Integrated gasification combined cycle plant with char preparation system

• US 9,873,840 B2
• Filed: 09/20/2010
• Issued: 01/23/2018
• Est. Priority Date: 09/18/2009
• Status: Active Grant

• Current Assignee: Wormser Energy Solutions, Inc.
• Original Assignee: Wormser Energy Solutions, Inc.
• Inventors: Wormser, Alex
• Primary Examiner(s): KIM, CRAIG SANG
• Application Number:
  US13/394,823
• Publication Number:
  US 20120167585A1
• Time in Patent Office: 2,682 Days
• CPC Class Codes: C10J 2200/156 Sluices, e.g. mechanical sluices for preventing escape of gas through the feed inlet
• CPC Class Codes: C10J 2300/093 Coal
• CPC Class Codes: C10J 2300/0956 Air or oxygen enriched air
• CPC Class Codes: C10J 2300/0976 as steam
• CPC Class Codes: C10J 2300/1606 Combustion processes
• CPC Class Codes: C10J 2300/1675 making use of a steam turbine
• CPC Class Codes: C10J 3/482 Gasifiers with stationary fluidised bed
• CPC Class Codes: C10J 3/725 Redox processes
• CPC Class Codes: C10J 3/84 with means for removing dust or tar from the gas
• CPC Class Codes: C10K 1/004 Sulfur containing contaminants, e.g. hydrogen sulfide
• CPC Class Codes: C10K 1/005 Carbon dioxide
• CPC Class Codes: C10K 1/024 by filtration
• CPC Class Codes: Y02E 20/18 Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]

Abstract

Provided herein are systems, methods and equipment that include Integrated Gasification Combined-Cycle technology to retrofit existing plants, that include, e.g., subsystems for separating char fines from syngas after it emerges from an internally-circulating fluidized bed carbonizer and injecting the char into the carbonizer draft tube as a fuel source. Efficiency and power generation are thus increased to the extent that inclusion of carbon capture systems are now possible for existing coal plants in order to significantly reduce carbon dioxide emissions.

Claims

1. An Integrated Gasification Combined-Cycle (IGCC) gasifier comprising:

a pressure vessel comprising at least one inlet conduit that receives a supply air, a steam supply, a solid fuel, and pulverized char, and at least one outlet conduit that passes the pulverized char and syngas, the pressure vessel containing an internally-circulating fluidized bed carbonizer comprising a draft tube that receives a stream of the solid fuel surrounded by a two-zone fluidized bed system comprising an upper bed that thermally cracks tars in volatiles, and an annular fluidized bed surrounding the draft tube that carbonizes the solid fuel with fluidizing air and steam, the internally-circulating fluidized bed carbonizer producing a syngas and a char from the solid fuel;

a syngas cooler coupled to an outlet duct of the internally-circulating fluidized bed carbonizer;

a separator coupled to the syngas cooler that separates entrained char from the syngas;

a syngas cleanup system having an input coupled to the at least one outlet conduit of the pressure vessel that removes contaminants from the syngas produced by the internally-circulating fluidized bed carbonizer;

a char preparation system coupled to the separator that prepares the entrained char to be injected into the internally-circulating fluidized bed carbonizer, the char preparation system comprising;

a cooler that removes heat from the char forming a cooled char,

a pulverizer coupled to the cooler that pulverizes the cooled char, and

an airlock coupled to the pulverizer; and

an injector that receives the pulverized char from the char preparation system along with a stream of air for combustion of the pulverized char and introduces the pulverized char into the draft tube disposed in the internally-circulating fluidized bed carbonizer, whereby the pulverized char burns in the draft tube, thereby improving utilization of the solid fuel.

2. The system of claim 1, wherein the solid fuel is coal.

3. The system of claim 1, further comprising an ash separator coupled to the pulverizer.

4. The system of claim 3, wherein the carbonizer comprises:

a distributor plate disposed within the carbonizer under an annular bubbling bed of char; and

a dipleg disposed beneath the carbonizer.

5. The system of claim 3, wherein a stream of high-density particles is added to the annular bubbling bed of char, the stream of high-density particles increasing a circulation rate of the char from the draft tube to the fluidized bed.

6. The system of claim 1, wherein the pulverized char is injected, along with the stream of air for combustion of the char, into a plenum beneath a distributor plate located beneath an annular fluidized bed of char external to the draft tube disposed in the carbonizer, and coal is injected into an inlet of the draft tube.

7. The system of claim 6, wherein the plenum comprises an inlet beneath the distributor plate to introduce an oxidant and steam for gasifying the annular bed.

8. The system of claim 6, further comprising sparge pipes located above the distributor plates, wherein some or all of the oxidant for gasifying the annular bed is fed into the annular bed to provide efficient combustion of the char.

9. The system of claim 6, further comprising a separator sleeve mounted on an inner radius of the distributor plate such that the flow of the char into the inlet of the draft tube is limited.

10. The system of claim 1, further comprising:

a first pressure vessel comprising an inlet coupled to an outlet of the syngas cleanup system so that the first pressure vessel receives enough steam and syngas so that the steam reacts with the carbon monoxide in the syngas causing a water gas shift reaction that converts the carbon monoxide into hydrogen and carbon dioxide;

an outlet for exhausting gases generated in the pressure vessel; and

at least one bed of a sorbent comprising a calcium carbonate chemically-active compound, wherein the carbon dioxide formed is captured by the sorbent; and

a second pressure vessel having an inlet coupled to the outlet of the first pressure vessel, and having a compressor used to pressurize the carbon dioxide captured in the first pressure vessel to a pipeline pressure, the second pressure vessel separating the carbon dioxide from the sorbent.

11. A method for increasing efficiency of an Integrated Gasification Combined-Cycle (IGCC) subsystem of a powerplant, the method including:

carbonizing a solid fuel by injecting the solid fuel into a pressurized carbonizer comprising a draft tube surrounded by a two-zone fluidized bed system comprising an upper bed that thermally cracks tars in volatiles, and an annular fluidized bed surrounding the draft tube that carbonizes a solid fuel with fluidizing air and steam, thereby producing a syngas stream and a char fines content;

separating the char fines content from the syngas stream;

cooling the char lines content;

pulverizing the char fines content;

reducing an ash fines concentration in the char fines content; and

injecting the char fines content into the draft tube of the pressurized carbonizer as a fuel used to more efficiently generate the syngas stream and the char fines content and to more completely utilize the solid fuel, wherein the efficiency of the IGCC subsystem is increased by the return of the char fines to the pressurized carbonizer and its use as a fuel therein.

12. The method of claim 11, further comprising performing a method of removing contaminants from the syngas, the method comprising:

filtering the syngas to provide a filtered syngas;

adsorbing a halide component from the filtered syngas in a fixed bed reactor; and

removing a sulfur component from the syngas with a regenerable desulfurizer comprising two circulating fluidized bed reactors that absorb the sulfur-bearing gases in the syngas in one reactor, and that regenerate the sorbent in the other reactor.