Use of a transparent composition for photobioreactors

• US 9,816,064 B2
• Filed: 09/11/2015
• Issued: 11/14/2017
• Est. Priority Date: 01/22/2009
• Status: Active Grant

• Current Assignee: Trinseo Europe Gmbh
• Original Assignee: Arkema France (Arkema)
• Inventors: Delprat, Patrick, Berge, Jerome, Boutillier, Jean-Marc
• Primary Examiner(s): Nutter, Nathan M
• Application Number:
  US14/851,721
• Publication Number:
  US 20160002581A1
• Time in Patent Office: 795 Days
• CPC Class Codes: C12M 21/02 Photobioreactors culturing algae A01G33/00, A01H4/001, C12N1/12
• CPC Class Codes: C12M 23/20 Material Coatings immunocoatings C12M25/00
• CPC Class Codes: C12M 23/22 Transparent or translucent parts glassware for laboratory use B01L3/00
• CPC Class Codes: C12M 39/00 Means for cleaning the apparatus or avoiding unwanted deposits of microorganisms apparatus for cleaning laboratory receptacles or instruments B01L13/02; cleaning in general B08B
• CPC Class Codes: Y10T 428/1393 Multilayer [continuous layer]
• CPC Class Codes: Y10T 428/3154 Of fluorinated addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/3175 Next to addition polymer from unsaturated monomer[s]
• CPC Class Codes: Y10T 428/31855 Of addition polymer from unsaturated monomers

Abstract

The present invention relates to photobioreactors and more particularly to the use of a transparent composition based on at least one methacrylic polymer for constructing installations for the culture of photosensitive organisms. This composition can be in the form of films, plates, profiled elements or cylinders such as tubes.

The invention also relates to a transparent multilayer structure comprising at least one layer of a methacrylic polymer and one layer comprising at least one antifouling additive, and to the use thereof for constructing installations for the culture of photosensitive organisms.

Claims

1. A photobioreactor for the culture of photosensitive organisms comprising a transparent composition of at least one methacrylic polymer wherein the methacrylic polymer is a copolymer of methyl methacrylate (MMA), comprising from 90 to 99.9% by weight of MMA and from 0.1 to 10% by weight of a comonomer, said methacrylic polymer having a weight-average molecular weight ranging from 140 000 g/mol to 160 000 g/mol (PMMA standard), wherein said composition comprises at least one antifouling and/or antistatic additive.

2. The photobioreactor of claim 1, wherein said antifouling and/or antistatic additive is a copolymer comprising polyamide blocks and polyether blocks that is present at a content ranging from 3% to 15% by weight relative to the total composition.

3. The photobioreactor of claim 1, wherein said antifouling and/or antistatic additive is a fluoropolymer chosen from homopolymers and copolymers of vinylidene fluoride (VDF) containing at least 50% by weight of VDF;

copolymers of tetrafluoroethylene and of ethylene (ETFE);

homopolymers and copolymers of trifluoroethylene (VF₃);

copolymers combining VDF and tetrafluoroethylene (EFEP);

copolymers, combining the residues of chlorotrifluoroethylene (CTFE), tetrafluoroethylene (TFE), hexafluoropropylene (HFP) and/or ethylene units;

terpolymers combining the residues of chlorotrifluoroethylene (CTFE), tetrafluoroethylene (TFE), hexafluoropropylene (HFP) and/or ethylene units and, optionally, VDF and/or VF₃ units, the fluoropolymer being present at a content ranging from 5 to 60% by weight relative to the total composition.

4. The photobioreactor of claim 3, wherein said fluoropolymer is a PVDF homopolymer or copolymer containing at least 75% of VDF.

5. The photobioreactor of claim 1, wherein said composition is in the form of films, plates, profiled elements or cylinders.

14. The photobioreactor of claim 1, wherein said photosensitive organisms, are selected from the group consisting of photo synthetic bacteria, microalgae, microorganisms, and plankton.

6. A multilayer structure comprising at least:

one or more transparent composition layers of at least one methacrylic polymer, wherein the methacrylic polymer is a copolymer of methyl methacrylate (MMA), comprising from 90 to 99.9% by weight of MMA and from 0.1 to 10% by weight of a comonomer, wherein the methacrylic polymer having a weight-average molecular weight ranging from 140 000 to 160 000 g/mol (PMMA standard);

one or more antifouling layers comprising at least one antifouling additive, wherein the one or more antifouling layers is in contact with a culture medium; and

wherein the one or more transparent composition layers and the one or more antifouling layers are directly in contact with one another.

7. The multilayer structure as claimed in claim 6, wherein the layer that is in contact with a culture medium consists either of an antifouling methacrylic polymer defined as a methacrylic polymer to which has been added at least one antifouling additive chosen from copolymers comprising polyamide blocks and polyether blocks or fluoropolymers, or an antifouling fluoropolymer.

8. The multilayer structure as claimed in claim 6, comprising, in the following order, at least:

one layer comprising at least one antistatic additive that is in contact with the air or the outside environment,

one layer of at least one methacrylic polymer,

one layer comprising at least one antifouling additive that is in contact with a culture medium.

9. The structure as claimed in claim 8, wherein the layer in contact with the air or the outside environment consists of an antistatic methacrylic polymer, defined as a methacrylic polymer to which has been added from 5 to 10% of an antistatic additive chosen from copolymers comprising polyamide blocks and polyether blocks.

10. The multilayer structure as claimed in claim 6, wherein said structure is in the form of a tube, a profiled element or a plate.

11. The multilayer tube as claimed in claim 10, wherein said tube has a diameter ranging from 2 to 100 cm and a length from 1 to 50 m.

12. The multilayer plate as claimed in claim 10, wherein said plate has a thickness ranging from 1 to 100 mm.

13. The multilayer structure as claimed in claim 6, comprising an installation for the culture of photosensitive organisms.

15. The photobioreactor of claim 13, wherein said photosensitive organisms, are selected from the group consisting of photosynthetic bacteria, microalgae, microorganisms, and plankton.