High pressure electrochemical cell and process for the electrochemical reduction of carbon dioxide

• US 9,873,951 B2
• Filed: 09/16/2013
• Issued: 01/23/2018
• Est. Priority Date: 09/14/2012
• Status: Active Grant

• Current Assignee: Avantium Knowledge Centre B.V. (Avantium NV)
• Original Assignee: Avantium Knowledge Centre B.V. (Avantium NV)
• Inventors: Kaczur, Jerry J., Sivasankar, Narayanappa, Cole, Emily Barton
• Primary Examiner(s): Wilkins, III, Harry D
• Application Number:
  US14/427,934
• Publication Number:
  US 20150267309A1
• Time in Patent Office: 1,590 Days
• Field of Search: None
• CPC Class Codes: C25B 1/00 Electrolytic production of inorganic compounds or non-metals
• CPC Class Codes: C25B 11/02 characterised by shape or form
• CPC Class Codes: C25B 11/031 Porous electrodes
• CPC Class Codes: C25B 15/08 Supplying or removing reactants or electrolytes; Regeneration of electrolytes
• CPC Class Codes: C25B 3/25 Reduction
• CPC Class Codes: C25B 9/00 Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
• CPC Class Codes: C25B 9/23 comprising ion-exchange membranes in or on which electrode material is embedded

Abstract

The present disclosure the present disclosure is directed to an electrochemical cell including an exterior pressure vessel, the exterior pressure vessel including a cylindrical body, a first end removably fastened to the cylindrical body to cover a first opening of the cylindrical body and a second end removably fastened to the cylindrical body to cover a second opening of the cylindrical body. The electrochemical cell may further include high surface area electrodes which may be configured to operate at high pressures, such as in the range of 2 to 100 atmospheres or more.

Claims

1. An electrochemical cell, comprising:

an exterior pressure vessel, the exterior pressure vessel including;

a cylindrical body, the cylindrical body being formed of a first semicircular section and a second semi-circular section which are removably fastened together;

a first end removably fastened to the cylindrical body to cover a first opening of the cylindrical body;

a second end removably fastened to the cylindrical body to cover a second opening of the cylindrical body;

an anode, the anode including a semi-circular section and a flat portion connected to the semi-circular portion, the anode being connected to the first semicircular section of the cylindrical body; and

a cathode, the cathode including a semi-circular section and a flat portion connected to the semi-circular portion, the cathode being connected to the second semi-circular section of the cylindrical body; and

a membrane, the membrane located between the anode and cathode, the membrane configured to control a flow of ions between the anode and the cathode.

2. The electrochemical cell of claim 1, wherein one of the first end or the second end is a flat structure.

3. The electrochemical cell of claim 1, wherein one of the first end or the second end is a cylindrical dome structure.

4. The electrochemical cell of claim 1, wherein the flat portion of the anode is a perforated metal screen.

5. The electrochemical cell of claim 1, wherein the flat portion of the cathode includes a cathode current distributor and a catalyst coating.

6. The electrochemical cell of claim 1, wherein the first end includes an anolyte inlet port and a catholyte inlet port and the second end includes an anolyte outlet port and a catholyte outlet port.

7. The electrochemical cell of claim 6, further comprising a pressure controller connected to at least one of the anolyte inlet, anolyte outlet, catholyte inlet or catholyte outlet.

8. The electrochemical cell of claim 1, wherein the anode has a length approximately a length of the cylindrical body.

9. The electrochemical cell of claim 1, wherein the cathode has a length approximately the length of the cylindrical body.