Low emissivity film

• US 9,822,229 B2
• Filed: 05/21/2008
• Issued: 11/21/2017
• Est. Priority Date: 05/24/2007
• Status: Active Grant

• Current Assignee: Innovia Films Limited (Innovia Films)
• Original Assignee: Innovia Films Limited (Innovia Films)
• Inventors: Marshall, Colin, Watters, Paul
• Primary Examiner(s): Golden, Chinessa
• Application Number:
  US12/601,246
• Publication Number:
  US 20100173145A1
• Time in Patent Office: 3,471 Days
• Field of Search: None
• CPC Class Codes: C08J 2475/00 Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
• CPC Class Codes: C08J 7/0427 with only one layer of a composition containing a polymer binder with more layers C08J7/042
• CPC Class Codes: C08J 7/043 Improving the adhesiveness of the coatings per se, e.g. forming primers adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50
• CPC Class Codes: C08J 7/048 Forming gas barrier coatings
• CPC Class Codes: C08K 3/08 Metals
• CPC Class Codes: C09D 5/38 Paints containing free metal not provided for above in groups C09D5/00 - C09D5/36
• CPC Class Codes: C09D 7/61 inorganic
• CPC Class Codes: C09D 7/70 characterised by shape, e.g. fibres, flakes or microspheres
• CPC Class Codes: Y10T 428/249978 Voids specified as micro
• CPC Class Codes: Y10T 428/25 Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
• CPC Class Codes: Y10T 428/273 of coating
• CPC Class Codes: Y10T 428/31544 Addition polymer is perhalogenated
• CPC Class Codes: Y10T 428/31609 Particulate metal or metal compound-containing
• CPC Class Codes: Y10T 428/31678 Of metal

Abstract

The present invention concerns a functional film material comprising a substrate layer and a coating layer, the coating layer comprising a block copolymeric binder and a particulate metal pigment therein, the ratio of pigment to binder in the coating layer being selected with reference to the coat weight to provide the functional film material with an emissivity of less than 0.5, and the substrate and coating layer being selected to provide the film with a VWTR (ambient) in excess 400 gm⁻² d⁻¹ bar⁻¹.

Claims

1. A functional film material for providing an insulation regime facilitated by low emissivity comprising:

a substrate layer selected from cellulose acetate, cellulose and derivatives thereof; and

a coating layer forming the outermost layer of the film, the coating layer comprising;

a block copolymeric binder, and

a particulate metal pigment therein,

a ratio of pigment to binder in the coating layer being selected with reference to a coat weight and to be within a range from 3;

1 to 1;

10 to provide the functional film material with an emissivity 0.5 or less;

the substrate and coating layer being selected to provide the film with an ambient water vapor transmission rate (WVTR (ambient)) in excess of 400 gm<sup>−

2</sup> d<sup>−

1</sup> bar<sup>−

1</sup>, wherein the WVTR of the substrate is at least 10 gm<sup>−

2</sup> d<sup>−

1</sup> bar<sup>−

1</sup> higher than the coating layer and

wherein the substrate layer has a higher WVTR than the coating layer, such that the determining factor of the WVTR of the film as a whole is the coating layer.

2. The functional film material according to claim 1 wherein the substrate layer has a WVTR (ambient) in excess of 400 gm⁻

2 d<sup>−

1</sup> bar<sup>−

1</sup>.

3. The functional film material according to claim 1 wherein the substrate layer has an oxygen permeability (OTR) of less than about 30 cm³ m⁻

2 d<sup>−

1</sup> bar<sup>−

1</sup>.

4. The functional film material according to claim 1 wherein the substrate layer is cellulose acetate.

5. The functional film material according to claim 1 wherein the substrate layer is regenerated cellulose.

6. The functional film material according to claim 1 wherein the block copolymeric binder is selected from materials comprising a hard and soft segment polymer of the type configured for fabrics allowing breathability.

7. The functional film material according to claim 6 wherein the block copolymeric binder is selected from hydrophilic polyurethanes.

8. The functional film material according to claim 1 wherein the particulate metal material is a polished metal material.

9. The functional film material according to claim 8 wherein the polished metal material is selected from the group consisting of aluminium, bronze, stainless steel, brass, gold, nickel, silver, silver coated glass, tin, copper, and mixtures of two or more thereof.

10. The functional film material according to claim 1 wherein the particulate metal material has a predominantly lamellar or plate-like form.

11. The functional film material according to claim 10 wherein a median aspect ratio of the particulate metal material is at least about 10:

1.

12. The functional film according claim 1 wherein the emissivity of the film is less than about 0.45.

13. The functional film according to claim 12 wherein the emissivity of the film is less than about 0.4.

14. The functional film according to claim 1 wherein the film substrate layer has a WVTR (ambient) in excess of 400 gm⁻

2 d<sup>−

1</sup> bar<sup>−

1</sup> and the coating layer is at least one of the group consisting of;

a semi-permeable membrane and a microporous layer.

15. The functional film according to claim 1 wherein the coat weight is from about 0.8 to about 2.5 gm⁻

2.

16. The functional film material according to claim 15 wherein at least one of the film and the substrate layer has a WVTR (ambient) in excess of 1000 gm⁻

2 d<sup>−

1</sup> bar<sup>−

1</sup>.

17. The functional film material according to claim 1 wherein at least one of the film and the substrate layer has a WVTR (ambient) in excess of 500 gm⁻

2 d<sup>−

1</sup> bar<sup>−

1</sup>.

18. The functional film material according to claim 1 wherein at least one of the substrate and the coating is a semi-permeable membrane.

19. The functional film material according to claim 1 wherein at least one of the substrate and the coating is microporous.