Preservation of cellulosic materials, compositions and methods thereof

• US 9,878,464 B1
• Filed: 06/29/2012
• Issued: 01/30/2018
• Est. Priority Date: 06/30/2011
• Status: Expired due to Fees

• Current Assignee: Apinee, Inc.
• Original Assignee: Apinee, Inc.
• Inventors: Stark, Joseph L., Schultz, Forrest S.
• Primary Examiner(s): Yuan, Dah-Wei D
• Assistant Examiner(s): Zhang, Hai Yan
• Application Number:
  US13/538,739
• Time in Patent Office: 2,041 Days
• Field of Search: 427384, 427408
• CPC Class Codes: A61L 2/00 Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor for contact lenses A61L12/00; atomisers for disinfecting agents A61M; sterilisation of packages or package contents in association with packaging B65B55/00; treatment of water, waste water, sewage or sludge C02F; disinfecting paper D21H21/36; disinfecting devices for water closets E03D; articles having provision for disinfection, see the relevant subclasses for these articles, e.g. H04R1/12
• CPC Class Codes: B27K 3/15 Impregnating involving polymerisation including use of polymer-containing impregnating agents macromolecular compounds derived from lignocellulosic materials C08H; compositions of lignin-containing materials C08L97/02

Abstract

The disclosure relates to compositions for preservation of cellulosic materials and methods of applying compositions for preservation of cellulosic materials. The compositions comprise a pre-polymer and optional nonionic surfactants and other additives. Compositions of optional nonionic surfactant mixtures and pre-polymers can be used advantageously in methods to preserve cellulosic materials by application of the material with preservatives at ambient atmospheric pressures.

Claims

1. A method for preserving cellulosic materials comprising:

a. applying to the cellulosic material a composition so that at least one portion of the composition penetrates a surface of the cellulosic material and another portion of the composition coats the surface of the cellulosic material, wherein the composition consists of;

from about 2.0 wt % to about 20 wt % of a mixture of a first pre-polymer having a weight-average molecular weight (MWw) of from 5,000 to about 10,000 and a second pre-polymer having a weight-average molecular weight (MWw) of less than 5,000; and

a solvent; and

b. curing the composition and the cellulosic material in a curing step having a duration of at least three days and comprising a curing temperature of ambient temperature and a curing pressure between atmospheric pressure and about 24 psig, wherein the curing temperature and curing pressure are maintained for the duration of the curing step;

wherein the cellulosic material comprises wood, and wherein curing comprises polymerization.

2. The method of claim 1, wherein the composition is applied to the material by soaking the material in the composition, or by brushing, wiping or spraying the composition on the surface of the material.

3. The method of claim 1, wherein the first pre-polymer has a weight-average molecular weight (MW_w) of from 5,000 to about 8,000 and the second pre-polymer has a weight-average molecular weight (MW_w) of from about 180 to about 1,000.

4. The method of claim 1, wherein the first and second pre-polymers are selected from the group consisting of methylene diphenyl isocyanate, polyvinyl acetate, phenol-formaldehyde, melamine-formaldehyde, urea-formaldehyde, urea-melamine-formaldehyde, urea-furfural, and mixtures thereof.

5. The method of claim 1, wherein the solvent is water or ethanol or methanol or a mixture thereof.

6. The method of claim 1, wherein at least some of the pre-polymer solution penetrates the surface of the material and wherein the pre-polymer that has penetrated the surface of the material chemically bonds to the material during curing.

7. The method of claim 1, wherein at least some of the pre-polymer solution remains on the surface of the material and wherein the pre-polymer that has remained on the surface of the material forms a protective crust on the material during curing.

8. The method of claim 1, wherein the method is capable of rendering the cellulosic material weather resistant.

9. The method of claim 1, wherein the method is capable of rendering the cellulosic material fire resistant.

10. The method of claim 1, wherein the method is capable of increasing the hardness, compression strength or modulus or combinations thereof of the cellulosic material.

11. The method of claim 1, wherein the composition has a pH of 7.5-13.

12. The method of claim 1, wherein the cellulosic material is a green wood board.

13. The method of claim 1, wherein the method is used to prepare utility poles.