Method for degumming vegetable oil

• US 9,845,442 B2
• Filed: 01/06/2017
• Issued: 12/19/2017
• Est. Priority Date: 01/19/2016
• Status: Active Grant

• Current Assignee: Archer Daniels Midland Company
• Original Assignee: Arisdyne Systems Incorporated
• Inventors: Kozyuk, Oleg, Reimers, Peter
• Primary Examiner(s): Cutliff, Yate K
• Application Number:
  US15/400,269
• Publication Number:
  US 20170204349A1
• Time in Patent Office: 347 Days
• CPC Class Codes: C11B 3/001 by a combination of two or more of the means hereafter
• CPC Class Codes: C11B 3/005 by wave energy or electric current, e.g. electrodialysis
• CPC Class Codes: C11B 3/04 with acids
• CPC Class Codes: C11B 3/06 with bases
• CPC Class Codes: C11B 3/16 by mechanical means

Abstract

A hydrodynamic cavitation method for degumming triglyceride oil is used to increase oil yield and reduce impurities. The residence time of the oil for degumming in the cavitation field is reduced to enhance removal of impurities such as phosphorus without prolonged exposure of the oil to cavitation conditions. The mass transfer of impurities from an oil phase to non-oil components or water is carried out in a non-cavitational, mass transfer reactor positioned downstream of a hydrodynamic cavitation device. A separation step can be used to remove the phosphatides and other impurities from the treated oil to form a purified oil product.

Claims

1. A method for degumming an oil comprising:

a. mixing oil containing phospholipids with a reagent to form a pre-treated oil mixture;

b. passing the pre-treated oil mixture through a hydrodynamic cavitation device to form a field of hydrodynamic cavitation bubbles in the pre-treated oil mixture for reacting the phospholipids in the oil with the reagent, the pre-treated oil mixture being subjected to the field of hydrodynamic cavitation bubbles for residence time of less than 10×

10<sup>−

5</sup> seconds;

wherein the reacted phospholipids remain in the oil of the pre-treated oil mixture such that the reacted phospholipids are not transferred to a water phase portion of the pre-treated oil mixture;

c. collapsing the hydrodynamic cavitation bubbles to form a processed oil mixture; and

d. directing the processed oil mixture to a mass transfer, non-cavitational reactor, the reacted phospholipids being transferred from an oil phase in the processed oil mixture to a water phase in the processed oil mixture.

2. The method of claim 1, further comprising separating the water phase from the oil phase to form a purified oil.

3. The method of claim 1, the reacted phospholipids are not transferred from the oil prior to collapse of the hydrodynamic cavitation bubbles.

4. The method of claim 1, the processed oil mixture being held in the mass transfer, non-cavitational reactor for at least 0.4 seconds.

5. The method of claim 1, the mass transfer, non-cavitational reactor being a static mixer, a pipe or a holding tank.

6. The method of claim 1, further comprising repeating steps b and c before step d is carried out.

7. The method of claim 1, the oil comprising a vegetable oil.

8. The method of claim 7, the vegetable oil being a crude vegetable oil or a water-degummed vegetable oil.

9. The method of claim 7, the oil being selected from the group consisting of acai oil, almond oil, babassu oil, blackcurrent seed oil, borage seed oil, canola oil, cashew oil, castor oil, coconut oil, coriander oil, corn oil, cottonseed oil, crambe oil, flax seed oil, grape seed oil, hazelnut oil, hempseed oil, jatropha oil, jojoba oil, linseed oil, macadamia nut oil, mango kernel oil, meadowfoam oil, mustard oil, neat'"'"'s foot oil, olive oil, palm oil, palm kernel oil, palm olein, peanut oil, pecan oil, pine nut oil, pistachio oil, poppy seed oil, rapeseed oil, rice bran oil, safflower oil, sasanqua oil, sesame oil, shea butter, soybean oil, sunflower seed oil, tall oil, tsubaki oil, walnut oil and a combination thereof.

10. The method of claim 1, the reagent being selected from the group consisting of water and a water solution of phosphoric acid, hydrochloric acid, sulfuric acid, ascorbic acid, acetic acid, citric acid, fumaric acid, maleic acid, tartaric acid, succinic acid, glycolic acid, sodium hydroxide, potassium hydroxide, sodium silicate, sodium carbonate, calcium carbonate or a combination thereof.

11. The method of claim 1, the oil phase in the processed oil mixture containing less than 1 ppm of phosphorus.

12. The method of claim 11, the processed oil mixture being held in the mass transfer, non-cavitational reactor for at least 0.4 seconds.

13. The method of claim 1, the oil phase in the processed oil mixture containing less than 0.8 ppm of phosphorus.

14. A method for degumming an oil comprising:

a. mixing a vegetable oil containing phospholipids with a aqueous acid solution to form a pre-treated oil mixture comprising a water phase and an oil phase;

b. passing the pre-treated oil mixture through a local constriction in a cavitation device to form a field of hydrodynamic cavitation bubbles in the pre-treated oil mixture such that the phospholipids in the oil phase react with the aqueous acid solution, the pre-treated oil mixture being subjected to the field of hydrodynamic cavitation bubbles for residence time of less than 10×

10<sup>−

5</sup> seconds;

wherein the reacted phospholipids in the field of hydrodynamic cavitation bubbles remain in the oil phase of the pre-treated oil mixture;

c. collapsing the hydrodynamic cavitation bubbles to form a processed oil mixture;

d. directing the processed oil mixture to a mass transfer, non-cavitational reactor, the reacted phospholipids being transferred from an oil phase in the processed oil mixture to a water phase in the processed oil mixture within the mass transfer, non-cavitational reactor; and

e. separating the water phase from the oil phase in the processed oil mixture to form a purified oil, wherein the purified oil contains less than 2 ppm of phosphorus.

15. The method of claim 14, the processed oil mixture being held in the mass transfer, non-cavitational reactor for at least 0.4 seconds.

16. The method of claim 14, the vegetable oil in the pre-treated mixture containing greater than 500 ppm of phosphorus.

17. The method of claim 14, the cavitation device being a static cavitation device and the local constriction being an orifice, baffle or nozzle.

18. The method of claim 14, the pre-treated mixture further comprising a base.

19. The method of claim 18, the base selected from the group consisting of sodium hydroxide, potassium hydroxide, sodium silicate, sodium carbonate, calcium carbonate, and a combination thereof.

20. The method of claim 14, the processed oil mixture being held in the mass transfer, non-cavitational reactor for at least 0.4 seconds and the purified oil containing less than 1 ppm of phosphorus.