Surface-enhanced Raman scattering element, and method for producing same

• US 9,863,884 B2
• Filed: 08/09/2013
• Issued: 01/09/2018
• Est. Priority Date: 08/10/2012
• Status: Active Grant

• Current Assignee: Hamamatsu Photonics KK
• Original Assignee: Hamamatsu Photonics KK
• Inventors: Shibayama, Katsumi, Ito, Masashi, Yokino, Takafumi, Hirose, Masaki, Yoshida, Anna, Ofuji, Kazuto, Maruyama, Yoshihiro, Kasahara, Takashi, Kawai, Toshimitsu, Hirohata, Toru, Kamei, Hiroki, Oyama, Hiroki
• Primary Examiner(s): BOLOGNA, DOMINIC JOSEPH
• Application Number:
  US14/420,510
• Publication Number:
  US 20150219562A1
• Time in Patent Office: 1,614 Days
• CPC Class Codes: B82Y 40/00 Manufacture or treatment of nanostructures
• CPC Class Codes: G01N 2021/651 Cuvettes therefore
• CPC Class Codes: G01N 21/03 Cuvette constructions
• CPC Class Codes: G01N 21/658 enhancement Raman, e.g. surface plasmons

Abstract

A SERS element comprises a substrate having a front face; a fine structure part formed on the front face and having a plurality of pillars; and a conductor layer formed on the fine structure part and constituting an optical function part for generating surface-enhanced Raman scattering. The conductor layer has a base part formed along the front face and a plurality of protrusions protruding from the base part at respective positions corresponding to the pillars. The base part has a thickness greater than the height of the pillars.

Claims

1. A surface-enhanced Raman scattering element comprising:

a substrate having a principal surface;

a fine structure part formed on the principal surface and having a plurality of projections; and

a conductor layer formed on the fine structure part and constituting an optical function part for generating surface-enhanced Raman scattering;

wherein the conductor layer has a base part formed along the principal surface and a plurality of protrusions protruding from the base part at respective positions corresponding to the projections; and

wherein the base part has a thickness greater than a height of the projections,

the projections are pillars, and

a gap that opens at an upper face of the base part positioned higher than a top part of a pillar and extends downward to a position lower than the top part of the pillar, the gap being formed between the base part and a protrusion.

2. A surface-enhanced Raman scattering element according to claim 1, wherein the projections are arranged periodically along the principal surface.

3. A surface-enhanced Raman scattering element according to claim 1, wherein a plurality of gaps are formed in the conductor layer between the base part and protrusions so as to surround the respective projections when seen in the projecting direction of the projections, the projecting direction being the thickness direction of the substrate.

4. A method for manufacturing a surface-enhanced Raman scattering element, the method comprising:

a first step of preparing a substrate having a principal surface formed with a fine structure part having a plurality of projections; and

a second step of forming a conductor layer on the fine structure part after the first step, the conductor layer constituting an optical function part for generating surface-enhanced Raman scattering, such that the conductor layer has a base part formed along the principal surface and a plurality of protrusions protruding from the base part at respective positions corresponding to the projections,

wherein, in the second step, the conductor layer is formed by vapor deposition such that the base part has a thickness greater than a height of the projections,

the projections are pillars, and

the method further comprising forming a gap that opens at an upper face of the base part positioned higher than a top part of a pillar and extends downward to a position lower than the top part of the pillar, the gap being formed between the base part and a protrusion.

5. A method for manufacturing a surface-enhanced Raman scattering element according to claim 4, wherein, in the second step, a width of the respective protrusions is adjusted according to the thickness of the base part.