Ink for ink-jet printing, printed cylindrical containers and method for producing the same

• US 9,815,995 B2
• Filed: 01/31/2013
• Issued: 11/14/2017
• Est. Priority Date: 02/03/2012
• Status: Active Grant

• Current Assignee: TOMATEC Co., Ltd. (Toyo Seikan Group Holdings, Ltd.)
• Original Assignee: Tokan Material Technology Co., Ltd., Toyo Seikan Group Holdings, Ltd.
• Inventors: Yamada, Koji, Hayashi, Kenji, Saito, Yukiko, Shimomura, Hiroshi
• Primary Examiner(s): Klemanski, Helene
• Application Number:
  US14/373,394
• Publication Number:
  US 20150010722A1
• Time in Patent Office: 1,748 Days
• Field of Search: 106 3105, 106 3106, 106 3127, 106 3137, 106 3158, 106 3159, 106 316, 106 3169, 106 3186, 106 3189, 347 21, 428 357
• CPC Class Codes: B41J 2/01 Ink jet
• CPC Class Codes: B41J 3/40733 Printing on cylindrical or rotationally symmetrical objects, e. g. on bottles
• CPC Class Codes: B41M 5/0088 by ink-jet printing
• CPC Class Codes: B41M 7/009 using thermal means, e.g. infrared radiation, heat
• CPC Class Codes: C08K 13/02 Organic and inorganic ingredients
• CPC Class Codes: C09D 11/10 based on artificial resins
• CPC Class Codes: C09D 11/322 Pigment inks
• CPC Class Codes: C09D 11/36 based on non-aqueous solvents
• CPC Class Codes: C09D 11/38 characterised by non-macromolecular additives other than solvents, pigments or dyes
• CPC Class Codes: Y10T 428/1352 Polymer or resin containing [i.e., natural or synthetic]

Abstract

An ink for ink-jet printing used for ink-jet printing images onto the ink non-absorptive surfaces of cylindrical containers, and comprising at least a water-soluble solvent, a coloring material, a surfactant, a thickener and/or a binder resin, the coloring material being contained in an amount of 5 to 20% by weight, the surfactant in an amount of 0.1 to 5% by weight, the thickener in an amount of not more than 10% by weight, and the binder resin being contained in an amount of not more than 30% by weight. Owing to its ink-jet printability, the ink for ink-jet printing of the invention can be favorably used for printing images on the non-absorptive cylindrical containers such as seamless cans that are used for containing beverages and foods.

Claims

1. A method of producing a printed cylindrical container by effecting an ink-jet printing on an ink non-absorptive surface of the cylindrical container by using an ink for ink-jet printing, and applying a finishing varnish on the ink non-absorptive surface, wherein

the ink for ink-jet printing comprises at least a water-soluble solvent, a coloring material selected from the group consisting of an inorganic pigment, an organic pigment and a dye, a surfactant, a thickener and/or a binder resin, the coloring material is contained in an amount of 5 to 20% by weight, the surfactant is contained in an amount of 0.1 to 5% by weight, the thickener is contained in an amount of not more than 10% by weight, and the binder resin is contained in an amount of not more than 30% by weight.

2. The method of producing a printed cylindrical container according to claim 1, wherein said binder resin comprises any one of an urethane resin, an epoxy resin, a polyester resin, a melamine resin or an acrylic resin, and is contained in an amount of 5 to 30% by weight.

3. The method of producing a printed cylindrical container according to claim 1, wherein said water-soluble solvent is at least one of a dialkyl glycol ether solvent, an ethylene glycol ether solvent or a propylene glycol ether solvent.

4. The method of producing a printed cylindrical container according to claim 1, wherein said water-soluble solvent has a boiling point of not lower than 120°

C.

5. The method of producing a printed cylindrical container according to claim 1, wherein said thickener is at least one of a cellulose ether soluble in alcohol or a polyvinyl acetal soluble in alcohol.

6. The method of producing a printed cylindrical container according to claim 1, wherein said surfactant is a siloxane modified with polyether.

7. The method of producing a printed cylindrical container according to claim 1, wherein said finishing varnish layer comprises an aqueous finishing varnish using, as the base resin, any one of an acrylepoxy resin, acrylamino resin, polyester resin or polyesteramino resin.

8. The method of producing a printed cylindrical container according to claim 1, wherein a white coating and/or an anchor coating is formed under the ink-jet-printed layer.

9. The method of producing a printed cylindrical container according to claim 1, wherein the image that is ink-jet-printed is false-baked before applying the finishing varnish and, thereafter, the finishing varnish that is applied is baked and cured.

10. The method of producing a printed cylindrical container according to claim 1, wherein the image is printed by the plate-type printing before or after the ink-jet printing.

11. The method of producing a printed cylindrical container according to claim 1, wherein the ink-jet printing is effected through at least one ink-jet printing station in which a plurality of ink-jet heads are arranged.

12. The method of producing a printed cylindrical container according to claim 1, wherein the temperature on the ink non-absorptive surface of the cylindrical container is adjusted to lie in a range of 25 to 100°

C. before the inkjet printing on the ink non-absorptive surface.