Laundry detergent composition

• US 9,896,646 B2
• Filed: 08/06/2015
• Issued: 02/20/2018
• Est. Priority Date: 08/07/2014
• Status: Active Grant

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Depoot, Karel Jozef Maria, Van Elsen, Katrien Andrea Lieven
• Primary Examiner(s): Mruk, Brian P
• Application Number:
  US14/819,463
• Publication Number:
  US 20160040103A1
• Time in Patent Office: 929 Days
• CPC Class Codes: C11D 1/04 Carboxylic acids or salts thereof soap C11D9/00
• CPC Class Codes: C11D 1/22 derived from aromatic compounds
• CPC Class Codes: C11D 1/66 Non-ionic compounds C11D1/002, C11D1/004, C11D1/008 take precedence
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/83 Mixtures of non-ionic with anionic compounds
• CPC Class Codes: C11D 1/86 Mixtures of anionic, cationic, and non-ionic compounds
• CPC Class Codes: C11D 17/043 Liquid or thixotropic (gel) compositions
• CPC Class Codes: C11D 17/045 Multi-compartment
• CPC Class Codes: C11D 3/0015 liquid
• CPC Class Codes: C11D 3/225 etherified, e.g. CMC
• CPC Class Codes: C11D 3/227 with nitrogen-containing groups

Abstract

The present invention is to a liquid laundry detergent composition comprising an anionic surfactant, a non-ionic surfactant, between 0.5 wt % and 25 wt % water and 0.05% and 2% by weight of the composition of a cationic polymer being an hydroxyethyl cellulose polymer derivatized with trimethyl ammonium substituted epoxide, wherein the anionic surfactant comprises fatty acid; and wherein;

• • the weight ratio of cationic polymer to anionic surfactant is less than 1:5;
  • the weight ratio of cationic polymer to non-ionic surfactant is more than 1:10;
  • the weight ratio of cationic polymer to total surfactant is less than 1:5;
  • and wherein the weight ratio of anionic to non-ionic surfactant is from 5:1 to 23:1,
    wherein ‘total surfactant’ means the level of all surfactant present in the liquid laundry detergent composition, including but not limited to all anionic, non-ionic and cationic surfactant.

Claims

1. A water-soluble unit dose article comprising a water-soluble film and a liquid composition,

the water-soluble unit dose article comprising at least two compartments,

the liquid composition being a liquid laundry detergent composition comprising an anionic surfactant, a non-ionic surfactant, between about 0.5 wt % and about 25 wt % water, and about 0.05% and about 2% by weight of the composition of a cationic polymer being an hydroxyethyl cellulose polymer derivatised with trimethyl ammonium substituted epoxide,

wherein the anionic surfactant comprises fatty acid, and wherein the non-ionic surfactant is selected from the group consisting of alcohol alkoxylate non-ionic surfactant, amine oxide surfactant, and mixtures thereof;

and

wherein;

the weight ratio of cationic polymer to anionic surfactant is less than about 1;

5;

the weight ratio of cationic polymer to non-ionic surfactant is more than about 1;

10;

the weight ratio of cationic polymer to total surfactant is less than about 1;

5;

and wherein the weight ratio of anionic to non-ionic surfactant is from about 5;

1 to about 23;

1,

wherein ‘

total surfactant’

means the level of all surfactant present in the liquid laundry detergent composition, including but not limited to all anionic, non-ionic and cationic surfactant, and

wherein the cationic polymer is present in the composition as a particle.

2. A water-soluble unit dose article according to claim 1, wherein the weight ratio of anionic to non-ionic surfactant is from about 5:

1 to about 20;

1.

3. A water-soluble unit dose article according to claim 1, wherein the weight ratio of anionic to non-ionic surfactant is from about 5:

1 to about 18;

1.

4. A water-soluble unit dose article according to claim 1, wherein the weight ratio of the anionic to non-ionic surfactant is from about 5:

1 to about 15;

1.

5. A water-soluble unit dose article according to claim 1, wherein the non-ionic surfactant comprises a fatty alcohol ethoxylate of formula R(EO)_n, wherein R represents an alkyl chain between about 4 and about 30 carbon atoms, (EO) represents one unit of ethylene oxide monomer and n has an average value between about 0.5 and about 20.

6. A water-soluble unit dose article according to claim 1, wherein the cationic polymer has a molecular weight of between about 100,000 and about 800,000 daltons.

7. A water-soluble unit dose article according to claim 1, wherein the anionic surfactant comprises linear alkylbenzene sulphonate.

8. A water-soluble unit dose article according to claim 1, wherein the cationic polymer is present at a level of between about 0.1% and about 1% by weight of the composition.

9. A water-soluble unit dose article according to claim 8, wherein the cationic polymer is present at a level of between about 0.2% and about 0.6% by weight of the of composition.

10. A water-soluble unit dose article according to claim 1, wherein the composition comprises a perfume, an encapsulated perfume, or a mixture thereof.

11. A water-soluble unit dose article according to claim 1, comprising an adjunct laundry detergent ingredient, wherein the adjunct laundry detergent ingredient is selected from bleach, bleach catalyst, dye, hueing agents, cleaning polymers, alkoxylated polyamines, polyethyleneimines, alkoxylated polyethyleneimines, soil release polymers, amphiphilic graft polymers, surfactants, solvents, dye transfer inhibitors, chelants, enzymes, perfumes, encapsulated perfumes, perfume delivery agents, suds suppressor, brighteners, polycarboxylates, structurants, anti-oxidant, deposition aids, silicones, clays, sucrose esters and mixtures thereof.

12. The water-soluble unit dose article according to claim 1, comprising at least three compartments.

13. The water-soluble unit dose article according to claim 1, where the compartments are arranged in a superposed orientation or in a side-by-side orientation.

14. The water-soluble unit dose article according to claim 1, wherein the article comprises enzymes in a compartment separate from the liquid composition comprising the cationic polymer.