Electro-conductive fibers with carbon nanotubes adhered thereto, electro-conductive yarn, fibers structural object, and production processes thereof

• US 9,885,146 B2
• Filed: 08/31/2009
• Issued: 02/06/2018
• Est. Priority Date: 09/02/2008
• Status: Active Grant

• Current Assignee: Chakyu Dyeing Co., Ltd., Mitsui & Company Limited, National University Corporation Hokkaido University
• Original Assignee: Chakyu Dyeing Co., Ltd., Kuraray Company Limited, Mitsui & Company Limited, National University Corporation Hokkaido University
• Inventors: Fugetsu, Bunshi, Akiba, Eiji, Hachiya, Masaaki
• Primary Examiner(s): Walshon, Scott R
• Application Number:
  US13/060,596
• Publication Number:
  US 20110151254A1
• Time in Patent Office: 3,081 Days
• Field of Search: 428367, 428375, 428357, 428408, 428 341, 428911, 428220, 4282991, 4284111, 428174, 478357, 977755, 977932, 977961
• CPC Class Codes: D06M 10/02 ultrasonic or sonic; Corona discharge
• CPC Class Codes: D06M 10/06 Inorganic compounds or elements
• CPC Class Codes: D06M 11/74 with carbon or graphite; with carbides; with graphitic acids or their salts
• CPC Class Codes: D06M 2200/00 Functionality of the treatment composition and/or properties imparted to the textile material
• CPC Class Codes: Y10T 428/292 In coating or impregnation

Abstract

Electro-conductive fibers comprise synthetic fibers and an electro-conductive layer containing carbon nanotubes and covering a surface of the synthetic fibers, and the coverage of the electro-conductive layer relative to the whole surface of the synthetic fibers is not less than 60% (particularly not less than 90%). The electric resistance value of the electro-conductive fibers ranges from 1×10⁻² to 1×10¹⁰ Ω/cm, and the standard deviation of the logarithm of the electric resistance value is less than 1.0. The thickness of the electro-conductive layer ranges from 0.1 to 5 μm, and the ratio of the carbon nanotubes may be 0.1 to 50 parts by mass relative to 100 parts by mass of the synthetic fibers. The electro-conductive layer may further contain a binder. The electro-conductive fibers may be produced by immersing the synthetic fibers in a dispersion with vibrating the synthetic fibers to form the electro-conductive layer adhered to the surface of the synthetic fibers. The electro-conductive fibers have the carbon nanotubes homogeneously and firmly adhered to an almost whole of a surface thereof and have an electro-conductivity and a softness.

Claims

1. An electro-conductive fiber, comprising:

at least one synthetic fiber; and

an electro-conductive layer, comprising at least one carbon nanotube, a surfactant and a binder, and covering a surface of the at least one synthetic fiber, and

having an electric resistance value at 20°

C. ranging from 1×

10<sup>−

2</sup> to 4.9×

10⁵ Ω

/cm,

wherein;

the carbon nanotube comprises a multi-walled carbon nanotube,

the surfactant comprises at least one member selected from the group consisting of an anionic surfactant, a cationic surfactant and a zwitterionic surfactant,

the binder comprises at least one hydrophilic adhesive resin selected from the group consisting of a polyester resin, an acrylic resin, a vinyl acetate resin and a urethane resin,

the covering of the electro-conductive layer relative to a whole surface of the at least one synthetic fiber is not less than 60%;

a ratio of the at least one carbon nanotube is 1 to 20 parts by mass relative to 100 parts by mass of the at least one synthetic fiber;

a ratio of the surfactant is 0.03 to 50 parts by mass relative to 100 parts by mass of the carbon nanotube; and

a ratio of the binder is 50 to 400 parts by mass relative to 100 parts by mass of the carbon nanotube; and

the electro-conductive layer has a thickness of from 0.1 to 5 μ

m.

2. The electro-conductive fiber of claim 1, wherein the covering of the electro-conductive layer relative to the whole surface of the at least one synthetic fiber is not less than 90%.

3. The electro-conductive fiber of claim 1, wherein the at least one synthetic fiber forms a yarn, and an average fineness of the yarn is 10 to 1000 dtex.

4. The electro-conductive fiber of claim 1, having an electric resistance value at 20°

C. ranging from 1×

10<sup>−

2</sup> to 1×

10⁸ Ω

/cm.

5. The electro-conductive fiber of claim 1, having a standard deviation of a logarithm of an electric resistance value of less than 1.0.

6. The electro-conductive fiber of claim 1, wherein, when two electrodes are attached to the electro-conductive fiber at an interval of 5 cm and a 12 V direct current or alternating current is applied on the electro-conductive fiber at 20°

C., a temperature of the electro-conductive fiber between the two electrodes is raised by not lower than 2°

C. after 60 seconds.

7. The electro-conductive fiber of claim 1, wherein the at least one synthetic fiber comprises at least one member selected from the group consisting of a polyester resin, a polyamide resin, a polyolefin resin, and an acrylic resin.

8. An electro-conductive yarn, comprising at least one of the electro-conductive fiber of claim 1.

9. The electro-conductive yarn of claim 8, which is a multifilament or a spun yarn.

10. The electro-conductive fiber of claim 1, wherein:

a ratio of the binder is 100 to 300 parts by mass relative to 100 parts by mass of the carbon nanotube.

11. The electro-conductive fiber of claim 1, wherein the carbon nanotube has an average diameter of about 5 to 300 nm.

12. The electro-conductive fiber of claim 11, wherein the multi-walled carbon nanotube has an average length of about 1 to 1000 μ

m.

13. The electro-conductive fiber of claim 11, which has an electric resistance value at 20°

C. ranging from 1×

10<sup>−

2</sup> to 1×

10⁴ Ω

/cm.

14. The electro-conductive fiber of claim 1, wherein the multi-walled carbon nanotubes form a network in the electro-conductive layer.

15. The electro-conductive fiber of claim 14, wherein the multi-walled carbon nanotubes are homogenously and firmly adhered to the surface of the synthetic fiber.

16. An electro-conductive fiber structural object, formed from at least one selected from the group consisting of the electro-conductive fiber of claim 1 and an electro-conductive yarn comprising at least one of the electro-conductive fiber.

17. The electro-conductive fiber structural object of claim 16, wherein a surface leakage resistance value at 20°

C. ranges from 1×

10<sup>−

2</sup> to 1×

10¹⁰ Ω

/cm, and the surface leakage resistance value after the fiber structural object is washed 20 times in accordance with JIS L 0217, No. 103 is 1 to 10000 times as large as the surface leakage resistance value before washing.

18. The electro-conductive fiber structural object according to claim 16, wherein, when two electrodes are attached to the electro-conductive fiber at an interval of 5 cm and a 12 V direct current or alternating current is applied on the electro-conductive fiber at 20°

C., a temperature of the electro-conductive fiber between the two electrodes is raised by not lower than 2°

C. after 60 seconds.

19. A process for producing the electro-conductive fiber of claim 1, the process comprising:

adhering the at least one carbon nanotube to a surface of the at least one synthetic fiber by contacting the surface with a dispersion comprising the at least one carbon nanotube, the surfactant, and the binder, to form the electro-conductive layer comprising the at least one carbon nanotube, the binder and the surfactant adhered to the surface of the at least one synthetic fiber; and

drying a resulting fiber comprising the at least one synthetic fiber having the electro-conductive layer adhered to the surface thereof,

to form the electro-conductive fiber.

20. The process of claim 19, wherein, in the contacting, the at least one synthetic fiber is immersed in the dispersion with vibrating the at least one synthetic fiber to adhere the at least one carbon nanotube, the binder and the surfactant to the surface of the at least one synthetic fiber and to form the electro-conductive layer.

21. The process of claim 20, wherein a frequency of vibrating is not less than 20 Hz.

22. The process of claim 19, wherein the surfactant comprises a zwitterionic surfactant.

23. The process of claim 19, wherein the binder comprises at least one selected from the group consisting of an aqueous polyester resin, an aqueous acrylic resin, a vinyl acetate resin, and a polyurethane resin.

24. The process of claim 19, wherein a ratio of the surfactant is 0.1 to 50 parts by mass relative to 100 parts by mass of the carbon nanotube.

25. An electro-conductive yarn, comprising at least one electro-conductive fiber obtained by the process of claim 19.

26. An electro-conductive fiber structural object formed from at least one selected from an electro-conductive fiber obtained by the process of claim 19 an electro-conductive yarn comprising at least one of the electro-conductive fiber.