Phenolic foam

• US 9,896,559 B2
• Filed: 09/18/2013
• Issued: 02/20/2018
• Est. Priority Date: 09/18/2012
• Status: Active Grant

• Current Assignee: Kingspan Holdings (Irl) Limited (Kingspan Group PLC)
• Original Assignee: Kingspan Holdings (Irl) Limited (Kingspan Group PLC)
• Inventors: Rochefort, Malcolm, Ripley, Lynne, Holland, Philip, Coppock, Vincent
• Primary Examiner(s): ZEMEL, IRINA SOPJIA
• Application Number:
  US14/429,044
• Publication Number:
  US 20150225528A1
• Time in Patent Office: 1,616 Days
• CPC Class Codes: C08J 2201/022 premixing or pre-blending a part of the components of a foamable composition, e.g. premixing the polyol with the blowing agent, surfactant and catalyst and only adding the isocyanate at the time of foaming
• CPC Class Codes: C08J 2201/026 Crosslinking before of after foaming
• CPC Class Codes: C08J 2203/14 Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
• CPC Class Codes: C08J 2203/142 Halogenated saturated hydrocarbons, e.g. H3C-CF3
• CPC Class Codes: C08J 2203/144 Perhalogenated saturated hydrocarbons, e.g. F3C-CF3
• CPC Class Codes: C08J 2203/182 of physical blowing agents, e.g. acetone and butane
• CPC Class Codes: C08J 2203/202 of physical blowing agents
• CPC Class Codes: C08J 2205/052 Closed cells, i.e. more than 50% of the pores are closed
• CPC Class Codes: C08J 2361/10 Phenol-formaldehyde condensates
• CPC Class Codes: C08J 2373/00 Characterised by the use of macromolecular compounds obtained by reactions forming a linkage containing oxygen or oxygen and carbon in the main chain, not provided for in groups C08J2359/00 - C08J2371/00; Derivatives of such polymers
• CPC Class Codes: C08J 9/0066 Use of inorganic compounding ingredients
• CPC Class Codes: C08J 9/141 Hydrocarbons
• CPC Class Codes: C08J 9/148 perfluorinated
• CPC Class Codes: C08J 9/149 Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143

Abstract

Phenolic closed-cell foam comprises a hydrocarbon blowing agent and includes an alkali metal silicate in an amount of at least 1% by weight. The foam has an aged thermal conductivity as determined by the procedures of EN13166:2008 of less than 0.025 W/m·K. The foam is formed from a phenolic resole resin mixture having a water content of greater than 15% by weight but less than 24% by weight.

Claims

1. A phenolic foam formed from a phenolic resole resin mixture comprising a phenolic resole resin, a surfactant, a blowing agent and an alkali metal silicate wherein the alkali metal silicate is added into the phenolic resin with a subsequent addition of an acid catalyst, the alkali metal silicate being present in an amount of at least 1% by weight, the phenolic resole resin mixture excluding optional fillers having a water content of from about 12% to about 24% by weight of the composition, the foam having a silica film formed within closed cells of the foam and thereby retain the blowing agent therein, the foam having an aged thermal conductivity as determined by the procedures of EN13166:

2008 or EN14314;

2009 of less than 0.025 W/m·

K.

2. The foam as claimed in claim 1 wherein the alkali metal silicate is present in an amount of from 1% to 10% by weight of the phenolic foam.

3. The foam as claimed in claim 1 wherein the alkali metal silicate is present in an amount of from 2.5% to 5% by weight of the phenolic foam.

4. The foam as claimed in claim 1 wherein the alkali metal silicate is hydrated and has the formula A₂SiO₃.nH₂O in which A is an alkali metal from Group 1 of the Periodic Table and n is an integer from 1 to 9.

5. The foam as claimed in claim 1 wherein the alkali metal silicate is selected from sodium silicate, potassium silicate and lithium silicate or mixtures thereof.

6. The foam as claimed in claim 1 wherein the silicate is sodium silicate pentahydrate.

7. The foam as claimed in claim 1 wherein the silicate is potassium silicate.

8. The foam as claimed in claim 1 wherein the silicate is lithium silicate.

9. The foam as claimed in claim 1 wherein the blowing agent is a hydrocarbon blowing agent.

10. The foam as claimed in claim 9 wherein the hydrocarbon comprises a mixture of cyclopentane and isopentane.

11. The foam as claimed in claim 9 wherein the blowing agent comprises a mixture of isopropyl chloride and isopentane.

12. The foam as claimed in claim 1 wherein the blowing agent comprises perfluoroalkane.

13. The foam as claimed claim 1 wherein the foam is formed from a phenolic resole resin mixture having a water content of greater than 15% by weight but less than 24% by weight and the alkali metal silicate is present in an amount of at least 1% by weight of the foam.

14. The foam as claimed in claim 13 wherein the alkali metal silicate is present in the phenolic resole resin mixture excluding fillers in an amount of from 1% to 10% by weight of the foam.

15. The foam as claimed in claim 13 wherein the alkali metal silicate is present in the resole resin mixture (excluding fillers) in an amount of from 2.5% to 5% by weight of the foam.

17. The foam as claimed in claim 1, wherein the foam is formed from a phenolic resin mixture having a water content of from about 15% by weight to about 24% by weight of the resin mixture.

18. The foams as claimed in claim 9, wherein the hydrocarbon comprises at least one pentane.

16. A method of making a foam product the method comprising forming the foam from a composition comprising:

a phenolic resin including surfactant, acid catalyst, blowing agent and alkali metal silicate and optional fillers, wherein the alkali metal silicate is added to the phenolic resin, and emulsified with blowing agent, prior to the addition of the acid catalyst,

the composition excluding optional fillers having a water content of from about 12% to about 24% by weight of the composition,

to produce a closed cell foam product a silica film within the closed cells of the foam, the foam having an aged thermal conductivity as determined by the procedures of EN13166;

2008 or EN14314;

2009 of less than 0.025 W/m·

K.

19. A method of making a phenolic foam product, the method comprising forming the foam by mixing an alkali metal silicate with a phenolic resin including a surfactant, prior to a subsequent acid catalyst addition, said phenolic resin having a water content of from 12% by weight to 24% by weight, emulsifying the mixture formed therefrom with blowing agent, and subsequently adding acid to cure the resultant mixture.