Metal oxide film and method for forming metal oxide film

• US 9,831,274 B2
• Filed: 06/09/2015
• Issued: 11/28/2017
• Est. Priority Date: 11/08/2012
• Status: Active Grant

• Current Assignee: Semiconductor Energy Laboratory Co., Ltd.
• Original Assignee: Semiconductor Energy Laboratory Co., Ltd.
• Inventors: Takahashi, Masahiro, Hirohashi, Takuya, Tsubuku, Masashi, Ishihara, Noritaka, Oota, Masashi
• Primary Examiner(s): Mondt, Johannes P
• Application Number:
  US14/734,080
• Publication Number:
  US 20150270405A1
• Time in Patent Office: 903 Days
• Field of Search: None
• CPC Class Codes: C23C 14/086 of zinc, germanium, cadmium, indium, tin, thallium or bismuth
• CPC Class Codes: G01N 23/207 Diffractometry using detectors, e.g. using a probe in a central position and one or more displaceable detectors in circumferential positions
• CPC Class Codes: G02F 1/1368 in which the switching element is a three-electrode device G02F1/136277 takes precedence
• CPC Class Codes: H01L 21/0237 Materials
• CPC Class Codes: H01L 21/02422 Non-crystalline insulating materials, e.g. glass, polymers
• CPC Class Codes: H01L 21/02554 Oxides
• CPC Class Codes: H01L 21/02565 Oxide semiconducting materials not being Group 12/16 materials, e.g. ternary compounds
• CPC Class Codes: H01L 21/02631 Physical deposition at reduced pressure, e.g. MBE, sputtering, evaporation
• CPC Class Codes: H01L 22/12 for structural parameters, e.g. thickness, line width, refractive index, temperature, warp, bond strength, defects, optical inspection, electrical measurement of structural dimensions, metallurgic measurement of diffusions electrical measurement of diffusions H01L22/14
• CPC Class Codes: H01L 27/1225 with semiconductor materials not belonging to the group IV of the periodic table, e.g. InGaZnO
• CPC Class Codes: H01L 29/04 characterised by their crystalline structure, e.g. polycrystalline, cubic or particular orientation of crystalline planes characterised by physical imperfections H01L29/30
• CPC Class Codes: H01L 29/24 including, apart from doping materials or other impurities, only semiconductor materials not provided for in groups H01L29/16, H01L29/18, H01L29/20, H01L29/22 including organic materials H10K99/00
• CPC Class Codes: H01L 29/66969 of devices having semiconductor bodies not comprising group 14 or group 13/15 materials comprising selenium or tellurium in uncombined form other than as impurities in semiconductor bodies of other materials, comprising cuprous oxide or cuprous iodide H01L21/02365
• CPC Class Codes: H01L 29/7869 having a semiconductor body comprising an oxide semiconductor material, e.g. zinc oxide, copper aluminium oxide, cadmium stannate
• CPC Class Codes: H01L 29/78693 the semiconducting oxide being amorphous
• CPC Class Codes: H01L 2924/00 Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
• CPC Class Codes: H01L 2924/0002 Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00

Abstract

A metal oxide film including a crystal part and having highly stable physical properties is provided. The size of the crystal part is less than or equal to 10 nm, which allows the observation of circumferentially arranged spots in a nanobeam electron diffraction pattern of the cross section of the metal oxide film when the measurement area is greater than or equal to 5 nmφ and less than or equal to 10 nmφ.

Claims

1. An oxide semiconductor film including crystals,

wherein a first plurality of circumferentially distributed spots are observable in a measurement area greater than or equal to an area with a diameter of 5 nmφ

and less than or equal to an area with a diameter of 10 nmφ

in a nanobeam electron diffraction pattern of a cross-section of the oxide semiconductor film,

wherein there is no difference between the first plurality of circumferentially distributed spots and a second plurality of circumferentially distributed spots which are observable in a nanobeam electron diffraction of a cross-section in which a measurement area is 5 nmφ

or more and 10 nmφ

or less with respect to the same oxide semiconductor film including the crystals after being irradiated with an electron beam whose beam diameter is converged to about 1 nmφ

for one minute,

wherein an acceleration voltage for the electron beam is 200 kV, and

wherein a crystalline peak is not observable in an XRD spectrum with respect to the oxide semiconductor film.

2. The oxide semiconductor film according to claim 1, wherein the oxide semiconductor film comprises one of indium, gallium, and zinc.

3. The oxide semiconductor film according to claim 1, wherein a halo pattern is observable in a selected-area electron diffraction pattern of a plane using a transmission electron microscope where a diameter of an electron beam is 300 nmφ

or more.

4. The oxide semiconductor film according to claim 1, wherein the oxide semiconductor film further comprises an amorphous part.

5. An oxide semiconductor film including crystals,

wherein size of one of the crystals is less than or equal to 10 nm,

wherein a first plurality of circumferentially distributed spots are observable in a measurement area greater than or equal to an area with a diameter of 5 nmφ

and less than or equal to an area with a diameter of 10 nmφ

in a nanobeam electron diffraction pattern of a cross-section of the oxide semiconductor film,

wherein there is no difference between the first plurality of circumferentially distributed spots and a second plurality of circumferentially distributed spots which are observable in a nanobeam electron diffraction of a cross-section in which a measurement area is 5 nmφ

or more and 10 nmφ

or less with respect to the same oxide semiconductor film including the crystals after being irradiated with an electron beam whose beam diameter is converged to about 1 nmφ

for one minute,

wherein an acceleration voltage for the electron beam is 200 kV, and

wherein a crystalline peak is not observable in an XRD spectrum with respect to the oxide semiconductor film.

6. The oxide semiconductor film according to claim 5, wherein the oxide semiconductor film comprises one of indium, gallium, and zinc.

7. The oxide semiconductor film according to claim 5, wherein a halo pattern is observable in a selected-area electron diffraction pattern of a plane using a transmission electron microscope where a diameter of an electron beam is 300 nmφ

or more.

8. The oxide semiconductor film according to claim 5, wherein the oxide semiconductor film further comprises an amorphous part.

9. An oxide semiconductor film including crystals,

wherein a first plurality of circumferentially distributed spots are observable in a measurement area greater than or equal to an area with a diameter of 5 nmφ

and less than or equal to an area with a diameter of 10 nmφ

in a nanobeam electron diffraction pattern of a cross-section of the oxide semiconductor film,

wherein spots having order of regularity that represents a crystal state in which crystals are aligned with a specific plane are observable in a nanobeam electron diffraction of a cross-section in which a diameter of an electron beam is converged to about 1 nmφ

in a cross-sectional direction of the measurement area of a film thinned from the oxide semiconductor film to be less than or equal to 10 nm,

wherein there is no difference between the first plurality of circumferentially distributed spots and a second plurality of circumferentially distributed spots which are observable in a nanobeam electron diffraction of a cross-section in which a measurement area is 5 nmφ

or more and 10 nmφ

or less with respect to the same oxide semiconductor film including the crystals after being irradiated with an electron beam whose beam diameter is converged to about 1 nmφ

for one minute, and

wherein an acceleration voltage for the electron beam is 200 kV, and

wherein a crystalline peak is not observable in an XRD spectrum with respect to the oxide semiconductor film.

10. The oxide semiconductor film according to claim 9, wherein the oxide semiconductor film comprises one of indium, gallium, and zinc.

11. The oxide semiconductor film according to claim 9, wherein size of one of the crystals is less than or equal to 10 nm.

12. The oxide semiconductor film according to claim 9, wherein a halo pattern is observable in a selected-area electron diffraction pattern of plane using a transmission electron microscope where a diameter of an electron beam is 300 nmφ

or more.

13. The oxide semiconductor film according to claim 9, wherein the oxide semiconductor film further comprises an amorphous part.