Facilitated processing for controlling bonding between sheet and carrier

• US 9,889,635 B2
• Filed: 12/13/2013
• Issued: 02/13/2018
• Est. Priority Date: 12/13/2012
• Status: Expired due to Fees

• Current Assignee: Corning Incorporated
• Original Assignee: Corning Incorporated
• Inventors: Bellman, Robert Alan, Bookbinder, Dana Craig, Manley, Robert George, Mazumder, Prantik
• Primary Examiner(s): O'HERN, BRENT T
• Application Number:
  US14/651,720
• Publication Number:
  US 20150306847A1
• Time in Patent Office: 1,523 Days
• Field of Search: 428 57
• CPC Class Codes: B32B 17/06 comprising glass as the main or only constituent of a layer, next to another layer of a specific material
• CPC Class Codes: B32B 2255/26 Polymeric coating
• CPC Class Codes: B32B 2457/206 Organic displays, e.g. OLED
• CPC Class Codes: B32B 2457/208 Touch screens
• CPC Class Codes: B32B 3/04 characterised by at least one layer folded at the edge, e.g. over another layer ; characterised by at least one layer enveloping or enclosing a material
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: C03C 2218/328 Partly or completely removing a coating
• CPC Class Codes: C03C 27/10 with the aid of adhesive specially adapted for that purpose
• CPC Class Codes: H10K 77/10 Substrates, e.g. flexible substrates
• CPC Class Codes: Y02E 10/549 Organic PV cells

Abstract

A method of forming an article from a glass sheet (20) having a glass-sheet bonding surface (24) and a glass carrier (10) having a carrier bonding surface (14). At least one of the glass sheet and carrier bonding surfaces is coated with a surface modification layer (30), and then the glass sheet is connected with the carrier via the surface modification layer. From the perimeter of the glass sheet and the carrier while connected, there is removed a portion of the surface modification layer so as to expose a portion (19, 29) of the bonding surface on each of the glass sheet and the carrier. The glass sheet and carrier are then heated at a temperature ≧400° C. so as to bond the perimeter of the glass sheet (26) with the perimeter of the carrier (16).

Claims

1. A method of forming an article, comprising:

obtaining a glass sheet having a glass-sheet bonding surface with a perimeter;

obtaining a glass carrier having a carrier bonding surface with a perimeter;

coating at least one of the glass sheet and carrier bonding surfaces with a surface modification layer;

connecting the glass sheet with the carrier via the surface modification layer;

removing, from the perimeter of the glass sheet and the carrier while connected, a portion of the surface modification layer so as to expose a portion of the bonding surface on each of the glass sheet and the carrier, wherein the exposed portion of the glass-sheet bonding surface adjoins the exposed portion of the carrier bonding surface; and

heating, after the removing and the exposing, the glass sheet and carrier at a temperature ≧

400°

C. but less than the strain point of both the glass of the glass sheet and the glass of the carrier so as to bond the perimeter of the glass sheet bonding surface with the perimeter of the carrier bonding surface.

2. The method of claim 1, wherein the glass-sheet bonding surface has an area equal to that of the carrier bonding surface.

3. The method of claim 1, wherein the removing comprises, in a vacuum chamber, treating the glass sheet as connected to the carrier with an O2 plasma.

4. The method of claim 1, wherein the removing comprises using UV radiation, heat, ablation of the surface modification layer with laser energy, or combinations thereof.

5. The method of claim 1, wherein prior to coating, the at least one of the glass-sheet bonding surface and the carrier bonding surface is cleaned with one or more of the following:

UV-Ozone, Oxygen plasma, ozonated deionized water (DI-O₃), standard clean 1 (SC1), standard clean 2 (SC2), wash chemistry including hydrogen fluoride (HF), or wash chemistry including sulfuric acid (H₂SO₄).

6. The method of claim 1, wherein the surface modification layer comprises an alkyl silane, a fluoro alkyl silane, an aromatic silane, a fluoro or chloro aromatic silane, or hexamethyldisilazane (HMDS).

7. The method of claim 1, wherein both of the glass-sheet and carrier bonding surfaces are coated with a surface modification layer.

8. The method of claim 1, wherein only one of the glass-sheet and carrier bonding surfaces is coated with a surface modification layer, and the other one of the glass-sheet and carrier bonding surfaces is heat treated so as to reduce the hydroxyl concentration thereon to a level substantially equal to a hydroxyl concentration on a glass surface that was cleaned with a standard clean 1 and then heated at 450°

C. for 1 hour.

9. The method of claim 1, wherein the surface modification layer is 0.1 to 100 nm thick.

10. The method of claim 1, wherein the surface modification layer is a self-assembled monolayer.

11. The method of claim 1, wherein the glass sheet has a thickness of ≦

300 microns.

12. The method of claim 1, wherein the carrier has a thickness of 200 microns to 3 mm.