead gaseous stream from said fractionation system;

generating a residue gas stream from said overhead gaseous stream from said fractionation system;

introducing said residue gas stream into a further separation means, and recovering from said further separation means a liquid product stream and an overhead vapor stream;

introducing either said liquid product stream or said overhead vapor stream to an LNG exchanger/separator;

subjecting either said liquid product stream or said overhead vapor stream to liquefaction in said LNG exchanger/separator; and

removing LNG liquid product from said LNG exchanger/separator,

wherein an overhead gaseous stream is removed from the top of said light ends fractionation column as said overhead gaseous stream from said fractionation system;

said overhead gaseous stream from said light ends fractionation column is split into a first portion and a second portion;

after said overhead gaseous stream from said light ends fractionation column is split into a first portion and a second portion, said first portion is heated by indirect heat exchange with an overhead gaseous stream removed from the top of said heavy ends fractionation column, whereby said overhead gaseous stream from the top of said heavy ends fractionation column is cooled by said indirect heat exchange;

said second portion of overhead gaseous stream is cooled by indirect heat exchange; and

the cooled second portion of overhead gaseous stream is introduced into said further separation means as said residue gas.

11. A process according to claim 10, said process further comprising:

introducing the cooled overhead gaseous stream from the top of said heavy ends fractionation column into said light ends fractionation column;

introducing said liquid product stream from said further separation means into said light ends fractionation column and/or said heavy ends fractionation column as a liquid reflux stream; and

introducing said overhead vapor stream from said further separation means into said LNG exchanger/separator.

12. A process according to claim 10, said process further comprising:

heating said overhead gaseous stream by indirect heat exchange with an overhead gaseous stream removed from the top of said heavy ends fractionation column, and said overhead gaseous stream from the top of said heavy ends fractionation column is cooled by said indirect heat exchange;

introducing the cooled overhead gaseous stream from the top of said heavy ends fractionation column into said light ends fractionation column;

heating and compressing the heated overhead gaseous stream from the light ends fractionation column;

cooling and expanding said overhead gaseous stream from the light ends fractionation column;

splitting the cooled and expanded overhead gaseous stream from the light ends fractionation column into a first expanded stream and a second expanded stream;

introducing said first expanded stream into said light ends fractionation column;

introducing said second expanded stream into further separation means as said residue gas; and

introducing said liquid product stream from said further separation means into said LNG exchanger/separator.

13. A process according to claim 10, wherein said process further comprises introducing said liquid product stream recovered from said further separation means into said light ends fractionation column as said liquid reflux stream.

14. A process according to claim 10, wherein said process further comprises introducing said liquid product stream recovered from said further separation means into said heavy ends fractionation column as said liquid reflux stream.

15. A process according to claim 10, wherein said process further comprises removing a bottoms liquid stream from a lower region of said heavy ends fractionation column, heating said bottoms liquid stream from said heavy ends fractionation column in said feed heat exchanger, and returning said bottoms liquid stream from said heavy ends fractionation column to the lower region of said heavy ends fractionation column.

16. A process according to claim 10, wherein said process further comprises removing a liquid stream from a first intermediate point of said heavy ends fractionation column, heating said liquid stream removed from said heavy ends fractionation column by indirect heat exchange with the feed stream in said feed heat exchanger, and introducing said liquid stream into said heavy ends fractionation column at another intermediate point below said first intermediate point.

17. A process according to claim 10, wherein said process further comprises splitting said bottoms liquid stream from the gas/liquid cold separator in to a first bottom liquid stream and a second bottoms liquid stream, introducing said first bottom liquid stream into said heavy ends fractionation column, delivering said second bottoms liquid stream is delivered to a liquid/liquid heat exchanger for indirect heat exchange with bottom liquid stream removed from said light ends fractionation column, and then introducing said second bottoms liquid stream into an intermediate region of said light ends fractionation column as a liquid reflux.

18. A process according to claim 10, wherein said process further comprises:

splitting said overhead gaseous stream from said gas/liquid cold separator into a first cold separator overhead gaseous stream and a second cold separator overhead gaseous stream;

splitting said bottoms liquid stream from said gas/liquid cold separator into a first cold separator bottoms liquid stream and a second cold separator bottoms liquid stream;

combining said second cold separator overhead gaseous stream and said second cold separator bottoms liquid stream;

cooling the resultant combined stream by indirect heat exchange with an overhead vapor from said light ends fractionation column, and

introducing the cooled combined stream into the top region of said light ends fractionation column to provide reflux.