Composite adsorbent material

• US 9,878,356 B2
• Filed: 07/31/2013
• Issued: 01/30/2018
• Est. Priority Date: 02/03/2011
• Status: Active Grant

• Current Assignee: The Forestry Commission (Government of United Kingdom), University of Surrey
• Original Assignee: The Forestry Commission (Government of United Kingdom), University of Surrey
• Inventors: De Leij, Franciscus Antonius Anna Maria, Stratford, James, Sneath, Helen, Hutchings, Tony
• Primary Examiner(s): HENDRICKSON, STUART L
• Application Number:
  US13/955,978
• Publication Number:
  US 20130316898A1
• Time in Patent Office: 1,644 Days
• CPC Class Codes: B01J 20/02 comprising inorganic material
• CPC Class Codes: B01J 20/0248 Compounds of B, Al, Ga, In, Tl B01J20/08 takes precedence
• CPC Class Codes: B01J 20/0277 Carbonates of compounds other than those provided for in B01J20/043
• CPC Class Codes: B01J 20/0285 Sulfides of compounds other than those provided for in B01J20/045
• CPC Class Codes: B01J 20/0292 Phosphates of compounds other than those provided for in B01J20/048
• CPC Class Codes: B01J 20/041 Oxides or hydroxides
• CPC Class Codes: B01J 20/043 Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
• CPC Class Codes: B01J 20/045 containing sulfur, e.g. sulfates, thiosulfates, gypsum
• CPC Class Codes: B01J 20/06 comprising oxides or hydroxides of metals not provided for in group B01J20/04
• CPC Class Codes: B01J 20/10 comprising silica or silicate
• CPC Class Codes: B01J 20/20 comprising free carbon; comprising carbon obtained by carbonising processes
• CPC Class Codes: B01J 20/28042 Shaped bodies; Monolithic structures
• CPC Class Codes: B01J 20/28057 Surface area, e.g. B.E.T specific surface area
• CPC Class Codes: B01J 20/28073 being in the range 0.5-1.0 ml/g
• CPC Class Codes: B01J 20/28085 being more than 50 nm, i.e. macropores
• CPC Class Codes: B01J 20/28097 being coated, filled or plugged with specific compounds
• CPC Class Codes: B01J 20/3078 Thermal treatment, e.g. calcining or pyrolizing
• CPC Class Codes: B01J 20/3204 Inorganic carriers, supports or substrates
• CPC Class Codes: B01J 20/3236 containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
• CPC Class Codes: B09C 1/08 chemically
• CPC Class Codes: C02F 1/281 : using inorganic sorbents
• CPC Class Codes: C02F 1/283 : using coal, charred products, or inorganic mixtures containing them
• CPC Class Codes: C02F 1/288 : using composite sorbents, e.g. coated, impregnated, multi-layered
• CPC Class Codes: C02F 1/488 : for separation of magnetic materials, e.g. magnetic flocculation
• CPC Class Codes: C02F 2101/103 : Arsenic compounds
• CPC Class Codes: C02F 2101/20 : Heavy metals or heavy metal compounds
• CPC Class Codes: C02F 2103/06 : Contaminated groundwater or leachate
• CPC Class Codes: C02F 2209/06 : pH
• CPC Class Codes: C02F 2303/16 : Regeneration of sorbents, filters

Abstract

The invention relates to composite adsorbent materials, and in particular, to highly porous carbon-based composite materials for the adsorption and stabilization of inorganic substances. The composite adsorbent material comprises a porous carbon carrier matrix and an adsorbent species, wherein the adsorbent species is precipitated within the pores of the carrier matrix. The invention extends to various uses of such adsorbent materials, for example in water purification, recovery of metals from waste streams and remediation applications, and where the adsorbant material is amended into soil, waste etc. for the purpose of breaking pollutant-receptor linkages.

Claims

1. A composite adsorbent material comprising a porous carbon carrier matrix and an adsorbent species, wherein:

the carrier matrix comprises non-activated charcoal, and

the adsorbent species is selected from one or more of a silicate or a hydrotalcite, precipitated within the pores of the carrier matrix.

2. The adsorbent material according to claim 1, wherein the adsorbent species is also disposed in void spaces formed between adjacent particles comprising the carrier matrix.

3. The adsorbent material according to claim 1, wherein the carrier matrix comprises or is derived from charred plant material, charred compost, a charred hardwood or a charred softwood species of plant.

4. A soil or waste amendment composition comprising the composite adsorbent material according to claim 1, for use in changing the pH of soil or waste.

5. The adsorbent material according to claim 1, wherein the carrier matrix is substantially macroporous, and wherein the macropores have average diameters in the range of 50 nm to 500 nm, or 50 to 300 nm, or 50 to 200 nm.

6. The adsorbent material according to claim 1, wherein the concentration of the adsorbent species in the composite material is between 1-90% (w/w), 10-75% (w/w) or 20-50% of the total weight of the composite material.

7. A particle comprising the composite adsorbent material according to claim 1, wherein the mean particle size is between about 0.1 mm and 50 mm, or between about 0.1 mm and 25 mm, or between about 0.25 mm and 50 mm.

8. The adsorbent material according to claim 1, wherein the adsorbent species is basic.

9. The adsorbent material according to claim 1, wherein the adsorbent species comprises a silicate.

10. The adsorbent material according to claim 1, wherein the adsorbent species comprises a metal silicate and/or hydrotalcite.

11. The adsorbent material according to claim 10, wherein the metal silicate and/or hydrotalcite comprises a reduced metal species of manganese, cobalt, copper, zinc, iron, nickel, bismuth or silver.

12. A method of preparing a composite adsorbent material according to claim 1, the method comprising the steps of:

(i) providing a porous carbon carrier matrix comprising non-activated charcoal; and

(ii) precipitating an adsorbent species selected from one or more of a silicate or a hydrotalcite within the pores of the carrier matrix, to thereby form a composite adsorbent material.

13. The method according to claim 12, wherein the carbon carrier matrix is heated to at least 300°

C., 400°

C., 450°

C., 500°

C., 600°

C., 800°

C., 1000°

C. or more in an oxygen limited environment prior to the precipitation step, and wherein the carbon matrix is impregnated with a soluble salt prior to being heated resulting in the reduction and precipitation of at least one of the ions of the impregnating salt.

17. A method of adsorbing inorganic substances, the method of comprising contacting the composite material of claim 1 with the inorganic substances.

18. A method according to claim 17, wherein the inorganic substances comprise an environmental contaminant or pollutant present in drinking water, or an industrial or agricultural effluent;

the inorganic substances comprising heavy metals or heavy-metal containing compounds present in landfill leachate, groundwater, drilling waste, mine drainage, mine spoil, or sewage sludge;

the inorganic substances comprising heavy metals or heavy metal-containing compounds, phosphates etc. and are present in soil amendments;

or the inorganic substances comprise bromates, arsenates, selenium, antimony, strontium, cyanides, chlorinated compounds, nitrates, sulphates or arsenites.

19. A method of removing a pollutant from a fluid, the method comprising contacting a fluid comprising a pollutant with the composite adsorbent material according to claim 1 under conditions suitable to remove the pollutant from the fluid, wherein the composite material is supported on a support, for example in a cartridge or is placed inside a porous bag or filter, or is fixed onto a solid support, over which the polluted fluid is passed.

14. A composite adsorbent material comprising a porous carbon carrier matrix and an adsorbent species, wherein:

the carrier matrix comprises non-activated carbon, and

the adsorbent species is an alkaline earth metal oxide, precipitated within the pores of the carrier matrix.

15. The composite adsorbent material according to claim 14, wherein the alkaline earth metal oxide is calcium oxide or magnesium oxide.

16. A method of preparing a composite adsorbent material according to claim 14, the method comprising the steps of:

(i) providing a porous carbon carrier matrix comprising non-activated carbon; and

(ii) precipitating an adsorbent species comprising an alkaline earth metal oxide within the pores of the carrier matrix, to thereby form a composite adsorbent material.