Electrochromic element, optical filter, lens unit, image pickup apparatus, and window member

• US 9,869,919 B2
• Filed: 06/24/2016
• Issued: 01/16/2018
• Est. Priority Date: 07/02/2015
• Status: Active Grant

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Kubo, Wataru, Igawa, Satoshi
• Primary Examiner(s): Dinh, Jack
• Application Number:
  US15/191,843
• Publication Number:
  US 20170003563A1
• Time in Patent Office: 571 Days
• Field of Search: 359265-275
• CPC Class Codes: G02F 1/15165 Polymers
• CPC Class Codes: G02F 1/153 Constructional details
• CPC Class Codes: G02F 1/1533 structural features not otherwise provided for
• CPC Class Codes: G02F 1/155 Electrodes
• CPC Class Codes: G02F 1/163 Operation of electrochromic cells, e.g. electrodeposition cells; Circuit arrangements therefor
• CPC Class Codes: G02F 2001/1502 complementary cell
• CPC Class Codes: G02F 2001/15145 the electrochromic layer comprises a mixture of anodic and cathodic compounds

Abstract

Provided is an electrochromic element, which is capable of correcting possible charge imbalance, and is suppressed in color remaining, the electrochromic element including: a first electrode; a second electrode; a third electrode; and an electrolyte, an anodic organic electrochromic compound, and a cathodic redox substance that are arranged between the first electrode and the second electrode, at least one of the first electrode and the second electrode being transparent, in which: the third electrode is electrically connectable to at least one of the first electrode and the second electrode through the electrolyte; the third electrode further has a redox substance; and a reduced form of the redox substance of the third electrode is more easily oxidized than a reduced form of the anodic organic electrochromic compound.

Claims

1. An electrochromic element, comprising:

a first electrode;

a second electrode;

a third electrode; and

an electrolyte, an anodic organic electrochromic compound, and a cathodic redox substance that are arranged between the first electrode and the second electrode,

at least one of the first electrode and the second electrode being transparent, wherein;

the third electrode is electrically connectable to at least one of the first electrode and the second electrode through the electrolyte;

the third electrode further has a redox substance; and

a reduced form of the redox substance of the third electrode is more easily oxidized than a reduced form of the anodic organic electrochromic compound.

2. The electrochromic element according to claim 1, wherein a redox potential E_EC(A) of the anodic organic electrochromic compound and a redox potential E_RO of the redox substance of the third electrode satisfy the following formula (I):

E_RO<

E_EC(A) 

 

(I).

3. The electrochromic element according to claim 1, wherein the third electrode is arranged outside an optical path of light to be transmitted through at least one of the first electrode and the second electrode.

4. The electrochromic element according to claim 1, wherein at least one of the organic electrochromic compounds incorporated between the first electrode and the second electrode is fixed to one of the first electrode and the second electrode.

5. The electrochromic element according to claim 1, wherein the redox substance of the third electrode comprises an electrochromic compound.

6. The electrochromic element according to claim 1, wherein the third electrode is arranged in at least part of a periphery of one of the first electrode and the second electrode.

7. The electrochromic element according to claim 1, wherein the third electrode has two or more kinds of redox substances.

8. The electrochromic element according to claim 1, further comprising a unit configured to control a potential difference between one of the first electrode and the second electrode, and the third electrode.

9. The electrochromic element according to claim 1, further comprising a unit configured to perform short-circuiting between one of the first electrode and the second electrode, and the third electrode at a time of a decoloring operation of the electrochromic element.

10. The electrochromic element according to claim 1, further comprising a detecting unit configured to detect a state of a charge balance of the electrochromic element.

11. The electrochromic element according to claim 10, wherein:

the detecting unit comprises an apparatus configured to measure a transmittance of the electrochromic element; and

the apparatus includes a light source and a light-receiving element.

12. An optical filter, comprising:

the electrochromic element of claim 1; and

an active element connected to the electrochromic element.

13. A lens unit, comprising:

an image pickup optical system including a plurality of lenses; and

the optical filter of claim 12.

14. An image pickup apparatus, comprising:

an image pickup optical system including a plurality of lenses;

the optical filter of claim 12; and

an image pickup element configured to receive light transmitted through the optical filter.

15. The image pickup apparatus according to claim 14, wherein the image pickup optical system is removably mounted.

16. A window member, comprising:

a pair of transparent substrates;

the electrochromic element of claim 1 arranged between the pair of transparent substrates; and

an active element connected to the electrochromic element.

17. An electrochromic element, comprising:

a first electrode;

a second electrode;

a third electrode; and

an electrolyte, a cathodic organic electrochromic compound, and a cathodic redox substance that are arranged between the first electrode and the second electrode,

at least one of the first electrode and the second electrode being transparent, wherein;

the third electrode is electrically connectable to at least one of the first electrode and the second electrode through the electrolyte;

the third electrode further has a redox substance; and

an oxidized form of the redox substance of the third electrode is more easily reduced than an oxidized form of the cathodic organic electrochromic compound.

18. The electrochromic element according to claim 17, wherein a redox potential E_EC(C) of the cathodic organic electrochromic compound and a redox potential E_RO of the redox substance of the third electrode satisfy the following formula (II):

E_RO>

E_EC(C) 

 

(II).

19. An electrochromic element, comprising:

a first electrode;

a second electrode;

a third electrode; and

an electrolyte, an anodic organic electrochromic compound, and a cathodic organic electrochromic compound that are arranged between the first electrode and the second electrode,

at least one of the first electrode and the second electrode being transparent, wherein;

the third electrode is electrically connectable to at least one of the first electrode and the second electrode through the electrolyte;

the third electrode has a redox substance;

a reduced form of the redox substance of the third electrode is more easily oxidized than a reduced form of the anodic organic electrochromic compound; and

an oxidized form of the redox substance of the third electrode is more easily reduced than an oxidized form of the cathodic organic electrochromic compound.

20. The electrochromic element according to claim 19, wherein a redox potential E_EC(A) of the anodic organic electrochromic compound, a redox potential E_EC(C) of the cathodic organic electrochromic compound, and a redox potential E_RO of the redox substance of the third electrode satisfy the following formula (III):

E_EC(C)<

E_RO<

E_EC(A) 

 

(III).