Rubber compositions and uses thereof

• US 9,840,611 B2
• Filed: 10/20/2014
• Issued: 12/12/2017
• Est. Priority Date: 10/18/2013
• Status: Active Grant

• Current Assignee: Soucy Techno Inc. (Soucy Holding Incorporated)
• Original Assignee: Soucy Techno Inc. (Soucy Holding Incorporated)
• Inventors: Bdard, Franois, Dub, Denis, MacDonald, Lyle, Cou, Jean-Damien
• Primary Examiner(s): JONES JR., ROBERT STOCKTON
• Application Number:
  US15/028,433
• Publication Number:
  US 20160272793A1
• Time in Patent Office: 1,149 Days
• CPC Class Codes: C08K 3/04 Carbon
• CPC Class Codes: C08K 3/041 Carbon nanotubes
• CPC Class Codes: C08K 3/36 Silica
• CPC Class Codes: C08K 7/02 Fibres or whiskers
• CPC Class Codes: C08K 7/24 inorganic
• CPC Class Codes: C08L 21/00 Compositions of unspecified rubbers
• CPC Class Codes: C08L 9/02 Copolymers with acrylonitrile

Abstract

There are provided rubber compositions comprising an elastomer comprising a rubber chosen from acrylonitrile-butadiene, hydrogenated acrylonitrile-butadiene, carboxylated acrylonitrile-butadiene and mixtures thereof; reinforcing fibers chosen from aramid fibers, carbon fibers, polyester fibers, glass fibers, nylon fibers and mixtures thereof, and/or nanometric filamentary structures chosen from nanowires, nanorods, nanofibers, nanoribbons, nanotubes and mixtures thereof, the nanometric filamentary structures being functionalized or unfunctionalized; and a filler chosen from carbon black and silica. These compositions can be cured or uncured and they can be used for preparing various articles. Methods for preparing such compositions are also disclosed.

Claims

1. A rubber composition comprising:

about 40 to about 70 wt. % of an elastomer comprising a rubber selected from the group consisting of acrylonitrile-butadiene, hydrogenated acrylonitrile-butadiene, carboxylated acrylonitrile-butadiene and mixtures thereof;

about 0.1 to about 10 wt. % of reinforcing fibers that are aramid fibers;

about 0.1 to about 10 wt. % of nanometric filamentary structures that are carbon nanotubes, said nanometric filamentary structures being functionalized or unfunctionalized; and

about 15 to about 40 wt. % of a filler selected from the group consisting of carbon black, silica and a mixture thereof,

wherein said rubber composition is a cured rubber composition having an elongation % of about 302 to about 650, measured according to ASTM D-412 standard.

2. The composition of claim 1, wherein in said composition, said elastomer, reinforcing fibers and/or nanometric filamentary structures and filler are substantially uniformly distributed.

3. The composition of claim 2, wherein said composition comprises about 45 to about 65 wt. % of said elastomer.

4. The composition of claim 2, wherein said composition comprises about 50 to about 60 wt. % of said elastomer.

5. The composition of claim 1, wherein said composition comprises about 0.25 to about 1.75 wt. % of said reinforcing fibers.

6. The composition of claim 5, wherein said composition comprises about 0.25 to about 1.75 wt. % of said nanometric filamentary structures.

7. The composition of claim 1, wherein said composition comprises about 0.5 to about 10 wt. % of said reinforcing fibers and/or nanometric filamentary structures.

8. The composition of claim 2, wherein said composition comprises about 1 to about 5 wt. % of said reinforcing fibers and/or nanometric filamentary structures.

9. The composition of claim 8, wherein said composition comprises about 20 to about 35 wt. % of said filler.

12. The composition of claim 7, wherein said elastomer comprises hydrogenated acrylonitrile-butadiene.

13. The composition of claim 7, wherein said elastomer comprises carboxylated acrylonitrile-butadiene.

14. The composition of claim 1, wherein said composition has, prior to curing, a Mooney viscosity ML 145°

C. of about 50 to about 100, measured according to ASTM D-1646 standard.

15. The composition of claim 1, wherein said composition has, prior to curing, a Mooney Scorch time t5 145°

C. of about 4 to about 8 minutes, measured according to ASTM D-1646 standard.

16. The composition of claim 7, wherein said composition has, prior to curing, a specific gravity of about 1.0 to about 1.5 g/mL, measured according to ASTM D-297 standard.

17. The composition of claim 1, wherein said rubber composition has a 100% modulus of about 300 to about 1500 psi measured according to ASTM D-412 standard.

18. The composition of claim 7, wherein said rubber composition has a 100% modulus of about 400 to about 900 psi, measured according to ASTM D-412 standard.

19. The composition of claim 17, wherein said rubber composition has a 300% modulus of about 1500 to about 3000 psi, measured according to ASTM D-412 standard.

20. The composition of claim 1, wherein said rubber composition, when submitted to a fuel B immersion test according to ASTM D-471 standard, has an elongation % of about −

10% to about 10%, measured according to ASTM D-412 standard, as compared to a sample measured before fluid immersion.

21. An article comprising a rubber composition as defined in claim 1.

10. A rubber composition comprising:

an elastomer comprising a rubber selected from the group consisting of acrylonitrile-butadiene, hydrogenated acrylonitrile-butadiene, carboxylated acrylonitrile-butadiene and mixtures thereof;

reinforcing fibers that are aramid fibers;

nanometric filamentary structures that are carbon nanotubes, said nanometric filamentary structures being functionalized or unfunctionalized; and

a filler selected from the group consisting of carbon black, silica, and a mixture thereof,

wherein said rubber composition is a cured rubber composition having an elongation % of about 302 to about 650, measured according to ASTM D-412 standard;

and a 100% modulus of about 300 to about 1500 measured according to ASTM D-412 standard.

11. A rubber composition comprising:

an elastomer comprising a rubber selected from the group consisting of acrylonitrile-butadiene, hydrogenated acrylonitrile-butadiene, carboxylated acrylonitrile-butadiene and mixtures thereof;

reinforcing fibers that are aramid fibers;

nanometric filamentary structures that are carbon nanotubes, said nanometric filamentary structures being functionalized or unfunctionalized; and

a filler selected from carbon black, silica, and a mixture thereof,

wherein said rubber composition is a cured rubber composition having an elongation % of about 302 to about 650, measured according to ASTM D-412 standard, a 100% modulus of about 300 to about 1500 psi measured according to ASTM D-412 standard, and a 300% modulus of about 1303 to about 3000 psi, measured according to ASTM D-412 standard.