Device for evaluation of fluids using electromagnetic energy

• US 9,869,636 B2
• Filed: 05/22/2015
• Issued: 01/16/2018
• Est. Priority Date: 02/21/2013
• Status: Active Grant

• Current Assignee: Visualant, Inc.
• Original Assignee: Visualant, Inc.
• Inventors: Mander, Richard Ian, Beach, Allan David, Denton, Michael Vivian, Furness, III, Thomas A., Tompkins, Alan Charles
• Primary Examiner(s): BOLOGNA, DOMINIC JOSEPH
• Application Number:
  US14/720,241
• Publication Number:
  US 20150253244A1
• Time in Patent Office: 970 Days
• CPC Class Codes: G01N 21/01 Arrangements or apparatus for facilitating the optical investigation
• CPC Class Codes: G01N 21/0303 Optical path conditioning in cuvettes, e.g. windows; adapted optical elements or systems; path modifying or adjustment G01N21/031 - G01N21/15 take precedence
• CPC Class Codes: G01N 21/05 Flow-through cuvettes G01N21/09 takes precedence; handling fluid samples G01N1/10
• CPC Class Codes: G01N 21/49 within a body or fluid
• CPC Class Codes: G01N 21/59 Transmissivity G01N21/25 takes precedence
• CPC Class Codes: G01N 2201/022 Casings
• CPC Class Codes: G01N 2201/06113 Coherent sources; lasers

Abstract

A portable, tabletop fluid sampling device simplifies spectral analysis to produce an accurate but inexpensive chromatic fingerprint for fluid samples. In one embodiment, the sampling device uses an array of variable wavelength LED emitters and photodiode detectors to measure Rayleigh scattering of electromagnetic energy from the fluid sample contained in a cuvette. Either the fluid itself, or particles suspended in the fluid can then be identified by performing spectral pattern matching to compare results of a spectral scan against a library of known spectra. A wide range of applications include substance identification, security screening, authentication, quality control, and medical diagnostics.

Claims

1. A sampling device, comprising:

a sample chamber, the sample chamber having an interior to receive a sample cuvette at least partially therein, the sample chamber having at least one opaque wall, a first aperture, a second aperture positioned diametrically across the sample chamber from the first aperture, and a third aperture positioned along an axis perpendicular to an optical axis that extends between the first and the second apertures, the first, the second, and the third apertures transmissive of electromagnetic energy of at least some wavelengths in an optical portion of the electromagnetic spectrum;

an emitter circuit board, the emitter circuit board spaced from the sample chamber opposed to the first aperture of the sample chamber, the emitter circuit board carrying a plurality of emitters, each of the emitters selectively operable to emit electromagnetic energy in a respective range of wavelengths toward the first aperture of the sample chamber, the ranges of wavelengths of at least some of the emitters different from the ranges of wavelengths of others of the emitters;

a calibration circuit board spaced outwardly of the sample chamber and positioned between the sample chamber and the emitter circuit board, the calibration circuit board having a first face opposed to the first aperture of the sample chamber, a second face opposite the first face, and a slit that is transmissive of electromagnetic energy of at least some wavelengths in the optical portion of the electromagnetic spectrum, the calibration circuit board having at least one calibration sensor affixed to the second face of the calibration circuit board to face the emitter circuit board to receive electromagnetic energy emitted by at least one of the emitters, substantially free of electromagnetic energy emitting, if any, from the sample chamber;

a direct sensor circuit board spaced outwardly of the sample chamber opposed to the second aperture of the sample chamber, the direct sensor circuit board having at least one primary sampling sensor positioned to receive electromagnetic energy emitting from the sample chamber via the second aperture; and

an indirect sensor circuit board spaced outwardly of the sample chamber opposed to the third aperture, the indirect sensor circuit board perpendicular to the direct sensor circuit board, the indirect sensor circuit board carrying a number of second primary sampling sensors positioned to receive electromagnetic energy indirectly scattered from the sample chamber along an axis that is perpendicular to the optical axis that extends between the first and the second apertures.

2. The sampling device of claim 1, wherein the indirect sensor circuit board is perpendicular to the calibration circuit board.

3. The sampling device of claim 2, wherein the emitter circuit board is parallel to the calibration circuit board.

4. The sampling device of claim 1, wherein the emitter circuit board is parallel to the calibration circuit board.

5. The sampling device of claim 1, wherein the calibration circuit board is parallel to the direct sensor circuit board.

6. The sampling device of claim 5, wherein the emitter circuit board is parallel to the calibration circuit board.

7. The sampling device of claim 1, wherein the at least one calibration sensor includes at least a first calibration sensor positioned to one side of the slit and at least a second calibration sensor positioned to another side of the slit, the other side of the slit disposed across the slit from the first side of the slit.

8. The sampling device of claim 7, wherein the emitters are all aligned with the slit.

9. The sampling device of claim 1, further comprising:

a spring that biases at least the sample cuvette outwardly from the housing.

10. The sampling device of claim 1, wherein the respective ranges of wavelengths of at least two of the emitters at least partially overlap.

11. The sampling device of claim 1, further comprising:

the sample cuvette sized and dimensioned to be at least partially received by the sample chamber, at least a portion of the sample cuvette transmissive to at least some of the wavelengths of electromagnetic energy emitted by the emitters.

12. The sampling device of claim 1, wherein the optical portion of the electromagnetic spectrum extends from near-infrared through near-ultraviolet.

13. The sampling device of claim 1, further comprising:

at least one port providing flow-through, fluid communication with the cuvette.

14. The sampling device of claim 1, further comprising:

at least one control subsystem communicatively coupled to the emitters, the primary sampling sensors; and

the calibration sensors; and

at least one temperature sensor communicatively coupled to the at least one control subsystem, wherein the at least one control subsystem controls operation based at least in part on information from both the calibration sensors and the at least one temperature sensor.

15. The sampling device of claim 14, wherein the at least one control subsystem calibrates an output value based at least in part on information from both the calibration sensors and the at least one temperature sensor.

16. The sampling device of claim 14, wherein the at least one control subsystem calibrates a drive signal supplied to at least one of the emitters based at least in part on information from both the calibration sensors and the at least one temperature sensor.

17. The sampling device of claim 14, wherein the sample chamber is rectangular, having two pairs of opposed walls.

18. The sampling device of claim 17, further comprising:

the sample cuvette which is square and sized and dimensioned to be at least partially received by the sample chamber, at least a portion of the sample cuvette transmissive to at least some of the wavelengths of electromagnetic energy emitted by the emitters.