Carbon purification of concentrated sugar streams derived from pretreated biomass

• US 9,809,867 B2
• Filed: 03/14/2014
• Issued: 11/07/2017
• Est. Priority Date: 03/15/2013
• Status: Expired due to Fees

• Current Assignee: Apalta Tehnoloogia Ou
• Original Assignee: SweetWater Energy, Inc
• Inventors: Parekh, Sarad, Felice, Carl P.
• Primary Examiner(s): Mayes, Melvin C
• Assistant Examiner(s): Cohen, Stefanie
• Application Number:
  US14/776,411
• Publication Number:
  US 20160032414A1
• Time in Patent Office: 1,334 Days
• Field of Search: None
• CPC Class Codes: C12P 19/02 Monosaccharides 2-ketogulonic acid C12P7/60
• CPC Class Codes: C12P 2203/00 Fermentation products obtained from optionally pretreated or hydrolyzed cellulosic or lignocellulosic material as the carbon source
• CPC Class Codes: C13K 1/04 Purifying
• CPC Class Codes: C13K 13/002 Xylose
• CPC Class Codes: C13K 13/007 Separation of sugars provided for in subclass C13K C13K3/00 takes precedence

Abstract

Provided are methods and compositions using activated carbon for optimizing purification and clarification of sugar streams produced from cellulosic or lignocellulosic biomass. Also provided are methods and compositions for decreasing one or more undesirable products during pretreatment.

Claims

1. A method of refining a sugar stream, the method comprising:

(a) acidifying the sugar stream to a pH of from about 1 to about 4 by adding an acid to produce an acidified sugar stream;

(b) heating activated carbon to a temperature of from about 100°

C. to about 300°

C. to produce heat activated carbon; and

(c) contacting the acidified sugar stream with the heat activated carbon for a sufficient time to produce a refined sugar stream.

2. The method of claim 1, wherein the heat activated carbon is at a higher temperature than the acidified sugar stream during the contacting.

3. The method of claim 1, further comprising pretreating or hydrolyzing a biomass comprising cellulosic, hemicellulosic, or lignocellulosic material to produce the sugar stream.

4. The method of claim 1, wherein the refined sugar stream comprises at least about 30% less of one or more inhibitors than the sugar stream.

5. The method of claim 4, wherein the one or more inhibitors comprise hydroxymethylfurfural, furfural, or a combination thereof.

6. The method of claim 1, wherein the refined sugar stream has a transparency that is at least about 20% higher than the sugar stream when measured at 600 nm.

7. The method of claim 1, wherein the refined sugar stream comprises at least about 30% less phenolic and aromatic compounds than the sugar stream when measured at 205 nm or 289 nm.

8. The method of claim 1, wherein the sugar stream comprises at least about 15% w/v of one or more sugars.

9. The method of claim 1, wherein the heat activated carbon is at from 2% to about 10% w/v in the sugar stream during the contacting.

10. The method of claim 1, further comprising removing the heat activated carbon from the refined sugar stream.

11. The method of claim 10, wherein removing the heat activated carbon from the refined sugar stream comprises adding diatomaceous earth to the sugar stream.

12. A method of refining a sugar stream, the method comprising:

(a) heating activated carbon to a temperature of from about 100°

C. to about 300°

C. to produce heat activated carbon;

(b) contacting the sugar stream with the heat activated carbon for a sufficient time to produce a refined sugar stream, wherein the heat activated carbon is at a temperature greater than the sugar stream.

13. The method of claim 12, wherein the heat activated carbon is at from 2% to about 10% w/v in the sugar stream during the contacting.

14. The method of claim 12, wherein the refined sugar stream comprises at least about 30% less of one or more inhibitors than the sugar stream.

15. The method of claim 14, wherein the one or more inhibitors comprise hydroxymethylfurfural, furfural, or a combination thereof.

16. The method of claim 12, wherein the refined sugar stream has a transparency that is at least about 20% higher than the sugar stream when measured at 600 nm.

17. The method of claim 12, wherein the refined sugar stream comprises at least about 70% less phenolic and aromatic compounds than the sugar stream when measured at 205 nm or 289 nm.

18. The method of claim 12, wherein the heat activated carbon is at from 2% to about 10% w/v in the sugar stream during the contacting.