Optically diffusive plastic having high stiffness

• US 9,897,722 B2
• Filed: 09/10/2015
• Issued: 02/20/2018
• Est. Priority Date: 09/10/2014
• Status: Active Grant

• Current Assignee: SHPP Global Technologies BV
• Original Assignee: SABIC Global Technologies BV (Government of Saudi Arabia)
• Inventors: Pan, Shengping, Yang, Jian, Ding, Yu, Huang, Guangde, An, Narong
• Primary Examiner(s): Santiago, Mariceli
• Application Number:
  US14/849,773
• Publication Number:
  US 20160070027A1
• Time in Patent Office: 894 Days
• CPC Class Codes: G02B 1/04 made of organic materials, e.g. plastics G02B1/08 takes precedence
• CPC Class Codes: G02B 1/041 Lenses
• CPC Class Codes: G02B 5/02 Diffusing elements; Afocal elements

Abstract

An optically diffusive plastic can comprise 40 to 94.9 mass % of a polymer resin matrix; 5 to 50 mass % of a glass filler; and 0.1 to 10 mass % of a light diffusing component; wherein the difference between refractive index of the polymer resin matrix and refractive index of the glass filler is less than or equal to 0.02; wherein a 1 millimeter (mm) thick sample of the optically diffusive plastic comprises a DLD value of greater than or equal to 1 degree (°) as measured by goniophotometry; wherein the 1 mm thick sample comprises a total transmittance of greater than or equal to 40% for incident light having a wavelength of 360 nanometers (nm) to 750 nm in air; and wherein a 3.2 mm thick sample of the optically diffusive plastic comprises a flexural modulus, measured at 23° C., of greater than or equal to 2,500 Megapascal (MPa).

Claims

1. An optically diffusive plastic comprising:

40 to 94.9 mass % of a polymer resin matrix;

5 to 50 mass % of a glass filler; and

0.1 to 10 mass % of a light diffusing component;

wherein the difference between refractive index of the polymer resin matrix and refractive index of the glass filler is less than or equal to 0.02;

wherein a 1 mm thick sample of the optically diffusive plastic comprises DLD value of greater than or equal to 1°

as measured by goniophotometry, and a total transmittance of greater than or equal to 40% for incident light having a wavelength of 360 nm to 750 nm in air as determined by ASTM D1003 Procedure A, using CIE standard illuminant D65; and

at least one of

wherein a 3.2 mm thick sample of the optically diffusive plastic comprises a flexural modulus, measured at 23°

C., of greater than or equal to 2,500 MPa as determined by ASTM D790; and

wherein a test sample of the optically diffusive plastic having a thickness of 1 mm, a width of 13.2 mm, and a length of 121 mm, is extended across a span of 60 mm exhibits a deflection of less than or equal to 10 mm when subjected to a load of 1 kgf applied by a load head having a 5 mm diameter and positioned in the center of the sample and center of the span in accordance to ASTM D5023.

2. The plastic of claim 1, wherein a 3.2 mm thick sample of the optically diffusive plastic comprises a flexural modulus, measured at 23°

C., of greater than or equal to 2,500 MPa as determined by ASTM D790.

3. The plastic of claim 1, wherein the deflection is less than or equal to 8 mm.

4. The plastic of claim 1, wherein haze of the 1 mm thick sample as determined by ASTM D1003 procedure A, using CIE standard illuminant C is greater than or equal to 95%.

5. The plastic claim 1, wherein the total transmittance is greater than or equal to 50% for incident light having a wavelength of 360 nm to 750 nm in air.

6. The plastic of claim 1, wherein the refractive index of the glass filler is 1.564 to 1.582.

7. The plastic claim 1, wherein the light diffusing component comprises poly(methylmethacrylate), a silicone bead, titanium dioxide, or a combination comprising at least one of the foregoing.

8. The plastic of claim 1, wherein the light diffusing component comprises polymethylsilsesquioxane, hydrolyzed poly(alkyl trialkoxysilanes), or both polymethylsilsesquioxane and hydrolyzed poly(alkyl trialkoxysilanes).

9. The plastic of claim 1, wherein the polymer resin matrix comprises a polycarbonate, a polyester, a polyester copolymer, a polycarbonate copolymer, poly(methyl methacrylate), polystyrene or a combination comprising at least one of the foregoing.

10. The plastic of claim 1, wherein the difference between the refractive index of the polymer resin matrix and the refractive index of the glass filler is less than or equal to 0.01.

11. The plastic of claim 1, wherein the DLD value is greater than or equal to 30°

.

12. The plastic of claim 1, wherein the DLD value is greater than or equal to 60°

.

13. The plastic of claim 1, wherein the total transmittance is greater than or equal to 60%.

14. The plastic of claim 1, wherein the flexural modulus is greater than or equal to 3,000 MPa.

15. The plastic of claim 1, wherein the flexural modulus is greater than or equal to 4,500 MPa.

16. An optical lens or an optical diffuser comprising the optically diffusive plastic of claim 1.

17. The plastic of claim 1, wherein optically diffusive plastic comprises 25 to 50 mass % of the glass filler.

18. The plastic of claim 17, wherein the polymer resin matrix comprises polycarbonate-polysiloxane.

19. An illuminating device comprising:

a light source; and

an optical element comprising an optically diffusive plastic, wherein the optically diffusive plastic comprises

40 to 94.9 mass % of a polymer resin matrix;

5 to 50 mass % of a glass filler; and

0.1 to 10 mass % of a light diffusing component;

wherein the difference between refractive index of the polymer resin matrix and refractive index of the glass filler is less than or equal to 0.02;

wherein a 1 mm thick sample of the optically diffusive plastic comprises DLD value of greater than or equal to 1°

as measured by goniophotometry, and a total transmittance of greater than or equal to 40% for incident light having a wavelength of 360 nm to 750 nm in air as determined by ASTM D1003 Procedure A, using CIE standard illuminant D65; and

at least one of

wherein a 3.2 mm thick sample of the optically diffusive plastic comprises a flexural modulus, measured at 23°

C., of greater than or equal to 2,500 MPa as determined by ASTM D790; and

wherein a test sample of the optically diffusive plastic having a thickness of 1 mm, a width of 13.2 mm, and a length of 121 mm, is extended across a span of 60 mm exhibits a deflection of less than or equal to 10 mm when subjected to a load of 1 kgf applied by a load head having a 5 mm diameter and positioned in the center of the sample and center of the span in accordance to ASTM D5023; and

wherein the optical lens or the optical diffuser is disposed between the light source and an object to be illuminated.

20. A method of forming an optical element comprising:

heating a optically diffusive, wherein the optically diffusive plastic comprises

40 to 94.9 mass % of a polymer resin matrix;

5 to 50 mass % of a glass filler; and

0.1 to 10 mass % of a light diffusing component;

wherein the difference between refractive index of the polymer resin matrix and refractive index of the glass filler is less than or equal to 0.02;

wherein a 1 mm thick sample of the optically diffusive plastic comprises DLD value of greater than or equal to 1°

as measured by goniophotometry, and a total transmittance of greater than or equal to 40% for incident light having a wavelength of 360 nm to 750 nm in air as determined by ASTM D1003 Procedure A, using CIE standard illuminant D65; and

at least one of

wherein a 3.2 mm thick sample of the optically diffusive plastic comprises a flexural modulus, measured at 23°

C., of greater than or equal to 2,500 MPa as determined by ASTM D790; and

wherein a test sample of the optically diffusive plastic having a thickness of 1 mm, a width of 13.2 mm, and a length of 121 mm, is extended across a span of 60 mm exhibits a deflection of less than or equal to 10 mm when subjected to a load of 1 kgf applied by a load head having a 5 mm diameter and positioned in the center of the sample and center of the span in accordance to ASTM D5023;

introducing the optically diffusive plastic into a cavity of a molding device, wherein the cavity is defined by a die having opposing surfaces, and wherein the cavity has a shape of the optical element;

pressing the opposing surfaces of the die together; and

cooling the cavity to form the optical element.