Multi-phase metering device for oilfield applications

• US 9,804,108 B2
• Filed: 11/18/2013
• Issued: 10/31/2017
• Est. Priority Date: 10/13/2010
• Status: Active Grant

• Current Assignee: PERM Inc.
• Original Assignee: Perm Instruments Inc.
• Inventors: Krioutchkov, Serguei I., Kantzas, Apostolos, Wang, Zhengyin
• Primary Examiner(s): Vargas, Dixomara
• Application Number:
  US14/083,308
• Publication Number:
  US 20140077806A1
• Time in Patent Office: 1,443 Days
• Field of Search: None
• CPC Class Codes: G01N 24/081 Making measurements of geologic samples, e.g. measurements of moisture, pH, porosity, permeability, tortuosity or viscosity
• CPC Class Codes: G01N 24/082 Measurement of solid, liquid or gas content
• CPC Class Codes: G01R 33/34053 Solenoid coils; Toroidal coils

Abstract

This application is related to a system and methods for sampling fluids and gases using nuclear magnetic resonance (NMR) technology. Specifically the system is related to an improved metallic pipe design for use at oil and gas well heads that includes integral coils for transmitting an NMR pulse sequence and detecting NMR signals and can be used as a component of an NMR instrument. The methods are related to obtaining and analyzing NMR spectra in stationary and flowing states.

Claims

1. A method of measuring the relative quantity of components in a high temperature and pressure fluid using nuclear magnetic resonance (NMR) relaxometry in an NMR pressure tube having a magnetic field, comprising the steps of:

a) calibrating the NMR pressure tube with a pure water sample by putting a pure water sample within the NMR pressure tube and applying an electromagnetic field to the pure water sample and recording a signal response using an NMR coil thereby providing a pure-water calibration curve;

b) calibrating the NMR pressure tube with a pure oil sample by putting a pure oil sample within the NMR pressure tube and applying an electromagnetic field to the pure oil sample and recording a signal response using the NMR coil thereby providing a pure-oil calibration curve;

c) introducing an at least two-component mixture into the NMR pressure tube;

d) measuring relaxation spectra of the mixture in the NMR pressure tube by applying an electromagnetic field to the mixture and recording a response using the NMR coil; and

e) calculating, using a processor, a quantity of oil and water in the at least two-component mixture by fitting the mixture relaxation spectra of step d) to a linear combination of the pure-water and pure-oil calibration curves of steps a) and b).

2. The method as in claim 1 wherein steps a) and b) include calculating total water amplitude and total oil amplitude respectively.

3. The method as in claim 2 further comprising repeating steps a) and b) over a selected temperature range.

4. The method as in claim 1 wherein during steps c) and d) the at least two-component mixture is stationary within the NMR pressure tube.

5. The method as in claim 4 wherein step e) includes averaging a component saturation value along a length of the NMR pressure tube.

6. The method as in claim 1 wherein during steps c) and d) the at least two-component mixture is flowing within the NMR pressure tube.

7. The method as in claim 1 wherein step e) includes calculating a volumetric component-cut and mass component-cut of one component of the mixture.

8. The method as in claim 1 wherein the at least two-component mixture includes different phases.

9. The method as in claim 8 wherein the different phases include a liquid phase and a gas phase.

10. The method as in claim 9 wherein the liquid phase is water.

11. The method as in claim 10 further comprising the step of calculating a gas-water ratio of the mixture.

12. The method as in claim 8 wherein the different phases include a hydrocarbon phase and a gas phase.

13. The method as in claim 12 further comprising the step of calculating a hydrocarbon-gas ratio of the mixture.

14. The method as in claim 1 wherein the at least two-component mixture includes a gas component, water component and hydrocarbon component.

15. The method as in claim 1 wherein the magnet and the applied electromagnetic fields are configured to obtain responses from hydrogen atoms from materials making up samples or mixtures within the NMR pressure tube.

16. An NMR apparatus for measuring the relative quantity of components in a high temperature and pressure fluid using nuclear magnetic resonance (NMR) relaxometry, the apparatus comprising:

an NMR pressure tube;

a magnet configured to apply a magnetic field within the NMR pressure tube;

an NMR coil configured to apply an electromagnetic field within the NMR pressure tube;

an electronic circuit for controlling the NMR coil to generate an electromagnetic field;

a data acquisition board for receiving an NMR response of a sample from the NMR coil;

a processor configured to process the NMR response to determine a quantity of oil and water in the sample by;

a) storing a pure-water calibration curve obtained by calibrating the NMR pressure tube with a pure water sample by putting a pure water sample within the NMR pressure tube and applying an electromagnetic field to the pure water sample and recording a signal response using the NMR coil;

b) storing a pure-oil calibration curve by calibrating the NMR pressure tube with a pure oil sample by putting a pure oil sample within the NMR pressure tube and applying an electromagnetic field to the pure oil sample and recording a signal response using the NMR coil;

c) receiving a mixture relaxation spectra corresponding to an at least two-component mixture within the NMR pressure tube, the relaxation spectra of the mixture in the NMR pressure tube having been obtained by applying an electromagnetic field to the mixture and recording a response using the NMR coil; and

d) calculating the quantity of oil and water in the at least two-component mixture by fitting the mixture relaxation spectra of step c) to a linear combination of the pure-water and pure-oil calibration curves of steps a) and b).