Stable emissive toner composition system and method

• US 9,823,594 B2
• Filed: 10/17/2016
• Issued: 11/21/2017
• Est. Priority Date: 08/21/2007
• Status: Active Grant

• Current Assignee: Angstrom Technologies, Inc.
• Original Assignee: Angstrom Technologies, Inc.
• Inventors: Coyle, William J., Stramondo, Anthony
• Primary Examiner(s): Vajda, Peter
• Assistant Examiner(s): ALAM, RASHID A
• Application Number:
  US15/295,638
• Publication Number:
  US 20170031255A1
• Time in Patent Office: 400 Days
• Field of Search: 4301371
• CPC Class Codes: G03G 9/0821 characterised by physical parameters magnetic parameters G03G9/083
• CPC Class Codes: G03G 9/08704 Polyalkenes
• CPC Class Codes: G03G 9/08711 with esters of acrylic or methacrylic acid
• CPC Class Codes: G03G 9/0926 characterised by physical or chemical properties
• CPC Class Codes: G03G 9/0928 Compounds capable to generate colouring agents by chemical reaction
• CPC Class Codes: G03G 9/09733 Organic compounds G03G9/08782 takes precedence
• CPC Class Codes: G03G 9/16 Developers not provided for in groups G03G9/06 - G03G9/135, e.g. solutions, aerosols

Abstract

A method of producing an emissive toner composition including selecting a photoluminescent agent, a charge control agent, and one or more additives and combining the photoluminescent agent, charge control agent, and one or more additives to form an emissive toner composition that when printed to produce an image component on a substrate, the emission spectra of the image component for irradiation with a first excitation energy includes only dominant emission peaks corresponding to one or more dominant emission peaks of the photoluminescent agent. The photoluminescent agent is selected such that it emits light having one or more dominant emission peaks in a first emission spectral region when irradiated with the first excitation energy. The charge control agent and one or more additives are selected such that they do not emit light in the visible spectrum when irradiated with visible light and does not emit light in the first emission spectral region when irradiated with the first excitation energy.

Claims

1. An emissive toner composition for marking an article with an image indicia for authentication, information, or decoration, the composition comprising:

a photoluminescent agent that emits light having one or more dominant emission peaks in the visible spectrum, each of the one or more dominant emission peaks centered at a corresponding emission wavelength, when irradiated with energy in the infrared spectral region;

a charge control agent that is chemically compatible with the photoluminescent agent and that does not emit light in the visible spectrum when irradiated with visible light and does not emit light in the visible spectrum when irradiated with energy in the infrared spectral region;

one or more additives that are compatible with the photoluminescent agent and the charge control agent and that do not emit light in the visible spectrum when irradiated with visible light and do not emit light in the visible spectrum when irradiated with energy in the infrared spectral region; and

the photoluminescent agent, the charge control agent, and the one or more additives forming an emissive toner composition having an emission spectra that includes only dominant emission peaks corresponding to the one or more dominant emission peaks of the photoluminescent agent, as measured in an image component printed on a substrate and irradiated with energy in the infrared spectral region.

2. A toner composition according to claim 1, wherein the image component has a photoluminescent toner stability factor of about greater than or equal to 25, wherein the photoluminescent toner stability factor is calculated according to the following equation:

PTSF=((1−

ALF-XE)×

ALF-QUV)×

100,

where PTSF is the photoluminescent toner stability factor, ALF-XE is the average loss in photoluminescence of the image component from day 3 to day 7 of a seven day xenon-arc exposure at 0.35 W/m² at 340 nm with the image component distanced from the xenon arc exposure at 10 inches and a temperature of 50degrees Celcius, and ALF-QUV is the average loss in photoluminescence of the image component from day 3 to day 7 of submission of the image component to QUV exposure conditions.

3. A toner composition according to claim 2, wherein the image component has a photoluminescent toner stability factor of about greater than or equal to 35.

4. A toner composition according to claim 2, wherein the image component has a photoluminescent toner stability factor of about greater than or equal to 48.

5. A toner composition according to claim 1, wherein the one or more dominant emission peaks include only a single dominant emission peak.

6. A toner composition according to claim 1, wherein the photoluminescent agent does not emit light in the visible spectrum when irradiated with visible light.

7. A toner composition according to claim 1, wherein the photoluminescent agent, charge control agent, and one or more additives are selected and present in an amount in the toner composition such that the image component is reflectively visible.

8. A toner composition according to claim 1, wherein the photoluminescent agent, charge control agent, and one or more additives are selected and present in an amount in the toner composition such that the image component is reflectively invisible.

9. A toner composition according to claim 1, wherein said charge control agent includes a charge control agent selected from the group consisting of:

a calixarene compound that does not emit light in the visible spectrum when irradiated with visible light and does not emit light in the visible spectrum when irradiated with said energy in the infrared spectral region;

a modified layered silicate that does not emit light in the visible spectrum when irradiated with visible light and does not emit light in the visible spectrum when irradiated with energy in the infrared spectral region;

a hydrophobically modified metal oxide that does not emit light in the visible spectrum when irradiated with visible light and does not emit light in the visible spectrum when irradiated with energy in the infrared spectral region.

10. An emissive toner composition for marking an article with an image indicia for authentication, information, or decoration, the composition comprising:

a photoluminescent agent that emits light having one or more dominant emission peaks in the visible spectrum, each of the one or more dominant emission peaks centered at a corresponding emission wavelength, when irradiated with energy in the infrared spectral region, the photoluminescent agent not emitting light in the visible spectrum when irradiated with visible light;

a charge control agent that is chemically compatible with the photoluminescent agent and that does not emit light in the visible spectrum when irradiated with visible light and does not emit light in the visible spectrum when irradiated with energy in the infrared spectral region, the charge control agent being present in a charge control effective amount and the charge control effective amount being reflectively invisible;

one or more additives that are compatible with the photoluminescent agent and the charge control agent and that do not emit light in the visible spectrum when irradiated with visible light and do not emit light in the visible spectrum when irradiated with energy in the infrared spectral region; and

the photoluminescent agent, the charge control agent, and the one or more additives forming an emissive toner composition having an emission spectra that includes only dominant emission peaks corresponding to the one or more dominant emission peaks of the photoluminescent agent, as measured in an image component printed on a substrate and irradiated with energy in the infrared spectral region.

11. A toner composition according to claim 10, wherein the image component has a photoluminescent toner stability factor of about greater than or equal to 25, wherein the photoluminescent toner stability factor is calculated according to the following equation:

PTSF=((1−

ALF-XE)×

ALF-QUV)×

100,

where PTSF is the photoluminescent toner stability factor, ALF-XE is the average loss in photoluminescence of the image component from day 3 to day 7 of a seven day xenon-arc exposure at 0.35 W/m² at 340 nm with the image component distanced from the xenon arc exposure at 10 inches and a temperature of 50degrees Celcius, and ALF-QUV is the average loss in photoluminescence of the image component from day 3 to day 7 of submission of the image component to QUV exposure conditions.

12. A toner composition according to claim 11, wherein the image component has a photoluminescent toner stability factor of about greater than or equal to 35.

13. A toner composition according to claim 11, wherein the image component has a photoluminescent toner stability factor of about greater than or equal to 40.

14. A toner composition according to claim 10, wherein the one or more dominant emission peaks include only a single dominant emission peak.

15. A toner composition according to claim 10, wherein the photoluminescent agent, charge control agent, and one or more additives are selected and present in an amount in the toner composition such that the image component is reflectively visible.

16. A toner composition according to claim 10, wherein the photoluminescent agent, charge control agent, and one or more additives are selected and present in an amount in the toner composition such that the image component is reflectively invisible.

17. A toner composition according to claim 10, wherein said charge control agent includes a charge control agent selected from the group consisting of:

a calixarene compound that does not emit light in the visible spectrum when irradiated with visible light and does not emit light in the visible spectrum when irradiated with said energy in the infrared spectral region;

a modified layered silicate that does not emit light in the visible spectrum when irradiated with visible light and does not emit light in the visible spectrum when irradiated with energy in the infrared spectral region;

a hydrophobically modified metal oxide that does not emit light in the visible spectrum when irradiated with visible light and does not emit light in the visible spectrum when irradiated with energy in the infrared spectral region.

18. An emissive toner composition for producing an emissive image component of an image indicia on a substrate, the composition comprising:

a photoluminescent agent that emits light having one or more emission peaks in the visible spectrum, each of said one or more emission peaks centered at a corresponding emission wavelength, when irradiated with energy in the infrared spectral region;

a charge control agent; and

one or more additives,

said photoluminescent agent, charge control agent, and one or more additives forming a toner composition having an emission spectra that includes only dominant emission peaks in the visible spectrum corresponding to said one or more emission peaks of said photoluminescent agent, as measured in an image component printed on a substrate and irradiated with energy in the infrared spectral region, wherein the image component has a photoluminescent toner stability factor of about greater than or equal to 25, wherein the photoluminescent toner stability factor is calculated according to the following equation;

PTSF=((1−

ALF-XE)×

ALF-QUV)×

100,

where PTSF is the photoluminescent toner stability factor, ALF-XE is the average loss in photoluminescence of said image component from day 3 to day 7 of a seven day xenon-arc exposure at 0.35 W/m² at 340 nm with said image component distanced from said xenon arc exposure at 10 inches and a temperature of 50 degrees Celsius, ALF-QUV is the average loss in photoluminescence of said image component from day 3 to day 7 of submission of said image component to QUV exposure conditions.